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  • 11
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 110 (1999), S. 5814-5820 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We present data on time-resolved infrared spectroscopy of ethanol diluted in deuterated ethanol at two concentrations of 1 and 50 vol % and excitation within the OH-stretching band. Transient spectral holes with widths of 35–55 cm−1 and 25 cm−1, respectively, are determined as well as breaking of hydrogen bonds after vibrational excitation. The lifetime of the OH mode of associated ethanol depends on the strength of the H bond and varies between 〈1 ps and 1.5±0.5 ps. While at the lower concentration the thermal effect due to the deposited energy is negligible, the higher concentration results in a pronounced heating of the excited molecules. Two different relaxation mechanisms of the excited OH mode of associated ethanol are discussed. © 1999 American Institute of Physics.
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  • 12
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 107 (1997), S. 9759-9763 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We propose a detailed structural model for ethanol oligomers assuming it to form open chains. An inhomogeneous broadening with a width of about 100 cm−1 of the OH-stretching mode of the hydrogen-bonded species is considered, a parabolic increase of the absorption strength and a cubic dependency of the frequency of this vibration with position within the associate. With these asumptions we are able to account for the measured conventional IR absorption spectra of ethanol at different dilutions in CCl4 with the most probable length of the associates ranging between 2 and 13 molecules, respectively. Application of our model to time-resolved spectroscopy on a 0.17 M sample with excitation performed at 3340 cm−1 yields a length of the excited oligomers of 4 to 5 and of broken species of 2 to 3, respectively. © 1997 American Institute of Physics.
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  • 13
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 106 (1997), S. 8974-8980 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Hydrogen-bonded ethanol molecules in internal positions of oligomers are investigated in solutions of carbon tetrachloride (concentration 0.17 M). After resonant excitation of the OH-stretching vibration by a 2-ps infrared pump pulse at 3340 cm−1, transient spectral hole burning within the inhomogeneously broadened band is observed with a delayed, independently tunable probing pulse of 1 ps duration. Evidence is presented that the vibrational excitation migrates along the oligomer chain with subsequent breaking of H bonds so that additional ethanol dimers and trimers are formed. Correspondingly, the number of ethanol monomers or hydroxilic groups with proton acceptor function is found to increase. Several time constants describing the various processes, e.g., the proposed migration of vibrational quanta along the H bonded chain, breaking of hydrogen bonds, and the reassociation of the generated shorter species, are determined by a comparison of the experimental data with model computations. © 1997 American Institute of Physics.
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  • 14
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 81 (1997), S. 2818-2821 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report on the observation of two-photon absorption for the direct gap in intrinsic germanium at room temperature using two independently tunable picosecond, mid-infrared light pulses. The two-photon absorption coefficient is determined for different wavelengths, and carrier densities down to about 1013 cm−3 could be detected at a sample length of 700 μm. Two-photon absorption in germanium is demonstrated to be a versatile tool for zero-point determination in time resolved pump-probe investigations and permits a precise measure of the time resolution of the laser system. © 1997 American Institute of Physics.
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  • 15
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 111 (1999), S. 6869-6874 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We report on a novel investigation of the solvated electron with excitation into the continuum band. The subsequent localization process of quasifree electrons in neat water is studied by femtosecond probe spectroscopy in the spectral range between 580 nm and 990 nm. Excitation is achieved by a pump pulse at 310 nm promoting equilibrated solvated electrons to well-defined levels in the continuum band approximately 0.7 eV above the band edge. The subsequent retrapping and solvation of the electron occurs via two observed intermediates with time constants of τ2=300±50 fs and τs=1.0±0.2 ps. The absorption bands of the two intermediates are derived by the help of a 4-level energy scheme. Comparison with investigations of the solvated electron after excitation with 2 eV visible pulses gives strong evidence that the second intermediate in the UV-excitation experiment is identical to the modified ground state s″ occupied after excitation in the visible. The present study with excitation of the solvated electrons to continuum states sheds also new light on the generation process of localized electrons in neat water. Our data present strong evidence that the so-called "wet electron" is the solvated electron in a modified, hot ground state. © 1999 American Institute of Physics.
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  • 16
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Optics Communications 77 (1990), S. 226-230 
    ISSN: 0030-4018
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
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  • 17
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Optics Communications 101 (1993), S. 43-48 
    ISSN: 0030-4018
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
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  • 18
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Optics Communications 97 (1993), S. 41-46 
    ISSN: 0030-4018
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
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  • 19
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Water Resources Association 37 (2001), S. 0 
    ISSN: 1752-1688
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Architecture, Civil Engineering, Surveying , Geography
    Notes: : Rhodamine WT dye-tracer injections in rivers of the Willamette Basin yield concentration-time curves with characteristically long recession times suggestive of active transient storage processes. The scale of drainage areas contributing to the stream reaches studied in the Willamette Basin ranges from 10 to 12,000 km2. A transient storage assessment of the tracer studies has been completed using the U.S. Geological Survey's One-dimensional Transport with Inflow and Storage (OTIS) model, which incorporates storage exchange and decay functions along with the traditional dispersion and advection transport equation. The analysis estimates solute transport of the dye. It identifies first-order decay coefficients to be on the order of 10−5/sec for the nonconservative Rhodamine W.T. On an individual subreach basis, the first-order decay is slower (typically by an order of magnitude) than the transient storage process, indicating that nonconservative tracers may be used to evaluate transient storage in rivers. In the transient storage analysis, a dimensionless parameter (As/A) expresses the spatial extent of storage zone area relative to stream cross section. In certain reaches of Willamette Basin pool-and-riffle, gravel-bed rivers, this parameter was as large as 0.5. A measure of the storage exchange flux was calculated for each stream subreach in the simulation analysis. This storage exchange is shown subjectively to be higher at higher stream discharges. Hyporheic linkage between streams and subsurface flows is the probable physical mechanism contributing to a significant part of this inferred active transient storage. Hyporheic linkages are further suggested by detailed measurements of river discharge with an Acoustic Doppler Current Profiler system delineating zones in two large rivers where water alternately enters and leaves the surface channels through gravel-and-cobble riverbeds. Measurements show patterns of hyporheic exchange that are highly variable in time and space.
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  • 20
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Physics Letters B 321 (1994), S. 254-258 
    ISSN: 0370-2693
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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