ISSN:
0025-116X
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
A preliminary investigation on the influence of the coagulation process on the solid-phase structure of poly(1,3,4-oxadiazole-2,5-diyl-1,4-phenylene) (1) is reported. Interesting correlations between the method of coagulation of the polymer from sulfuric acid solution and the structure which develops, as observed by thermal analysis, X-ray diffraction, infrared spectroscopy, and optical microscopy are found. A new method for the preparation of highly crystalline spherulites of 1 is described. This method allows to grow a relatively large number of “single spherulites”, because coagulation and crystallization induced by a non-solvent may be stopped before impingements occur.
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/macp.1990.021911103
Permalink