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  • 1
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 123 (1990), S. 1591-1594 
    ISSN: 0009-2940
    Schlagwort(e): Zeolite ; Microwave irradiation ; Claisen rearrangement ; Dehydrogenation ; Dehydration ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Microwave-Induced Reactions of Organic Substrates in the Cage of ZeolitesMicrowave irradiation of compounds 1, 7, 15, 19, 23, and 24adsorbed on Y zeolites has been studied. The reaction rate of the corresponding rearrangement, dehydrogenation and dehydration is dramatically enhanced as compared with reactions under thermal conditions.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Publikationsdatum: 2018-07-01
    Beschreibung: Deep moist convection is an inherently multiscale phenomenon with organization processes coupling convective elements to larger-scale structures. A realistic representation of the tropical dynamics demands a simulation framework that is capable of representing physical processes across a wide range of scales. Therefore, storm-resolving numerical simulations at 2.4 km have been performed covering the tropical Atlantic and neighboring parts for 2 months. The simulated cloud fields are combined with infrared geostationary satellite observations, and their realism is assessed with the help of object-based evaluation methods. It is shown that the simulations are able to develop a well-defined intertropical convergence zone. However, marine convective activity measured by the cold cloud coverage is considerably underestimated, especially for the winter season and the western Atlantic. The spatial coupling across the resolved scales leads to simulated cloud number size distributions that follow power laws similar to the observations, with slopes steeper in winter than summer and slopes steeper over ocean than over land. The simulated slopes are, however, too steep, indicating too many small and too few large tropical cloud cells. It is also discussed that the number of larger cells is less influenced by multiday variability of environmental conditions. Despite the identified deficits, the analyzed simulations highlight the great potential of this modeling framework for process-based studies of tropical deep convection.
    Print ISSN: 0027-0644
    Digitale ISSN: 1520-0493
    Thema: Geographie , Geologie und Paläontologie , Physik
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Publikationsdatum: 2020-05-13
    Beschreibung: Clouds and aerosols contribute the largest uncertainty to current estimates and interpretations of the Earth’s changing energy budget. Here we use a new-generation large-domain large-eddy model, ICON-LEM (ICOsahedral Non-hydrostatic Large Eddy Model), to simulate the response of clouds to realistic anthropogenic perturbations in aerosols serving as cloud condensation nuclei (CCN). The novelty compared to previous studies is that (i) the LEM is run in weather prediction mode and with fully interactive land surface over a large domain and (ii) a large range of data from various sources are used for the detection and attribution. The aerosol perturbation was chosen as peak-aerosol conditions over Europe in 1985, with more than fivefold more sulfate than in 2013. Observational data from various satellite and ground-based remote sensing instruments are used, aiming at the detection and attribution of this response. The simulation was run for a selected day (2 May 2013) in which a large variety of cloud regimes was present over the selected domain of central Europe. It is first demonstrated that the aerosol fields used in the model are consistent with corresponding satellite aerosol optical depth retrievals for both 1985 (perturbed) and 2013 (reference) conditions. In comparison to retrievals from ground-based lidar for 2013, CCN profiles for the reference conditions were consistent with the observations, while the ones for the 1985 conditions were not. Similarly, the detection and attribution process was successful for droplet number concentrations: the ones simulated for the 2013 conditions were consistent with satellite as well as new ground-based lidar retrievals, while the ones for the 1985 conditions were outside the observational range. For other cloud quantities, including cloud fraction, liquid water path, cloud base altitude and cloud lifetime, the aerosol response was small compared to their natural variability. Also, large uncertainties in satellite and ground-based observations make the detection and attribution difficult for these quantities. An exception to this is the fact that at a large liquid water path value (LWP 〉 200 g m−2), the control simulation matches the observations, while the perturbed one shows an LWP which is too large. The model simulations allowed for quantifying the radiative forcing due to aerosol–cloud interactions, as well as the adjustments to this forcing. The latter were small compared to the variability and showed overall a small positive radiative effect. The overall effective radiative forcing (ERF) due to aerosol–cloud interactions (ERFaci) in the simulation was dominated thus by the Twomey effect and yielded for this day, region and aerosol perturbation −2.6 W m−2. Using general circulation models to scale this to a global-mean present-day vs. pre-industrial ERFaci yields a global ERFaci of −0.8 W m−2.
    Print ISSN: 1680-7316
    Digitale ISSN: 1680-7324
    Thema: Geologie und Paläontologie
    Publiziert von Copernicus im Namen von European Geosciences Union.
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Publikationsdatum: 2018-05-03
    Beschreibung: Cirrus clouds play an important role in determining the radiation budget of the earth, but many of their properties remain uncertain, particularly their response to aerosol variations and to warming. Part of the reason for this uncertainty is the dependence of cirrus cloud properties on the cloud formation mechanism, which itself is strongly dependent on the local meteorological conditions. In this work, a classification system (Identification and Classification of Cirrus or IC-CIR) is introduced to identify cirrus clouds by the cloud formation mechanism. Using reanalysis and satellite data, cirrus clouds are separated into four main types: orographic, frontal, convective and synoptic. Through a comparison to convection-permitting model simulations and back-trajectory-based analysis, it is shown that these observation-based regimes can provide extra information on the cloud-scale updraughts and the frequency of occurrence of liquid-origin ice, with the convective regime having higher updraughts and a greater occurrence of liquid-origin ice compared to the synoptic regimes. Despite having different cloud formation mechanisms, the radiative properties of the regimes are not distinct, indicating that retrieved cloud properties alone are insufficient to completely describe them. This classification is designed to be easily implemented in GCMs, helping improve future model–observation comparisons and leading to improved parametrisations of cirrus cloud processes.
    Print ISSN: 1680-7316
    Digitale ISSN: 1680-7324
    Thema: Geologie und Paläontologie
    Publiziert von Copernicus im Namen von European Geosciences Union.
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Publikationsdatum: 2017-04-13
    Beschreibung: The HD(CP)2 Observational Prototype Experiment (HOPE) was performed as a major 2-month field experiment in Jülich, Germany, in April and May 2013, followed by a smaller campaign in Melpitz, Germany, in September 2013. HOPE has been designed to provide an observational dataset for a critical evaluation of the new German community atmospheric icosahedral non-hydrostatic (ICON) model at the scale of the model simulations and further to provide information on land-surface–atmospheric boundary layer exchange, cloud and precipitation processes, as well as sub-grid variability and microphysical properties that are subject to parameterizations. HOPE focuses on the onset of clouds and precipitation in the convective atmospheric boundary layer. This paper summarizes the instrument set-ups, the intensive observation periods, and example results from both campaigns. HOPE-Jülich instrumentation included a radio sounding station, 4 Doppler lidars, 4 Raman lidars (3 of them provide temperature, 3 of them water vapour, and all of them particle backscatter data), 1 water vapour differential absorption lidar, 3 cloud radars, 5 microwave radiometers, 3 rain radars, 6 sky imagers, 99 pyranometers, and 5 sun photometers operated at different sites, some of them in synergy. The HOPE-Melpitz campaign combined ground-based remote sensing of aerosols and clouds with helicopter- and balloon-based in situ observations in the atmospheric column and at the surface. HOPE provided an unprecedented collection of atmospheric dynamical, thermodynamical, and micro- and macrophysical properties of aerosols, clouds, and precipitation with high spatial and temporal resolution within a cube of approximately 10  ×  10  ×  10 km3. HOPE data will significantly contribute to our understanding of boundary layer dynamics and the formation of clouds and precipitation. The datasets have been made available through a dedicated data portal. First applications of HOPE data for model evaluation have shown a general agreement between observed and modelled boundary layer height, turbulence characteristics, and cloud coverage, but they also point to significant differences that deserve further investigations from both the observational and the modelling perspective.
    Print ISSN: 1680-7316
    Digitale ISSN: 1680-7324
    Thema: Geologie und Paläontologie
    Publiziert von Copernicus im Namen von European Geosciences Union.
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Publikationsdatum: 2019-06-01
    Beschreibung: A configuration of the High-Altitude Long-Range Research Aircraft (HALO) as a remote sensing cloud observatory is described, and its use is illustrated with results from the first and second Next-Generation Aircraft Remote Sensing for Validation (NARVAL) field studies. Measurements from the second NARVAL (NARVAL2) are used to highlight the ability of HALO, when configured in this fashion, to characterize not only the distribution of water condensate in the atmosphere, but also its impact on radiant energy transfer and the covarying large-scale meteorological conditions—including the large-scale velocity field and its vertical component. The NARVAL campaigns with HALO demonstrate the potential of airborne cloud observatories to address long-standing riddles in studies of the coupling between clouds and circulation and are helping to motivate a new generation of field studies.
    Print ISSN: 0003-0007
    Digitale ISSN: 1520-0477
    Thema: Geographie , Physik
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
  • 8
    Publikationsdatum: 2015-03-31
    Beschreibung: The seasonality in large-scale meteorology and low-level cloud amount (CClow) is explored for a 5° × 5° area in the North Atlantic trades, using 12 years of ERA-Interim and MODIS data, supported by 2 years of Barbados Cloud Observatory (BCO) measurements. From boreal winter to summer, large-scale subsiding motion changes to rising motion, along with an increase in sea surface temperature, a clockwise turning and weakening of low-level winds, and reduced cold-air advection, lower-tropospheric stability (LTS), and surface fluxes. However, CClow is relatively invariant around 30%, except for a minimum of 20% in fall. This minimum is only pronounced when MODIS scenes with large high-level cloud amount are excluded, and a winter maximum in CClow is more pronounced at the BCO. On monthly time scales, wind speed has the best correlation with CClow. Existing large-eddy simulations suggest that the wind speed–CClow correlation may be explained by a direct deepening response of the trade wind layer to stronger winds. Large correlations of wind direction and advection with CClow also suggest that large-scale flow patterns matter. Smaller correlations with CClow are observed for LTS and surface evaporation, as well as negligible correlations for relative humidity (RH) and vertical velocity. However, these correlations considerably increase when only summer is considered. On synoptic time scales, all correlations drop substantially, whereby wind speed, RH, and surface sensible heat flux remain the leading parameters. The lack of a single strong predictor emphasizes that the combined effect of parameters is necessary to explain variations in CClow in the trades.
    Print ISSN: 0022-4928
    Digitale ISSN: 1520-0469
    Thema: Geographie , Geologie und Paläontologie , Physik
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Publikationsdatum: 2017-11-06
    Beschreibung: The doldrums - a zone of calm and variable winds in the deep tropics between the trades - were of key importance to nineteenth century maritime travel. As a result, the region was a focus in atmospheric science at that time. However, as sailing ships were replaced by steamboats, scientific interest shifted to the heavy precipitating storms within the doldrums: the deep convective systems of the intertropical convergence zone. Now, in storm-system-resolving simulations over a period of two months that cover a large part of the tropical Atlantic, the doldrums are one of the most prominent features. The doldrums are substantially less pronounced in coarser-resolution simulations that use a parameterization for convection, despite their large-scale extent. We conclude that explicitly representing the storm scale dynamics and their coupling to the surface wind on the storm-system scales helps to maintain the systems of winds that define the doldrums. We suggest that the lack of these wind systems could explain the persistent tropical precipitation biases in climate models. © 2017 The Author(s).
    Print ISSN: 1752-0894
    Digitale ISSN: 1752-0908
    Thema: Geologie und Paläontologie
    Publiziert von Springer Nature
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Publikationsdatum: 2019-09-30
    Beschreibung: Over the tropical oceans, the large-scale, meridional circulation drives the accumulation of moist and warm air, leading to a relatively narrow, convectively active band. Therein, deep moist convection interacts with its heterogeneous environment—the intertropical convergence zone (ITCZ)—and organizes into multiscale structures that strongly impact Earth’s hydrological cycle and radiation budget. Understanding the spatial correlations and interactions among deep convective clouds is important, but challenging. These clouds are investigated in this study with the help of large-domain, storm-resolving simulations over the tropical Atlantic. Based on vertically integrated mass flux fields, deep convective updraft cells are identified with object-based techniques and analyzed with respect to their structural behavior and spatial arrangement. The pair-correlation method, which compares simulated pair numbers as a function of pair distance to an appropriately chosen reference, is applied and extended to allow for spatial statistics in a heterogeneous environment (i.e., the ITCZ). Based on pair-correlation analysis, the average probability is enhanced to find an updraft cell pair within 100 km compared to a random distribution. Additionally, the spatial arrangement of larger or stronger cells deviates more from randomness compared to smaller or weaker cells, which might be related to their stronger dynamical interaction mechanisms. Using simplified equilibrium statistics of interacting cells, several spatial characteristics of the storm-resolving simulations can be reproduced.
    Print ISSN: 0022-4928
    Digitale ISSN: 1520-0469
    Thema: Geographie , Geologie und Paläontologie , Physik
    Standort Signatur Erwartet Verfügbarkeit
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