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  • 11
    Publication Date: 2017-02-01
    Print ISSN: 0969-8043
    Electronic ISSN: 1872-9800
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Published by Elsevier
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  • 12
    Publication Date: 2021-02-01
    Description: Radon ( 222 Rn) and thoron ( 220 Rn) are two isotopes belonging to the noble gas radon ( sensu lato ) that is frequently employed for the geochemical surveillance of active volcanoes. Temperature gradients operating at subvolcanic conditions may induce chemical and structural modifications in rock-forming minerals and their related 222 Rn– 220 Rn emissions. Additionally, CO 2 fluxes may also contribute enormously to the transport of radionuclides through the microcracks and pores of subvolcanic rocks. In view of these articulated phenomena, we have experimentally quantified the changes of 220 Rn signal caused by dehydration of a zeolitized tuff exposed to variable CO 2 fluxes. Results indicate that, at low CO 2 fluxes, water molecules and hydroxyl groups adsorbed on the glassy surface of macro- and micropores are physically removed by an intermolecular proton transfer mechanism, leading to an increase of the 220 Rn signal. By contrast, at high CO 2 fluxes, 220 Rn emissions dramatically decrease because of the strong dilution capacity of CO 2 that overprints the advective effect of carrier fluids. We conclude that the sign and magnitude of radon ( sensu lato ) changes observed in volcanic settings depend on the flux rate of carrier fluids and the rival effects between advective transport and radionuclide dilution.
    Electronic ISSN: 2054-5703
    Topics: Natural Sciences in General
    Published by The Royal Society
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  • 13
    Publication Date: 2020-08-13
    Description: Estimating the quantity of CO2 diffusively emitted from the Earth’s surface has important implications for volcanic surveillance and global atmospheric CO2 budgets. However, the identification and quantification of non-hydrothermal contributions to CO2 release can be ambiguous. Here, we describe a multi-parametric approach employed at the Nisyros caldera, Aegean Arc, Greece, to assess the relative influence of deep and shallow gases released from the soil. In April 2019, we measured diffuse soil surface CO2 fluxes, together with their carbon isotope compositions, and at a depth of 80 cm, the CO2 concentration, soil temperature, and the activities of radon and thoron. The contributions of deep CO2 and biogenic CO2 fluxes were distinguished on the basis of their carbon isotope compositions. A Principal Component Analysis (PCA), performed on the measured parameters, effectively discriminates between a deep- and a shallow degassing component. The total CO2 output estimated from a relatively small testing area was two times higher with respect to that observed in a previous survey (October 2018). The difference is ascribed to variation in the soil biogenic CO2 production, that was high in April 2019 (a wet period) and low or absent in October 2018 (a dry period). Accounting for seasonal biogenic activity is therefore critical in monitoring and quantifying CO2 emissions in volcanic areas, because they can partially- or completely overwhelm the volcanic-hydrothermal signal.
    Electronic ISSN: 2045-2322
    Topics: Natural Sciences in General
    Published by Springer Nature
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  • 14
    Publication Date: 2021-02-02
    Description: In the frame of Radon rEal time monitoring System and Proactive Indoor Remediation (RESPIRE), a LIFE 2016 project funded by the European Commission, the contribution of building materials of volcanic origin to indoor radon concentration was investigated. First, total gamma radiation and related outdoor dose rates of geological materials in the Caprarola area (Central Italy) were measured to defi ne main sources of radiation. Second, Rn-222 and Rn-220 exhalation rates of these rocks used as building materials were measured using an accumulation chamber connected in a closed loop with a RAD7 radon monitor. Among others, the very porous “Tufo di Gallese” ignimbrite provided the highest values. This material was then used to construct a scale model room of 62 cm × 50 cm × 35 cm (inner length × width × height, respectively) to assess experimental radon and thoron activity concentration at equilibrium and study the effects of climatic conditions and different coatings on radon levels. A fi rst test was carried out at ambient temperature to determine experimental Rn-222 and Rn-220 equilibrium activities in the model room, not covered with plaster or other coating materials. Experimental Rn-222 equilibrium was recorded in just two days demonstrating that the room “breaths”, exchanging air with the outdoor environment. This determines a dilution of indoor radon concentration. Other experiments showed that inner covers (such as plasterboard and different kinds of paints) partially infl uence Rn-222 but entirely cut the short-lived Rn-220. Finally, decreases in ambient temperature reduce radon exhalation from building material and, in turn, indoor activity concentration.
    Description: This research was accomplished in the frame of RESPIRE, a LIFE 2016 project funded by the European Commission. GRANT AGREEMENT N. LIFE 16ENV/IT/000553
    Description: Published
    Description: 71-76
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Building materials ; Indoor radon ; Indoor thoron ; Model room ; Natural radiation ; Radon and thoron exhalation rates ; Using a scale model room to assess the contribution of building material of volcanic origin to indoor radon
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 15
    Publication Date: 2020-09-15
    Description: Naturally occurring 222Rn is increasingly recognized as a powerful environmental tracer in hydrology. Radon-in-water concentrations can be measured in the field by stripping radon from a water sample into a gas volume and measuring the respective radon-in-gas concentration using a portable radon-in-gas monitor. Alternatively, radon is firstly extracted from the water body by diffusion through a radon exchanger such as polypropylene (PP) tubing and then is measured using a radon-in-gas monitor, connected in closed-loop to the PP membrane. The paper discusses results of field experiments in which the Radon-in-Water Probe (Durridge co.), a 2.2 m long PP tubing, connected to a RAD7 monitor (method A), is used to determine dissolved radon concentration in four water bodies characterised by different water flow velocity and radon concentration. The efficiency of this method is validated by comparison with two established methods, gamma-ray spectrometer + charcoal canister (method B) and RAD7 monitor + Big Bottle RAD H20 accessory (method C). Relative efficiency of method A is directly proportional to water flow velocity, ranging from about 0.50 ± 0.05 at 0.01 m/s to about 0.92 ± 0.08 at 0.57 m/s. A minimum of 2–3 h are needed to collect enough records to asymptotically fit radon-in-gas data and obtain equilibrium radon concentration, which is then converted into radon-in water concentration, considering the temperature-dependency of radon partition coefficient between water and air. Equilibrium condition is reached after about 6–8 h. No correlation was found between relative efficiency and radon concentration. An equation is proposed to correct radon data as a function of water flow velocity, even for poorly moving water bodies. The DURRIDGE Water Probe is useful to monitor radon-in-water levels, without the potential risk of radon loss during water sampling and sample handling. However, it must be pointed out that duplicate or triplicate sampling using other methods similarly permit to evaluate whether radon loss is an issue.
    Description: Published
    Description: 106179
    Description: 2IT. Laboratori analitici e sperimentali
    Description: JCR Journal
    Keywords: Radon-in-water probe ; RAD7 ; Water flow ; Valle della Caffarella ; 05.06. Methods
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 16
    Publication Date: 2020-09-15
    Description: Geochemical and geophysical surveys employing radon deficit, resistivity, and induced polarization (IP) measurements were undertaken on soil contaminated with non-aqueous phase liquids (NAPLs) in two different sites in India and in Italy. Radon deficit, validated through the comparison with average soil radon in reference unpolluted areas, shows the extension of contamination in the upper part of the unsaturated aquifers. In site 1 (Italy), the spill is not recent. A residual film of kerosene covers soil grains, inhibiting their chargeability and reducing electrical resistivity difference with background unpolluted areas. No correlation between the two parameters is observed. Soil volatile organic compounds (VOCs) concentration is not linked with radon deficit, supporting the old age of the spillage. NAPL pollution in sites 2a and 2b (India) is more recent and probably still active, as demonstrated by higher values of electrical resistivity. A good correlation with IP values suggests that NAPL is still distributed as droplets or as a continuous phase in the pores, strengthening the scenario of a fresh spill or leakage. Residual fraction of gasoline in the pore space of sites 2a and 2b is respectively 1.5 and 11.8 kg per cubic meter of terrain. This estimation is referred to the shallower portion of the unsaturated aquifer. Electrical resistivity is still very high indicating that the gasoline has not been strongly degraded yet. Temperature and soil water content influence differently radon deficit in the three areas, reducing soil radon concentration and partly masking the deficit in sites 2a and 2b.
    Description: Published
    Description: 12515–12527
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 17
    Publication Date: 2021-01-07
    Description: Estimating the quantity of CO2 diffusively emitted from the Earth's surface has important implications for volcanic surveillance and global atmospheric CO2 budgets. However, the identification and quantification of non-hydrothermal contributions to CO2 release can be ambiguous. Here, we describe a multi-parametric approach employed at the Nisyros caldera, Aegean Arc, Greece, to assess the relative influence of deep and shallow gases released from the soil. In April 2019, we measured diffuse soil surface CO2 fluxes, together with their carbon isotope compositions, and at a depth of 80 cm, the CO2 concentration, soil temperature, and the activities of radon and thoron. The contributions of deep CO2 and biogenic CO2 fluxes were distinguished on the basis of their carbon isotope compositions. A Principal Component Analysis (PCA), performed on the measured parameters, effectively discriminates between a deep- and a shallow degassing component. The total CO2 output estimated from a relatively small testing area was two times higher with respect to that observed in a previous survey (October 2018). The difference is ascribed to variation in the soil biogenic CO2 production, that was high in April 2019 (a wet period) and low or absent in October 2018 (a dry period). Accounting for seasonal biogenic activity is therefore critical in monitoring and quantifying CO2 emissions in volcanic areas, because they can partially- or completely overwhelm the volcanic-hydrothermal signal.
    Description: Published
    Description: 13782
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 18
    Publication Date: 2021-02-22
    Description: Radon isotopes (222Rn, 220Rn) are noble, naturally occurring radioactive gases. They originate from the alpha decay of radium isotopes (226Ra, 224Ra), which occur in most materials in the environment, i.e. soil, rocks, raw and building materials. Radon is also found in ground and tap water. The two radon isotopes are chemically identical, but they have very different halflives: 3.82 days for radon (222Rn) and 56 seconds for thoron (220Rn). Thus, they behave very differently in the environment. Both isotopes are alpha-emitters; their decay products are polonium, bismuth and lead isotopes. The main source of radon in air (indoor or outdoor) is soil, where radon concentrations are very high and reach tens of Bq/m3. Radon release from soil into the atmosphere depends on radium (226Ra) concentration in soil, soil parameters (porosity, density, humidity) and weather conditions (e.g. air temperature and pressure, wind, precipitation). Outdoor radon concentrations are relatively low and change daily and seasonally. These changes may be used to study the movement of air masses and other climatic conditions. Radon gas enters buildings (homes, workplaces) through cracks, crevices and leaks that occur in foundations and connections between different materials in the building. This is due to temperature and pressure differences between indoors and outdoors. Indoor radon is the most important source of radiation exposure to the public, especially on ground floor. Radon and its decay products represent the main contributor to the effective dose of ionising radiation that people receive. Radon is generally considered as the second cause of increased risk of lung cancer (after smoking). The only way to assess indoor radon concentration is to make measurements. Different methods exist, but the most common one is to use track-etched detectors. Such detectors may be used to perform longterm (e.g. annual) measurements in buildings. The exposure time is important because indoor radon levels change daily and seasonally. Moreover, radon concentration shows a high spatial variation on a local scale, and is strongly connected with geological structure, building characteristics and ventilation habits of occupants. A European map of indoor radon concentration has been prepared and is displayed. It is derived from survey data received from 35 countries participating on a voluntary basis.
    Description: Published
    Description: 108-137
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Keywords: Radon ; European Map ; Indoor radon ; Radon detectors ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 19
    Publication Date: 2021-07-14
    Description: Fumaroles are a common manifestation of volcanic activity that are associated with large emissions of gases into the atmosphere. These gases originate from the magma, and they can provide indirect and unique insights into magmatic processes. Therefore, they are extensively used to monitor and forecast eruptive activity. During their ascent, the magmatic gases interact with the rock and hydrothermal fluids, which modify their geochemical compositions. These interactions can complicate our understanding of the real volcanic dynamics and remain poorly considered. Here, we present the first complete imagery of a fumarolic plumbing system using three-dimensional electrical resistivity tomography and new acoustic noise localization. We delineate a gas reservoir that feeds the fumaroles through distinct channels. Based on this geometry, a thermodynamic model reveals that near-surface mixing between gas and condensed steam explains the distinct geochemical compositions of fumaroles that originate from the same source. Such modeling of fluid interactions will allow for the simulation of dynamic processes of magmatic degassing, which is crucial to the monitoring of volcanic unrest.
    Description: Published
    Description: id 7580
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 20
    Publication Date: 2020-02-24
    Description: Glass bottles are generally employed for water sampling because glass is impervious to radon and is not lost during sample storage. On the other hand, glass is fragile and may break, so 1 L High Density PolyEthylene (HDPE) bottles (Thermo Scientific Nalgene) are tested in place of glass vessels employing Big Bottle RAD H2O device (Durridge Company) coupled with RAD7 monitor. The purpose of this calibration is to quantify radon loss during storage in HDPE bottles, evaluate possible radon uptake by known volume of desiccant (Drierite, granular CaSO4) and quantify radon interaction with the rubber and plastic parts of the experimental circuit. These processes have been separately investigated, performing proper experiments for the assessment of their influence on resulting radon data using seven series of solutions at known activity concentrations in the range from 27 to 194 Bq/L. Percent radon loss during storage in 1 L HDPE bottles has been estimated at 0.0045 min-1. Radon absorption by desiccant, expressed as ‘equivalent’ volume of Drierite is 0.673 ± 0.092 L and is somehow independent, within errors, from i) the amount of water already absorbed in Drierite, ii) a recirculation time greater than 30 min and iii) radon concentrations. Radon absorption/desorption from rubber and plastic parts of the experimental device has been assessed as a function of concentration gradient between the inner volume of the circuit and the pores of polymer's. A final algorithm accounting for the above described physical processes has been developed for long runs (2-3 h). A simplified calculation method for short measurements (30 min) is also provided.
    Description: Published
    Description: 1-7
    Description: 2IT. Laboratori analitici e sperimentali
    Description: JCR Journal
    Keywords: Radon ; Diffusion coefficient ; RAD7 monitor ; HDPE ; 05.04. Instrumentation and techniques of general interest
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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