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  • 1
    Monograph available for loan
    Monograph available for loan
    Chur : Bischofberger
    Call number: G 6145 / Regal 13
    Type of Medium: Monograph available for loan
    Pages: 260 S. : Ill., graph. Darst.
    Edition: 1. öffentl., neu durchgearb. Ausg.
    Location: Magazine - must be ordered
    Branch Library: GFZ Library
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Experiments in fluids 20 (1996), S. 210-217 
    ISSN: 1432-1114
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract In order to investigate the temporal behavior of dynamic flow processes, a movie version of particle image velocimetry (PIV) with a high framing capability has been developed. The experimental setup includes a copper vapor laser capable to produce pulse sequences with more than 100 pulses with a repetition rate of up to 30 kHz and a rotating drum camera to record the Mie scattering signals from the particles seeded to the flow. With this setup, image sequences with a number of consecutive images (40–70 depending on the image size) of a dynamic process can be taken on high resolution 36 mm film. To evaluate the 2-dimensional velocity vector fields, an algorithm based on the crosscorrelation of subareas in consecutive images has been developed and optimized in terms of computing time. The technique was applied to resolve the instationary flow field in a single cylinder spark ignition (SI) engine during the compression stroke.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1432-1130
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Some YBa2Cu3O7-δ films and heterostructures prepared by Chemical Vapor Deposition (CVD) were analyzed in our laboratories by EPMA-EDX or WDX, RBS, SNMS and AES. It was found that in some cases the results of composition analysis can significantly deviate from each other. At least two main reasons for these deviations exist: the different lateral resolution and the application of different reference samples for the calibration.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 2944-2950 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Measurements of the absorption by pure CO2 in the 4.3 μm region are presented. They refer to the temperature of 291 K and densities in the 1–80 amagat range. Calculations based on the addition of Lorentzian contributions strongly overestimate the absorption since they do not account for line overlapping. The energy corrected sudden approximation (ECSA) is used to model line mixing within the impact approximation. The scaling parameters of this model are deduced from line-broadening data. This calculation strongly underestimates the absorption in the spectral region near the edges of the vibrational band, whereas it overestimates the absorption in the far wings of the lines. This is attributed to the impact approximation which does not account for the frequency dependence of the relaxation operator. This dependence is roughly determined from our results; it is in good qualitative agreement with the few corresponding available results.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 2999-3006 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The ability of available theoretical models in describing broadening mechanisms is tested for the CO2–O2, CO2–CO2, and CO2–N2 systems. It is shown that the Anderson–Tsao–Curnutte theory is inaccurate since short-range forces can contribute significantly to broadening. We use the approach of Robert and Bonamy, but the usual expansion of the atom–atom potential to the fourth order around the intermolecular distance appears insufficient at short distances for these particular systems. We propose a better representation of the radial dependence of the atom–atom potential, while keeping the previous analytical expression of the cross section. Satisfactory results are obtained for both the rotational quantum number dependence of room-temperature CO2–O2, CO2–CO2, and CO2–N2 half-widths and the evolution of CO2–N2 broadening with temperature. It is shown that the isotropic part of the potential involved in the trajectory calculation must be coherently deduced from the atom–atom interaction potential.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 5916-5925 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: In order to understand the influence of H2O on the stimulated Raman Q-branch spectra of nitrogen in combusting media, an exhaustive theoretical and experimental study has been carried out. Starting from a semiclassical model, particularly convenient at high temperature, the Q-line broadening and shifting coefficients have been calculated over a wide temperature range and for a large number of lines. Stimulated Raman Spectra (SRS) measurements have allowed us to test these calculated line broadening coefficients and thus establish the high accuracy of semiclassical values. The theoretical broadening coefficients have been inverted to deduce state-to-state rotational relaxation rates by using two types of fitting laws. A partial test of the resulting Q-branch profiles has been realized at moderate pressures leading to a discrimination between these two laws. Furthermore, the effect of rotational energy transfers on collisionally narrowed profiles at higher densities has been simulated and compared with the pure N2 case.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Numerous comparisons between predictions of the model presented in part I of this paper and experimental H2O infrared linewidths are presented. It is shown that our model, contrary to those used up to now, gives accurate results for H2O room-temperature line broadening by O2 and Ar, and for high rotational quantum-number lines by N2. First accurate experimental widths and intensities of some H2O ν2-band lines in the 400–900 K temperature range are also presented. Detailed analysis of the data demonstrates the great influence of a "resonance overtaking'' mechanism. The latter results from the modifications of both the perturber rovibrational population distribution and kinetic energy with temperature; it strongly enhances the contributions of the collision-induced rotational transitions involving significant energy jumps. This mechanism is well accounted for by our model and quantitatively explains the unusually slow decrease of some linewidths with temperature.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 93 (1990), S. 2217-2221 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We present experimental and theoretical results on the absorption in the Ar-broadened wing of the infrared CO2 ν3 band. Measurements have been made in the 293–765 K temperature range for total gas pressures up to 60 bar and are in good agreement with previous determinations at room temperature. Calculations have been carried out by using a line by line coupling theory presented and tested previously [J. Chem. Phys. 89, 625 (1988) and 91, 2163 (1989)]. The theoretical approach accounts for both line mixing and the wave-number dependence of the relaxation operator. It enables correct modeling of the temperature dependence of absorption. The strong sublorentzian absorption resulting from competitions between negative and positive individual line contributions is analyzed.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 87 (1987), S. 2781-2789 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A semiclassical theory of asymmetric-top molecule line broadening, developed in part I of this series of papers for linear perturbers, is extended to asymmetric-top perturbers. This model has been successfully applied in part II to the broadening of H2O lines by N2, O2, and Ar. The present applications to the self-broadening of H2O infrared and Raman lines in the 300–900 K range also show the quality of the model. Due to the high electrostatic forces involved in the H2O–H2O interaction, the short-range anisotropic potential has little influence. Nevertheless, the need for a modeling of the trajectory is demonstrated, mainly in the case of high rotational quantum number lines.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 114 (2001), S. 4669-4684 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Combining molecular beam techniques and time-resolved infrared reflection absorption spectroscopy (TR-IRAS) we have studied the kinetics of the CO oxidation reaction on an alumina-supported Pd model catalyst. The Pd particles are deposited by metal evaporation under ultrahigh vacuum (UHV) conditions onto a well-ordered alumina film, prepared on a NiAl(110) single crystal. Particle size, density and structure of the Pd deposits have been characterized in previous studies. In the low temperature region, transient and steady-state experiments have been performed over a wide range of CO and oxygen fluxes by crossing two effusive molecular beams on the sample surface. We determine the steady-state CO2 production rate as a function of the CO fraction in the impinging gas flux. Simultaneously, the occupation of CO adsorption sites under steady-state conditions is monitored by in situ IR spectroscopy. The origin of different types of CO2 transients is discussed. In particular we focus on the transient CO2 production after switching off the CO beam. For the model catalyst investigated, detailed reaction rate measurements in combination with time-resolved IRAS show that the origin of the particular transient behavior of the supported model system is not due to the presence of specific adsorption sites on small particles, as has been proposed previously. Instead, we show that the transient behavior can be semiquantitatively simulated on the basis of a simple kinetic model considering a homogeneous surface, and accounting for the inhibition of the dissociative adsorption of O2 at high CO coverage. Moreover, it is discussed how the inherent heterogeneity of the supported particle system can additionally enhance the observed effect. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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