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  • 11
    Publication Date: 2023-01-21
    Description: Closure of the Central American Seaway (CAS) and hydrology of the Caribbean Sea triggered Northern Hemisphere Glaciation and played an important role in the Pliocene to modern‐day climate re‐establishing the deep and surface ocean currents. New data on Mn/Ca obtained with femtosecond laser ablation inductively coupled plasma mass spectrometry on well‐preserved tests of the epibenthic foraminifer Cibicidoides wuellerstorfi and infaunal C. mundulus contribute to the interpretation of paleoenvironmental conditions of the Caribbean Sea between 5.2 and 2.2 Ma (million years) across the closure of the CAS. Hydrothermal activity at the Lesser Antilles may be a primary source of Mn in the well‐oxygenated Plio‐Pleistocene Caribbean Sea. Incorporation of Mn in the benthic foraminifer shell carbonate is assumed to be affected by surface ocean nutrient cycling, and may hence be an indicator of paleoproductivity.
    Description: Plain Language Summary: The closure of the Panama Isthmus caused the expansion of ice sheets in the Northern Hemisphere and changed the water current dynamics and climate in the Caribbean Sea since the Pliocene (∼5.3 million years ago). New Mn/Ca data measured using femtosecond laser ablation inductively coupled plasma mass spectrometry on the deep‐sea benthic foraminifer species Cibicidoides wuellerstorfi and Cibicidoides mundulus help us understand past environmental conditions of the Caribbean Sea prevailed between 5.2 and 2.2 million years ago. While manganese might be sourced from the surrounding hydrothermal vents, its incorporation in the foraminifer shell carbonate might be related to nutrient cycling and may indicate past biological productivity in the ocean.
    Description: Key Points: Femtosecond‐laser ablation inductively coupled plasma mass spectrometry provides a new approach on distinguishing Mn of the ontogenetic shell calcite from Mn of the authigenic coatings. Ontogenetic Mn within the foraminifer shell calcite may result from the regional nutrient cycle. Mn in the deep eastern Caribbean Sea may mainly derive from hydrothermal sources along the Antilles Island Arc.
    Description: MPIC
    Description: https://doi.org/10.17632/bps7nw7922.1
    Keywords: ddc:560 ; manganese ; Cibicidoides wuellerstorfi ; Cibicidoides mundulus ; Central American Seaway ; trace elements ; hydrothermal ; paleoproductivity
    Language: English
    Type: doc-type:article
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  • 12
    Publication Date: 2022-12-10
    Description: Faults and fractures can be permeable pathways for focused fluid flow in structurally controlled ore‐forming hydrothermal systems. However, quantifying their role in fluid flow on the scale of several kilometers with numerical models typically requires high‐resolution meshes. This study introduces a modified numerical representation of m‐scale fault zones using lower‐dimensional elements (here, one‐dimensional [1D] elements in a 2D domain) to resolve structurally controlled fluid flow with coarser mesh resolutions and apply the method to magmatic‐hydrothermal ore‐forming systems. We modeled horizontal and vertical structure‐controlled magmatic‐hydrothermal deposits to understand the role of permeability and structure connectivity on ore deposition. The simulation results of vertically extended porphyry copper systems show that ore deposition can occur along permeable vertical structures where ascending, overpressured magmatic fluids are cooled by downflowing ambient fluids. Structure permeability and fault location control the distribution of ore grades. In highly permeable structures, the mineralization can span up to 3 km vertically, resulting in heat‐pipe mechanisms that promote the ascent of a magmatic vapor phase to an overlying structurally controlled epithermal system. Simulations for the formation of subhorizontal vein‐type deposits suggest that the major control on fluid flow and metal deposition along horizontal structures is the absence of vertical structures above the injection location but their presence at greater distances. Using a dynamic permeability model mimicking crack‐seal mechanisms within the structures leads to a pulsating behavior of fracture‐controlled hydrothermal systems and prevents the inflow of ambient fluids under overpressured conditions.
    Description: Plain Language Summary: Faults and fractures can serve as permeable pathways for focused fluid flow in the subsurface and therefore be essential geological features for the formation of economic mineral deposits. However, quantifying their role in the hydrothermal systems on the scale of several kilometers with numerical models typically requires high‐resolution meshes. This study presents a modified numerical representation of m‐scale fault zones with variable orientations to understand the hydrology of magmatic‐hydrothermal ore‐forming systems. The vertically extended systems simulation results show that ore deposition can occur along permeable vertical structures where ascending magmatic fluids are cooled by downflowing ambient fluids. Structure permeability and fault location can directly control the distribution of ore grades. In contrast, mineralization in horizontal structures requires the absence of vertical structures above the injection location of metal‐bearing magmatic volatiles but their presence at greater distances. Our model also shows how dynamic opening and closing of the structures in response to magmatic degassing can lead to a pulsating behavior and prevent the downflow of ambient fluids.
    Description: Key Points: We describe structurally controlled fluid flow by representing faults and fractures as one‐dimensional line elements within a 2D modeling domain. Vertical structures are efficient pathways for focused fluid flow and formation of high‐grade mineralization. Ore formation in horizontal fractures requires a hydraulic connection to distal vertical fault zones.
    Description: German Federal Ministry of Education and Research
    Description: Deutsche Forschungsgemeinschaft, DFG http://dx.doi.org/10.13039/501100001659
    Description: Helmholtz Recruitment Initiative
    Keywords: ddc:551 ; magmatic‐hydrothermal systems ; ore deposits ; fluid flow ; numerical simulations ; faults and fractures
    Language: English
    Type: doc-type:article
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  • 13
    Publication Date: 2024-02-21
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The Mg/Ca of marine calcareous Planktic Foraminifera (PF) shells is commonly used for sea surface temperature reconstructions. However, compared to open marine environments, hypersaline (>40) oligotrophic seas have been shown to accommodate PF with higher Mg/Ca and divergent temperature to Mg/Ca relationships. To investigate influencing factors of PF Mg uptake in hypersaline regions, we measured the Mg/Ca of two flux‐dominating PF species, 〈italic〉Globigerinoides ruber albus〈/italic〉 and 〈italic〉Turborotalita clarkei〈/italic〉, derived from a monthly resolved time series of sediment traps in the Gulf of Aqaba, northern Red Sea as well as the corresponding temperature, salinity, and 〈italic〉p〈/italic〉H values. The PF exhibit elevated Mg/Ca which cannot be explained by post‐deposition or interstitial sediment diagenetic processes. 〈italic〉G. ruber albus〈/italic〉 displays Mg/Ca trends that strongly follow seasonal mixed layer temperature changes. Conversely, 〈italic〉T〈/italic〉. 〈italic〉clarkei〈/italic〉 Mg/Ca trends do not follow temperature but rather show significant Mg/Ca enrichment following mixing of the surface water column. We present a framework for incorporating elevated Mg/Ca into global Mg/Ca‐T calibrations for 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉 and present a new Mg/Ca‐T calibration suitable for hypersaline marine environments.〈/p〉
    Description: Plain Language Summary: Past seawater temperature is reconstructed from the magnesium‐to‐calcium ratio (Mg/Ca) in the calcareous shells of a group of marine microplankton called foraminifera. Two foraminifer species, 〈italic〉Globigerinoides ruber albus〈/italic〉 and 〈italic〉Turborotalita clarkei〈/italic〉, are abundant in the Gulf of Aqaba, northern Red Sea, at year‐round high temperatures and salinities. The shells of these foraminifera have elevated Mg/Ca relative to other marine regions, and here, we explore the factors causing this. The Mg/Ca values of both 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉 and 〈italic〉T〈/italic〉. 〈italic〉clarkei〈/italic〉 reflect the environmental conditions of the water column. For 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉, temperature and salinity appear to be factors responsible for the Mg/Ca trends and elevated values. We incorporate the new Mg/Ca data for 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉 to calibrate elevated Mg/Ca with temperature for high‐salinity (>40) marine environments. The Mg/Ca of the deeper dwelling 〈italic〉T〈/italic〉. 〈italic〉clarkei〈/italic〉 show higher ratios following deep mixing of the surface water column and may indicate annually recurring phytoplankton blooms caused by nutrient input into the sunlit ocean surface.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉A new Mg/Ca temperature calibration for high salinity environments is presented for 〈italic〉Globigerinoides ruber albus〈/italic〉〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉A framework for incorporating high salinity environments into global Mg/Ca‐T calibrations is provided〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Enhanced Mg/Ca in subsurface dwelling 〈italic〉Turborotalita clarkei〈/italic〉 may indicate seasonal deep mixing of the upper water column〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Israel Science Foundation http://dx.doi.org/10.13039/501100003977
    Description: Minerva PhD Fellowship Stipend
    Description: Advance School for Environmental Studies
    Description: https://doi.org/10.1594/PANGAEA.959629
    Description: https://doi.org/10.17617/3.EXFQC2
    Keywords: ddc:551.9 ; Gulf of Aqaba ; Planktic Foraminifera shells ; Mg/Ca ; sea surface temperature reconstructions
    Language: English
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  • 14
    Electronic Resource
    Electronic Resource
    Springer
    Marine biology 28 (1974), S. 261-263 
    ISSN: 1432-1793
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A single application of 100 parts per billion Sevin in seawater caused disruption of schooling behavior of Menidia menidia in an artificial setting. Although the change, primarily a spreading out of the school over a larger area, was observed after 24 h exposure, placing the fish in clean water did not bring about a return of normal schooling patterns until 72 h. This is attributed to the accumulation of 1-naphthol, a toxic product of hydrolysis of Sevin. The adaptive significance of changes in schooling behavior is discussed.
    Type of Medium: Electronic Resource
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  • 15
    ISSN: 1432-1793
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract We have previously found great differences in susceptibility to methylmercury (meHg) among batches of eggs produced by different females. This study compares the range and distribution of susceptibility in two populations of killifish, one from a creek in Montauk, New York, USA a rather pristine area, the other from Pile's Creek in Linden, New Jersey, an area heavily impacted by metal and oil pollution. After treatment with 0.05 ppm meHg, the distribution of craniofacial defects in embryos of the Montauk population ranged from very tolerant to very susceptible. The distribution of cardiovascular defects also ranged from very tolerant to very susceptible. Skeletal defects were prevalent in most batches of eggs. However, in the Pile's Creek population, very few females produced susceptible eggs, and most batches were tolerant with respect to the three types of malformations, especially the craniofacial defects. The ability to adapt to pollution is one reason that this species has remained abundant in such a highly polluted area. The ability of some species to adapt to chronic pollution by developing tolerance is a phenomenon that should be considered in choosing organisms for routine bioassay procedures, since the results will depend on the degree to which the population has become tolerant to the toxicant.
    Type of Medium: Electronic Resource
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  • 16
    ISSN: 0169-4758
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Medicine
    Type of Medium: Electronic Resource
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  • 17
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of fish biology 11 (1977), S. 0 
    ISSN: 1095-8649
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology
    Notes: When F. heteroclitus embryos were exposed to inorganic mercury at concentrations of 0.03 or 0.1 mg/1 at the early blastula stage, the percentage of successful axis formation was reduced and a significant proportion of embryos developed cyclopia or intermediate conditions leading to cyclopia. Treatment at the late blastula stage reduced the severity of the defects. Embryos which developed in lead at concentrations of 1 and 10 mg/1 were normal in appearance until hatching, at which time they exhibited lordosis or were unable to uncurl from the position they had while still inside the chorion. No significant effects of cadmium at concentrations up to 10 mg/1 were noted.
    Type of Medium: Electronic Resource
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  • 18
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of environmental contamination and toxicology 16 (1976), S. 197-202 
    ISSN: 1432-0800
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Type of Medium: Electronic Resource
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  • 19
    Electronic Resource
    Electronic Resource
    Springer
    Archives of environmental contamination and toxicology 17 (1988), S. 355-363 
    ISSN: 1432-0703
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Notes: Abstract Tolerance to mercury in two populations of the grass shrimpPalaemonetes pugio was examined at different stages of this animal's life cycle. One population came from a mercury-contaminated creek, Piles Creek (PC), near industrialized Linden, New Jersey. The other population came from a relatively clean area, Big Sheepshead Creek (BSC), near non-industrialized Tuckerton, New Jersey. Larval grass shrimp showed no significant difference between populations in terms of mortality in 0.01 mg/L HgCl2, although treated BSC larvae metamorphosed significantly (P 〈 0.05) more slowly than their respective control group. While no BSC larvae survived the 0.0125 mg/L methylmercuric chloride (meHg) treatment, PC larvae exposed to 0.0125 mg/L meHg survived as well as their controls, indicating enhanced tolerance to meHg in this population. Adult shrimp were exposed for 14 days to control, 0.025 mg/L meHg, 0.025 mg/L HgCl2, 0.05 mg/L meHg, or 0.05 mg/L HgCl2 PC shrimp were significantly (P 〈 0.05) more tolerant to both 0.025 mg/L meHg, and 0.025 mg/L HgCl2 than were the BSC adults. Polyacrylamide gel electrophoresis suggests that both populations of shrimp are capable of producing a metallothionein like protein (MT) in response to treatment with HgCl2; MT is found in higher levels in field-caught PC shrimp than in field-caught BSC shrimp. MT was not present in field-collected, viable eggs from either population.
    Type of Medium: Electronic Resource
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  • 20
    Electronic Resource
    Electronic Resource
    Springer
    Archives of environmental contamination and toxicology 20 (1991), S. 118-124 
    ISSN: 1432-0703
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Notes: Abstract The effects of chromated copper arsenate (CCA), used for treating wood in docks, pilings, and bulkheads, were studied in several estuarine organisms. Leaching of metals from treated wood into sea water was assayed by atomic absorption spectrophotometry. Fiddler crabs (Uca pugilator) were subjected to limb removal and were placed in containers with treated wood of various sizes or control wood. Limb regeneration rate was retarded in a dose-dependent fashion and mortality occurred with the treated wood, reaching 100% in the tank with the largest piece of wood. Embryos of the mummichog (Fundulus heteroclitus) were allowed to develop in culture dishes in which CCA-treated or untreated wood was soaking. Mortality was noted in the dishes with treated wood and to a smaller extent in those with untreated wood. Containers containing CCA-treated wood, control wood, or no wood were stocked first with the algaUlva lactuca, then snails (Nassarius obsoletus). Chlorophyll content of the algae was reduced with the treated wood within a few days, and snails with the treated wood became moribund and died within a few days. In the controls containing untreated wood or no wood, no such effects were seen. Studies with individual or combinations of two or three of the metals with snails and algae indicated that the copper was primarily responsible for the snail mortality and algal bleaching seen in the treated wood experiments. In all experiments, the toxicity of the wood decreased over time; when the experiments were repeated with the same pieces of wood, effects were diminished.
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