ALBERT

Notes: [Auszug] Argon from neutron-irradiated mineral separates and whole rock samples of a metamorphosed breccia (65015) from Apollo 16 has been analysed with a large number of gas extraction steps in order to obtain a high resolution in the apparent ages and to identify the gas released from different sources. ...

Notes: [Auszug] Micro-inclusions in diamonds from Zaire and Botswana differ in composition from the more common large inclusions of the peridotitic or eclogitic assemblages. These sub-micrometre inclusions resemble potassic magmas in their composition, but are enriched in H2O, ...

Notes: Abstract Initial 87Sr/86Sr and 143Nd/144Nd ratios of Phanerozoic granitoids and related intrusions of the New Zealand block display a mixing-type array indicative of the involvement in their sources of old continental crustal material, most likely of Proterozoic age.ɛ Sr(T) values range from −4 to +273 (87Sr/86Sr=0.7041–0.7233), while ɛ Nd(T) ranges from +2.7 to −11.0. Preexisting metasedimentary rocks have generally higher ɛ Sr and lower ɛ Nd (ranging to present-day values of +646 and −15.0, respectively), and, particularly for the Mesozoic intrusives, are isotopically appropriate mixing end-members. The widespread, early Paleozoic Greenland Group graywackes, which are derived from Proterozoic sources, are modeled as the source of the crustal end-member mixing with mantle-derived mafic magmas to produce the intrusive rocks. Four different types of models are applied to the isotopic and trace-element (Rb, Sr, Ba, REE) data: simple mixing; mixing with a partial melt of the metasedimentary rock, with or without isotopic equilibrium; and assimilation-fractional crystallization. Based on these models, some constraints may be applied on petrogenesis (e.g., the lack of high Rb concentrations points to the presence of biotite, and HREE depletion points to the presence of garnet); however, the models fail to adequately explain all the data. The New Zealand granitoids show similarities in isotopic character not only to rocks from offshore islands on the New Zealand block, but also to similar-aged granitoids in adjacent regions of Antarctica and Australia. This points to similarities in crustal character between continental blocks formerly proximal in Gondwanaland. We note an overall increase in ɛ Nd and decrease in ɛ Sr in felsic magmas from the Paleozoic to the Mesozoic to the Cenozoic in New Zealand, indicative of a decrease over time in the level of influence of recycled continental crust in subduction-related magmatism.

Notes: Abstract Young volcanic rocks from different sections of the Aleutian Islands-Alaska Peninsula Arc have been measured for 87Sr/86Sr, 143Nd/144Nd and some trace elements. We found the 143Nd/144Nd to be highly restricted in range (ɛ Nd=6 to 7) and low as compared to midocean ridge ba-salts (MORB). This indicates that the source of the Aleutian Arc magmas is different from MORB and remarkably isotopically homogeneous with respect to Nd. The range reported here for arc rocks is substantially smaller than found by other workers. However, the Sr isotope ratios vary considerably (ɛ Sr=−24 to −14). Those samples from small volcanic centers north of the main arc (second arc) are characterized by low ɛ Sr. Our data in combination with previous studies suggest that there are slight geochemical differences between discrete sections of the arc. The general uniformity of Nd isotope ratios are thought to be the surface expression of an efficient mixing or homogenization process beneath the arc plate, but which still causes a wide dispersion in Sr isotopic composition. To relate the arc rocks to the broader tectonic setting and to identify possible sources of arc magmas, measurements were done on volcanic and sedimentary rocks from the North Pacific/Bering Sea area. Alkali basalts from the back-arc islands St. George, Nunivak and St. Lawrence and alkali-rich tholeiites from the fore-arc have ɛ Nd=+4 to +9 and are correlated on the ɛ Sr-ɛ Nddiagram parallel to the mantle array but shifted to lower ɛ Sr. These samples are thought to be isotopically representative of the mantle transported to that region. A tholeiitic basalt from the Kamchatka Basin ocean floor (back-arc), however, yielded typical MORB values (ɛ Nd=10, ɛ Sr=−24). Composite sediment samples were made from DSDP cores in the Aleutian Abyssal Plain, Gulf of Alaska and the Alka Basin which represent mixtures of continentally and arc-derived materials. These composites have intermediate Nd isotopic (ɛ Nd= −2 and +2) and high Sr isotopic values (ɛ Sr=+9 and +37). These data show that possible source materials of the Aleutian Arc volcanics are isotopically different from and much more heterogeneous than the arc rocks themselves. On the basis of this study and of literature data, we developed a set of alternative models for volcanic arc magma generation, based on the restricted range in ɛ Nd and the wider range in ɛ Sr for arc rocks. Different isotopic and trace element characteristics found in different arcs or arc sections are explained by varying mixing proportions or concentrations in source materials. The basic observations require rather strict mixing ratios to obtain constant ɛ Nd. The preferred model is one where the melting of subducted oceanic crust is controlled by the amount of trapped sediment with the melting restricted to the upper part of the altered basaltic layer. Homogenization within the upper part of the oceanic crust is brought about by hydrothermal circulation attending dewatering of the slab during subduction and possibly some oxygen exchange of the magmas on ascent.

Notes: Abstract Sm-Nd whole-rock and mineral data for the Kings River ophiolite define two isochrons of 485±21 Ma and 285±45 Ma age with ε Nd (483)= +10.7±0.5 and εNd (285)= +9.9±1.1, respectively. The 483 Ma isochron is defined by samples of the main igneous construct. Samples from crosscutting diabase dikes and flaser gabbro sheets within the peridotite unit yield the 285 Ma isochron. The 483 Ma data provide the first evidence of lower Paleozoic oceanic crust in the Sierran ophiolite belt. New U-Pb analyses of zircons from a plagiogranite lying on the 483 Ma Sm-Nd isochron yield upper and lower intercepts with the concordia of 430 −60 +200 and 183±15 Ma. Published zircon ages have underestimated the primary age of the ophiolite by 200–300 m.y. due to the effects of polymetamorphism. The 483 Ma samples have initial 87Sr/86Sr=0.7023–0.7030, 206Pb/204Pb=17.14–17.82, 207Pb/204Pb=15.37–15.52, 208Pb/204Pb=36.80–37.38. The 285 Ma samples have similar initial 87Sr/86Sr, but more radiogenic Pb. The range in Sr and Pb compositions is probably due to introduction of radiogenic Sr and Pb during multiple post-emplacement metamorphic events. The high ε Nd, low 87Sr/86Sr, 206Pb/204Pb, 207Pb/204Pb, 208Pb/204Pb of the least disturbed samples are clearly diagnostic of a midocean ridge origin for the 483 Ma portion of the ophiolite. Igneous activity at 285 Ma is thought to have occurred in an arc or back-arc setting, or perhaps along a leaky transform. The initial ε Nd (483)=+10.7 is indistinguishable from that of the similar age Trinity Peridotite (Jacobsen et al. 1984). This value is the highest yet reported for the Mesozoic or Paleozoic depleted mantle and requires either a mantle source that was depleted ∼ 850 m.y. earlier than average or a source more highly depleted than average. Alternatively, if such values were more typical of the early Paleozoic mantle than is currently thought, then there has been little evolution of the depleted mantle over the last ∼ 500 m.y. This requires that the modern mantle has been refluxed by material with low εNd, such as continental crust.

Notes: Abstract We have measured shifts in the isotopic a bundances of Gd and Sm in soils from the Apollo 17 deep drill stem and calculated the neutron fluence from these measurements. The measurements show two well defined regions of nearly constant fluence: (1) a thick deep section with a very large neutron fluence, and (2) a thinner shallow region with a small fluence. This depth dependence is most plausibly described by a model of rapid accumulation in the last 100–200 m.y., the layered structure reflecting accumulations of isotopically homogeneous source material. This interpretation is compatible with a variety of other characteristics of the soils, including the spallation produced126Xe normalized to target element abundances. An alternative model of deposition, followed by irradiation without mixing, followed by shallow mixing will quantitatively describe the data. The model yields an age of 1.25 AE for the bottom of the drill stem. This model was rejected because of the implausible requirement that the soils from the drill stem be accumulated from a source of unirradiated material. The uniformity of various properties of soils provides criteria for defining major stratigraphic intervals in the drill stem which differ from those identified by the Preliminary Examination Team. Neutron fluences measured on shallow and deep soils from all lunar landing sites have been normalized to irradiation in an arbitrary standard chemical environment. We infer from histograms of the normalized fluences that there is a distinct difference in neutron fluence between shallow and deep samples which implies a general vertical stratification of neutron fluence in the lunar regolith. The regolith can be divided into three vertical regions: (1) a well mixed surface layer, ∼100 g cm−2 thick, with an average fluence of 2.3 × 1016 n cm−2, (2) a poorly mixed zone extending from 100 g cm−2 to at least 500 g cm−2 with an average fluence of 3.5 × 1016 n cm−2, and (3) a deep layer of lightly irradiated materials (〈1016 n cm−2). Analysis of this stratification, using a vertical mixing model, indicates that the probability of mixing to several hundred g cm−2 is comparable to the probability of mixing to several kg cm−2. This is in contrast to the depth-cratering rate models which have been inferred from crater size frequency distributions using a power law. Alternatively, this discrepancy can be resolved if the true157Gd capture rate is 1/3 of the value calculated by Lingenfelteret al. (1972). The most plausible interpretation is that vertical mixing models are not an adequate description of relatively rare deep cratering events which result in significant lateral heterogeneity and addition of unirradiated material to the lunar surface.