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  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 31 (1991), S. 789-792 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effects of flamespray coating conditions on two ethylene-carboxylic acid copolymers (Primacor 1420 and Nucrel 535) and a polyether block amide (Pebax 5533) on crystallinity and mechanical properties were investigated by differential scanning calorimetry (DSC), Gardner impact resistance, and conical mandrel bend tests. Plastic flamespray provides a means to apply thermoplastic powder coatings in the field with a wide range of properties to meet specific application requirements. The flamespray process did not significantly affect the crystallinity in the polymers studied, however, polymers possessing functional groups in the backbone such as the polyether block amide may experience some reduction in physical properties during the flamespray coating process. We have also successfully applied some high temperature thermoplastics (such as liquid crystal polymers) providing for coatings, with outstanding temperature and chemical resistance.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2037-2046 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: To understand better the impact of gas phase reactions on chemical vapor deposition, a new experimental method has been developed to isolate and study homogeneous reactions separately from heterogeneous reactions. This new system heats reactant gases by rapidly compressing them to temperatures greater than 1,000 K; the walls of the reactor remain constant at 500 K or less. Pressure and volume measurements determine the mean temperature of the gas. Results from a series of test reactions and simple models show that this apparatus and measurement method work well. The apparatus is inexpensive and simple to use, and has advantages over shock tubes and static systems.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 793-802 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A piston reactor has been developed to examine some aspects of particle formation during the pyrolysis of silane (SiH4). This reactor generates conditions intermediate between a static pyrolysis reactor and a shock tube reactor. It effectively excludes contributions of wall reactions to the pyrolysis experiments. The apparent kinetics for this reactor do not conform to values published in the literature. A model that incorporates silane-particle reactions can account for the deviations. In addition, emission of visible light accompanies the sooting reactions. The source of this emission seems to be the sum of incandescence from the hot particles and continuum radiation from another source.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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