ALBERT

Description: ZnO nanorods (NRs) with an average length and diameter of 186 and 20 nm, respectively, were prepared through a mild solvothermal route and used as photocatalysts either as dispersed powder or immobilized on glass slides. The ZnO NRs were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). Dispersed ZnO NRs and, to a lesser extent, immobilized ZnO NRs were demonstrated to exhibit high photocatalytic activity under simulated sunlight of low intensity (5.5 mW/cm2) both for the degradation of the Orange II dye and for Escherichia coli bacterial decontamination (2.5-fold survival decrease after 180 min irradiation for immobilized NRs). SEM, atomic force microscopy (AFM), fluorescence spectroscopy, and epifluorescence microscopy demonstrate that cell surface damages are responsible of bacterial inactivation. The immobilized ZnO NRs could be reused up to five times for bacterial decontamination at comparable efficiency and therefore have great potential for real environmental applications.

Description: The Multi-angle Imaging SpectroRadiometer (MISR) sensor onboard the Terra satellite provides high accuracy albedo products. MISR deploys nine cameras each at different view angles, which allow a near-simultaneous angular sampling of the surface anisotropy. This is particularly important to measure the near-instantaneous albedo of dynamic surface features such as clouds or sea ice. However, MISR’s cloud mask over snow or sea ice is not yet sufficiently robust because MISR’s spectral bands are only located in the visible and the near infrared. To overcome this obstacle, we performed data fusion using a specially processed MISR sea ice albedo product (that was generated at Langley Research Center using Rayleigh correction) combining this with a cloud mask of a sea ice mask product, MOD29, which is derived from the MODerate Resolution Imaging Spectroradiometer (MODIS), which is also, like MISR, onboard the Terra satellite. The accuracy of the MOD29 cloud mask has been assessed as 〉90% due to the fact that MODIS has a much larger number of spectral bands and covers a much wider range of the solar spectrum. Four daily sea ice products have been created, each with a different averaging time window (24 h, 7 days, 15 days, 31 days). For each time window, the number of samples, mean and standard deviation of MISR cloud-free sea ice albedo is calculated. These products are publicly available on a predefined polar stereographic grid at three spatial resolutions (1 km, 5 km, 25 km). The time span of the generated sea ice albedo covers the months between March and September of each year from 2000 to 2016 inclusive. In addition to data production, an evaluation of the accuracy of sea ice albedo was performed through a comparison with a dataset generated from a tower based albedometer from NOAA/ESRL/GMD/GRAD. This comparison confirms the high accuracy and stability of MISR’s sea ice albedo since its launch in February 2000. We also performed an evaluation of the day-of-year trend of sea ice albedo between 2000 and 2016, which confirm the reduction of sea ice shortwave albedo with an order of 0.4–1%, depending on the day of year and the length of observed time window.

Description: Elderly Bedouin men in southern Israel are a unique traditional population living in remote unrecognized villages and experiencing rapid social transition, in addition to deep poverty and political tension. In this study, we aimed to explore stressful events, as self-defined by the participants, and the ways in which these men have coped with those stressful events. This study involved 12 men, aged 69–74, who participated in in-depth narrative interviews during which they were asked about transformative stressful events in their lives and how they had managed, understood, and utilized human capital, meaning-making, and other methods of coping. Analysis of the interviews revealed several themes: (a) the definition of stressful events within the cultural context, (b) the use of human capital to overcome those events, (c) the transformation of experience from hindsight into a didactic narrative that can be used to assign meaning to past events, which can then be passed on to the next generation, and (d) cultural transition as a catalyst for the creation of new understandings of events. This paper sheds new light on how elderly indigenous Bedouin men self-define stressful situations within a complex and unstable cultural context. This specific context, can help us to gain insight into how indigenous impoverished older men in similar contexts may self-define their stress and coping, based on the types of generalization accepted in qualitative research. The methodological contribution of this work lies in its use of narrative to culturally contextualize phenomenological meaning structures. Its theoretical contribution lies in its examination of the concept of stress within a specific cultural context.

Description: Stochastic optimisation in Riemannian manifolds, especially the Riemannian stochastic gradient method, has attracted much recent attention. The present work applies stochastic optimisation to the task of recursive estimation of a statistical parameter which belongs to a Riemannian manifold. Roughly, this task amounts to stochastic minimisation of a statistical divergence function. The following problem is considered: how to obtain fast, asymptotically efficient, recursive estimates, using a Riemannian stochastic optimisation algorithm with decreasing step sizes. In solving this problem, several original results are introduced. First, without any convexity assumptions on the divergence function, we proved that, with an adequate choice of step sizes, the algorithm computes recursive estimates which achieve a fast non-asymptotic rate of convergence. Second, the asymptotic normality of these recursive estimates is proved by employing a novel linearisation technique. Third, it is proved that, when the Fisher information metric is used to guide the algorithm, these recursive estimates achieve an optimal asymptotic rate of convergence, in the sense that they become asymptotically efficient. These results, while relatively familiar in the Euclidean context, are here formulated and proved for the first time in the Riemannian context. In addition, they are illustrated with a numerical application to the recursive estimation of elliptically contoured distributions.

Description: The purpose of this article is to obtain the exact and approximate numerical solutions of linear and nonlinear singular conformable pseudohyperbolic equations and conformable coupled pseudohyperbolic equations through the conformable double Laplace decomposition method. Further, the numerical examples were provided in order to demonstrate the efficiency, high accuracy, and the simplicity of present method.

Description: Surface albedo is of crucial interest in land–climate interaction studies, since it is a key parameter that affects the Earth’s radiation budget. The temporal and spatial variation of surface albedo can be retrieved from conventional satellite observations after a series of processes, including atmospheric correction to surface spectral bi-directional reflectance factor (BRF), bi-directional reflectance distribution function (BRDF) modelling using these BRFs, and, where required, narrow-to-broadband albedo conversions. This processing chain introduces errors that can be accumulated and then affect the accuracy of the retrieved albedo products. In this study, the albedo products derived from the multi-angle imaging spectroradiometer (MISR), moderate resolution imaging spectroradiometer (MODIS) and the Copernicus Global Land Service (CGLS), based on the VEGETATION and now the PROBA-V sensors, are compared with albedometer and upscaled in situ measurements from 19 tower sites from the FLUXNET network, surface radiation budget network (SURFRAD) and Baseline Surface Radiation Network (BSRN) networks. The MISR sensor onboard the Terra satellite has 9 cameras at different view angles, which allows a near-simultaneous retrieval of surface albedo. Using a 16-day retrieval algorithm, the MODIS generates the daily albedo products (MCD43A) at a 500-m resolution. The CGLS albedo products are derived from the VEGETATION and PROBA-V, and updated every 10 days using a weighted 30-day window. We describe a newly developed method to derive the two types of albedo, which are directional hemispherical reflectance (DHR) and bi-hemispherical reflectance (BHR), directly from three tower-measured variables of shortwave radiation: downwelling, upwelling and diffuse shortwave radiation. In the validation process, the MISR, MODIS and CGLS-derived albedos (DHR and BHR) are first compared with tower measured albedos, using pixel-to-point analysis, between 2012 to 2016. The tower measured point albedos are then upscaled to coarse-resolution albedos, based on atmospherically corrected BRFs from high-resolution Earth observation (HR-EO) data, alongside MODIS BRDF climatology from a larger area. Then a pixel-to-pixel comparison is performed between DHR and BHR retrieved from coarse-resolution satellite observations and DHR and BHR upscaled from accurate tower measurements. The experimental results are presented on exploring the parameter space associated with land cover type, heterogeneous vs. homogeneous and instantaneous vs. time composite retrievals of surface albedo.

Description: Langmuir DOI: 10.1021/acs.langmuir.6b01241

Description: Langmuir DOI: 10.1021/acs.langmuir.5b02857

Description: Energy & Fuels DOI: 10.1021/acs.energyfuels.6b00208

Description: ACS Sustainable Chemistry & Engineering DOI: 10.1021/acssuschemeng.6b01659