ISSN:
0947-3440
Keywords:
Matrix isolation
;
IR spectroscopy
;
Photochemistry
;
Ab initio calculations
;
Alkene complexes
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The matrix-isolated ethylene-bromine complex (1) and the cyclopropene-bromine complex (8) have been chosen to examine which ab initio method (MP2 or BLYP) is more suitable to calculate the IR spectra and structures of π complexes. In addition the photochemistry of 1 and 8 has been investigated and the mechanism of the photochemically induced reactions is discussed.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.199719970208
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