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  • 11
    Electronic Resource
    Electronic Resource
    Cellulose hydrolysis after combined action of high pressure and shear deformation (1987)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 34 (1987), S. 677-687 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1987.070340221
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  • 12
    Electronic Resource
    Electronic Resource
    A new process for fabricating nonwoven fibrous-reinforced elastomer composites (1992)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 45 (1992), S. 1693-1704 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new type of mold was developed and tested for structural reaction injection molding (SRIM) of elastomer composites having polymer matrices made from a mixture of two components. These mixtures had short pot lives and relatively high viscosity. Channel systems for polymer feeding and vacuum application were investigated. The mold cavity was provided with up to 24 polymer feeding holes and 38 vacuuming holes. The cavity and channels were made from transparent materials that allowed easy observation and video recording of the polymer matrix flow. In addition, some design parameters were studied such as channel layout. Investigations were carried out on the mechanism of polymer matrix flow and fiber breakage during the formation of fiber-reinforced composites made of non-woven fiber reinforcement structures with considerably longer fiber lengths than reported earlier. Other studies included determination of the effects of fiber type, fiber dimensions, and fiber/matrix v/v ratio on the matrix flow during impregnation. © 1992 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1992.070451002
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  • 13
    Electronic Resource
    Electronic Resource
    Environmental stress crack growth in medium-density polyethylene pipe (1981)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 26 (1981), S. 1049-1056 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1981.070260327
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  • 14
    Electronic Resource
    Electronic Resource
    A new process for fabricating nonwoven fibrous-reinforced elastomer composites (1992)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 46 (1992), S. 375-375 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1992.070460219
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  • 15
    Electronic Resource
    Electronic Resource
    Continuous extrusion of high-modulus semicrystalline polymers (1981)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 26 (1981), S. 395-409 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A process has been developed by which very high-modulus semicrystalline polymer films can be extruded continuously from a melt. This is accomplished by controlled cooling of the melt in a two-stage flow channel. A temperature gradient along the flow channel quenches the melt prior to an area reduction in which the polymer undergoes solid-state orientation. Analysis of high-density polyethylene tapes extruded by this process shows that they have properties similar to samples hydrostatically extruded at 120°C. Infrared analysis was used to determine both the degree of crystallinity and degree of orientation in these tapes as well as previously prepared hydrostatically extruded samples.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1981.070260202
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  • 16
    Electronic Resource
    Electronic Resource
    Fabrication methods for latex-based elastomer composites reinforced with long discontinuous fibers (1992)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 44 (1992), S. 263-277 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Rubber- or elastomer-based composites have so far been reinforced with randomly dispersed staple fibers of very short lengths. In this work, methods have been devised to produce composites where the dispersed fibers have considerably greater lengths. This achievement was possible by applying the rubber or elastomer as latex when mixing it with the fibers. As compared with earlier processes, the viscosity is considerably lower, thus permitting easier mixing so that longer staple fibers can readily be used.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1992.070440211
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  • 17
    Electronic Resource
    Electronic Resource
    Functional groups and degradation of cotton oxidized by hypochlorite (1962)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 58 (1962), S. 1023-1037 
    Details
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Functional groups and degradation of cotton oxidized by hypochlorite at several pH values in the range 5-10 were studied. The carboxyl group content of the oxidized cottons increases, while the aldehyde and ketone group contents decrease with increase in pH. Approximately 40% of the oxidant consumed is accounted for by the functional groups at all pH values. The ratio of carboxyl, aldehyde, and ketone groups formed per scission is 1-1.5:3:3.5 at the acidic pH range and 5:0.8:0.0 at pH 10. Oxygen consumption per scission is 26 atoms, out of which 10.4 atoms are accounted for by the functional groups. The rest of the oxygen is explained by oxidation of the soluble products of the short chain material in the fiber phase and by the functional groups of the short chains with D.P. up to 37. The degradation was found to be random at the whole pH range studied, as proved by the ratio of the number-average and weight-average molecular weights and by the linearity of the plot of log [η] vs. log (Oc + Oc0) where Oc is the oxygen consumed and Oco a constant. It is suggested that the degradation and oxidation reactions occur simultaneously and, at a given pH, with similar rates, so that all carbon atoms of an anhydroglucose unit in all chains of the amorphous phase will have a similar probability of being attacked.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1962.1205816663
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  • 18
    Electronic Resource
    Electronic Resource
    Studies on the chemical syntheses and on the characteristics of polyaniline derivatives (1995)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 33 (1995), S. 1227-1234 
    Details
    ISSN: 0887-624X
    Keywords: polyanilines ; derivatives ; chemical synthesis ; oxidation state ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Syntheses of parent polyaniline and methyl, methoxy, and ethoxy ortho-substituted polyanilines were performed using the conventional chemical methodology and monitored using the new open-circuit-potential (Voc) profile technique. The intermediate pernigraniline oxidation state was identified and isolated at the Voc maximum (A) during the conventional chemical synthesis of poly(o-methoxyaniline) in the emeraldine oxidation state. The introduction of the substituent on the aniline ring leads to longer polymerization times and lower Voc values. Syntheses in the presence of two different monomers in solution were also investigated and showed preferential polymerization of the monomer with the lowest Voc potential. All polymers produced were characterized by elemental analysis, gel permeation chromatography, UV-VIS spectroscopy, and cyclic voltammetry. The influence of the substituent on the Voc profile and on the polymer characteristics are rationalized in terms of steric and electronic effects. © 1995 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1995.080330805
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  • 19
    Electronic Resource
    Electronic Resource
    Magnetic field induced reversed (Negative) magnetization for electrochemically deposited Tc = 260 K Oxidized Films of Chromium Cyanide MagnetsWe gratefully acknowledge support from the US National Science Foundation, Grant no. CHE-9320478, Department of Energy, Division of Materials Science, Grant no. DE-FG02-86ER45271.A000, Department of Energy, Division of Advanced Energy Projects, Grant no. DE-FG02-96ER12198, and the Office of Naval Research. (1997)
    Weinheim : Wiley-Blackwell
    Advanced Materials 9 (1997), S. 645-647 
    Details
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/adma.19970090812
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  • 20
    Electronic Resource
    Electronic Resource
    Kinetics of irreversible dissociation for proteins bound cooperatively to DNA (1984)
    New York : Wiley-Blackwell
    Biopolymers 23 (1984), S. 1249-1259 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: We consider the irreversible dissociation kinetics of proteins that bind cooperatively and nonspecifically to DNA. Our model consists of an infinitely long one-dimensional nucleic acid lattice on which are bound protein ligands. A set of adjacent bound proteins forms a cluster of length n. A protein molecule may dissociate from any site within the bound cluster, not only from the ends, as was assumed in a previous model of this process due to Lohman [(1983) Biopolymers 22, 1697-1713]. By considering this additional pathway, we present a more general treatment of the dissociation kinetics of cooperatively bound ligands. We show that dissociation from the (n-2) internal positions of an n-cluster is an important pathway when the initial fractional saturation of the lattice is close to unity and the co operatively is low. When the fractional saturation is initially equal to 1 and the co operatively is low, our model does not give the zero-order dissociation kinetics predicted by the Lohman model.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.360230709
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