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  • Chemical Engineering  (336)
  • Inorganic Chemistry
  • GENERAL
  • 1970-1974  (483)
  • 1955-1959  (118)
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Publisher
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 415-416 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2019-06-27
    Keywords: GENERAL
    Type: NASA-CR-126424 , Am. Assoc. for Advan. of Sci. Mariner to Mars; 4 p
    Format: text
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 24-31 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Flow at the entrance of a tube or channel is of interest in many polymer processes. Except for mathematical treatments at high Reynolds numbers and in creeping Newtonian flow, one must turn to empirical correlating equations and qualitative observations. These are discussed in two parts, one on pressure drop and the other on flow patterns. The discussion of pressure drop is largely a review, dealing with inertial, viscous, and elastic contributions to the pressure drop in tapered and sharp-edged entrances; also presented are new data for a viscoelastic polymer solution in tapered cone entrances. In the section on flow patterns, stress birefringent data for a very elastic solution flowing into a channel entrance show an unusual effect: stress discontinuities, not unlike “shock waves,” upstream and downstream of the entrances. This is in contrast to Newtonian and less elastic materials in which the stress patterns change gradually between the developed flow region and the entrance region.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 193-203 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The capillary flow instability resulting in extrudate distortion has been studied for ethylene polymer melts using a molecular structure approach. It is found that the instability initiates at a critical value of elastic strain energy independent of (average) molecular weight for linear polyethylene. Once the flow breaks down, a slip interface within the melt is formed near the capillary wall, causing an abrupt increase in volumetric throughput. The velocity gradient within the melt remains continuous through the instability, however. Low molecular weight species present in the molecular weight distribution of linear polyethylene tend to suppress slip. Blends of linear and branched polyethylene exhibit instability behavior characteristic of both components throughout the entire range of composition. Results are discussed in terms of specific molecular mechanisms.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 11 (1971), S. 377-380 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The thermal stability of polyethylene containing conventional antioxidants is adversely affected by contact with copper, by certain pigments, and by the addition of a few percent of polypropylene as a processing aid. Polyethylene inhibited with 0.1% of phenolic antioxidants has approximately the same oxidative stability when in contact with a copper surface as the unprotected polymer. A mechanism is suggested to account for the loss of stability in the presence of copper. Pigments vary in the extent to which they adversely affect the oxidative stability of polyethylene. Since several factors may combine to decrease the stability of protected polyethylene compositions, as determined by accelerated tests, it is essential that their contribution under service conditions be determined. The predicted life at temperatures encountered in service is determined by extrapolating accelerated test data to that constant temperature which is calculated to cause the same degree of degradation as would occur during the daily and seasonal temperature cycles encountered in use.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 14 (1974), S. 806-809 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The flow and processing behavior of commercial plastics is determined not only by the characteristics of the base resin but also by the presence of additives of various kinds. In this study the influence of a number of additives on the rheological behavior of molten ABS was investigated using a capillary extrusion rheometer and a Weissenberg rheogoniometer. The additives studied included molding lubricants, rubber impact modifiers, flame-retardant additives, and residual unreacted components remaining from the polymerization process. The mechanisms by which these species affect flow characteristics are described.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 340-344 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The cross-linked, ladderlike structure of cured pyrrones is not susceptible to forming at ordinary temperatures and pressures. At unusually high processing temperatures, of the order of 500°C, these intractable materials are observed to undergo transient flow sufficient to allow molding of the material. This observation, supported by analytical information, suggests that the flow occurs because of the breakage of covalent organic bonds and subsequent structural rearrangement of the cross-linked polymer network. This is in accord with a number of isolated reports of the pyrolytic behavior of several polymers.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 13 (1973), S. 280-286 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The physical structure of a number of styrene-butadiene copolymers were investigated via dynamic mechanical and swelling studies on uncrosslinked and gamma-radiation cross-linked films that had initially been solvent cast from toluene or methyl ethyl ketone. The mechanical behavior of these films before and after crosslinking was found to depend on the material history as well as the chemical structure of the copolymer, in agreement with observations made by other experimental techniques. A simple morphological interpretation was given to the dynamic mechanical spectra as a function of radiation dosage and a limited discussion of the swelling behavior is included.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 14 (1974), S. 161-161 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 13 (1973), S. 455-461 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Pronounced effects of thermal treatment on the properties of graphite fiber/polycarbonate and glass fiber/polycarbonate composites have been demonstrated and explained. At 20 volume percent loading of random-in-a-plane, discontinuous fibers, both specimen strength and modulus in both fiber systems were found to increase dramatically upon molding above 260-265°C, whereas only the graphite system was further improved by subsequent annealing. In the latter case, property improvement is due to generation of a crystalline innerlayer at the interface, which apparently transfers the stresses more effectively from fiber to fiber. Regardless of the type of fiber, molding at 275°C (slightly above 260-265°C, the melting point of crystalline polycarbonate) results in improved properties due to better wetting of the fibers by the resin. Hot forming of graphite reinforced polycarbonate composites between the molding and annealing steps takes advantage of the higher processability of the unannealed material in addition to providing increased modulus and strength in the final molded article.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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