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  • 11
    ISSN: 1573-9139
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Conclusions A systematic study of the strength characteristics of an alumina cement with certain plasticizer and mineral additions was conducted. It was shown that sodium polyphosphate and calcium chromelignosulfonate act as intense plasticizers in the alumina cement facilitating reduction of mixed water up to 15–20%. It was established that the plasticizing additions help in increasing the strength of cement. Based on thermographic, x-ray, petrographic, and electron microscopic studies, the products (results) of hydration of the high-alumina cement and their relationship with the degree of strengthening were established. It was shown that the cement containing calcium chromelignosulfonate preserves the high strength of the aluminosilicate refractory concrete during heating up to 1000°C.
    Type of Medium: Electronic Resource
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  • 12
    ISSN: 1573-9139
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Conclusions At the Chasov Yar refractories combine we developed and introduced a technology for the production of chamotte kaolin refractories with a porosity of not more than 12% and a mass proportion of not less than 42% Al2O3 on the basis of chamotte from high-grade Polozhe kaolin, and also additions to the batch of finely milled mullite-corundum chamotte. Using the new technology we produced a batch of goods designated ShPD-42 for lining the shafts, bosh, and upper parts of blast furnaces of large capacity.
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    Springer
    Refractories and industrial ceramics 35 (1994), S. 184-188 
    ISSN: 1573-9139
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Formation of a combined nitride-containing binder for mullite-alumina refractories is studied. An optimal combination is found to consist of 80% crystalline silicon, 10% silicon carbide, and 10% aluminum, magnium, or zirconium oxide. Mullite-alumina refractories with selected binders showed high resistance to the effects of slag, alkali, and iron.
    Type of Medium: Electronic Resource
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  • 14
    Electronic Resource
    Electronic Resource
    Springer
    Refractories and industrial ceramics 32 (1991), S. 558-563 
    ISSN: 1573-9139
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Conclusions The reported results form a part of the complex investigations carried out at the Ukrainian Scientific-Research Institute of Refractories on the structure evolution processes in the polycrystalline fibers based on zirconium dioxide. Using the methods of x-ray phase analysis, petrographic analysis, and electron microscopy, we studied the phase formation in the polycrystalline ZrO2 fibers of three systems (additiveless ZrO2, CaO-containing ZrO2, and Y2O3-containg ZrO2) in the 1000–1500°C range. It was established that the additiveless zirconium dioxide fibers are represented by the monoclinic ZrO2 and that at 1400°C, their strength decreases due to a significant change in the volume of the unit cells (as a result of the tetragonal-monoclinic transformation). A study of the phase composition of the ZrO2-Y2O3 and the ZrO2-CaO fibers established that the structure of the fibers of the former system contains a large quantity of the tetragonal phase and finer crystals. After the second firing at 1500°C, the monoclinic phase of ZrO2 appears during the cooling process; its quantity depends on the resistance offered by the solid solutions to the eutectoid decomposition and increases with increasing temperature of the initial technological firing. The presence of significant quantities of the monoclinic phase of ZrO2 leads to destructive changes in the fibers and to an increased additional shrinkage of the material at 1500°C. The minimum content of the monoclinic ZrO2 and the finer structure (smaller grain size) are observed in the Y2O3-stabilized zirconium dioxide fibers that were fired in advance at 1200°C.
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  • 15
    ISSN: 1573-9139
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Conclusions Impregnation of blast-furnace aluminosilicate refractories with carbon-containing substance makes their structure more compact and greatly enhances the quality. The open porosity of the impregnated specimens decreases by 42–47 rel.%, the gas permeability is reduced, the compressive stress (in the cold) is increased by a factor of 1.5–2, the onset temperature of deformation under a load of 2 kgf/cm2 is raised by 50–100°C, the slag resistance is increased by a factor of 2–4 (depending on the amount of coke residue), the alkali resistance is enhanced owing to the presence of coke residue, which, by blocking off the chamotte grains from the active reagents (K2O, Na2O), promotes formation of more refractory mineral compositions in the form of large crystals of mullite andβ-alumina, cemented by refractory glass of presumably nepheline composition. This enhancement of the refractory properties as a result of impregnation with carbon-containing substance will increase the resistance of the lining of the lower stack and the bosh of blast furnaces.
    Type of Medium: Electronic Resource
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  • 16
    Electronic Resource
    Electronic Resource
    Springer
    Powder metallurgy and metal ceramics 15 (1976), S. 96-99 
    ISSN: 1573-9066
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Conclusions 1. Milling in a planetary mill raises the level of crystal lattice microdistortions in chromium oxide powder, reduces the particle size of the powder, and breaks up its mosaic blocks. The kinetics of the variation of the particle and block sizes is characterized by saturation. 2. Fine crystal structure defects are annealed out in the temperature range 900–1100°C. Marked densification of chromium oxide during calcining in a reducing atmosphere begins at 1300°C. 3. Milling as a means of activation substantially improves the sintering of Cr2O3 powders at temperatures of 1500–1600°C. For activated chromium oxide powders a correlation is found between the degree of sintering and the level of structural defectiveness.
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