ISSN:
1573-9171
Keywords:
fullerene, iridium hydride complexes
;
configuration of complexes
;
coordination
;
regioselectivity
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The iridium hydride complex HIr(CO)(PPh3)3 reacts with fullerenes C60 and C70 yielding (η2-Cn)IrH(CO)(PPh3)2 (n = 60, 70) complexes. Their composition, configuration, and the position of the double bond coordinated with the metal atom in the fullerene moiety have been established by IR studies (comparison with deuterated analogs), and1H and31P NMR spectroscopy.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00697152
Permalink