ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Contributions to the Chemistry of Transition Metal Alkyl Compounds. XII. On Attempts to prepare Benzyl Compounds of Nickel, Cobalt, and IronReport about attempts to prepare benzyl compounds of nickel, cobalt and iron by reactions of halides of these metals, triaryl and trialkylphosphine complexes of nickel and cobalt halides, bis(cyclooctadiene-1,5)nickel and tetrakis(triphenylphosphine)-nickel with several benzylating agents. In the course of some reactions the intermediate formation of instable benzyl compounds seems to occur, but an isolation failed in each case.
Notes:
Bericht über Versuche zur Benzylierung von Nickel-, Kobalt-und Eisenhalogeniden, Triaryl- und Trialkylphosphinkomplexen von Nickel- und Kobalthalogeniden, Nickel-bis-cyclooctadien und Nickeltetrakis-triphenylphosphin mit verschiedenen Benzylierungsreagenzien. Bei einigen der Reaktionen erfolgte offensichtlich intermediär die Bildung instabiler Benzylmetallverbindungen, doch gelang in keinem Falle deren Isolierung.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19734020210
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