ALBERT

Description: Relict dune fields that are found as far south as 14° N in the modern-day African Sahel are testament to equatorward expansions of the Sahara desert during the Late Pleistocene. However, the discontinuous nature of dune records means that abrupt millennial-timescale climate events are not always resolved. High-resolution marine core studies have identified Heinrich stadials as the dustiest periods of the last glacial in West Africa although the spatial evolution of dust export on millennial timescales has so far not been investigated. We use the major-element composition of four high-resolution marine sediment cores to reconstruct the spatial extent of Saharan-dust versus river-sediment input to the continental margin from West Africa over the last 60 ka. This allows us to map the position of the sediment composition corresponding to the Sahara–Sahel boundary. Our records indicate that the Sahara–Sahel boundary reached its most southerly position (13° N) during Heinrich stadials and hence suggest that these were the periods when the sand dunes formed at 14° N on the continent. Heinrich stadials are associated with cold North Atlantic sea surface temperatures which appear to have triggered abrupt increases of aridity and wind strength in the Sahel. Our study illustrates the influence of the Atlantic meridional overturning circulation on the position of the Sahara–Sahel boundary and on global atmospheric dust loading.

Description: Relict dune fields that are found at 14° N in the modern-day African Sahel are testament to equatorward expansions of the Sahara desert during the late Pleistocene. However, difficulties of dating dune formation mean that abrupt millennial-scale climate events are not always resolved in these records. High-resolution marine core studies have identified Heinrich Stadials as the dustiest periods of the last glacial, although no studies have mapped the spatio-temporal evolution of dust export from West Africa. We use the major-element composition of four marine sediment cores to reconstruct the spatial extent of Saharan-dust versus river-sediment input to the continental margin from West Africa over the last 60 ka. This allows us to map the position of the sediment composition corresponding to the Sahara-Sahel boundary. Our records indicate that the Sahara-Sahel boundary reached its most southerly position (13° N) during Heinrich Stadials, suggesting that these were the periods when the sand dunes formed at 14° N on the continent, rather than at the Last Glacial Maximum. We find that SSB position was closely linked to North Atlantic sea surface temperatures, which during Heinrich Stadials triggered abrupt increases of aridity and wind strength in the Sahel, exposing new dust sources. This result illustrates the influence of the Atlantic meridional overturning circulation on the southerly extent of the Sahara desert and has implications for global atmospheric dust loading.

Description: This paper, developed under the framework of the RECCAP initiative, aims at providing improved estimates of the carbon and GHG (CO2, CH4 and N2O) balance of continental Africa. The various components and processes of the African carbon and GHG budget were considered, and new and available data derived by different methodologies (based on inventories, ecosystem fluxes, models, and atmospheric inversions) were integrated. The related uncertainties were quantified and current gaps and weakness in knowledge and in the monitoring systems were also considered in order to provide indications on the future requirements. The vast majority of the results seem to agree that Africa is probably a small sink of carbon on an annual scale, with an average value of −0.61 ± 0.58 Pg C yr−1. Nevertheless the emissions of CH4 and N2O may turn Africa into a source in terms of CO2 equivalents. At sub-regional level there is a significant spatial variability in both sources and sinks, mainly due to the biome's differences and the different anthropic impacts, with southern Africa as the main source and central Africa, with its evergreen tropical forests, as the main sink. Emissions from land use change in Africa are significant (around 0.32 ± 0.05 Pg C yr−1) and even higher than the fossil fuel ones; this is a unique feature among all the continents. In addition there can be significant carbon losses from land even without changes in the land use (forest), as results from the impact of selective logging. Fires also play a significant role, with 1.03 ± 0.22 Pg C yr−1 of carbon emissions, mainly (90%) originated by savanna and woodland burning. But whether fire carbon emissions are compensated by CO2 uptake during the growing season, or are a non-reversible loss of CO2, remains unclear. Most of these figures are subjected to a significant interannual variability, on the order of ± 0.5 Pg C yr−1 in standard deviation, accounting for around 25% of the year-to-year variation in the global carbon budget. These results, even if still highly uncertain, show the important role that Africa plays in the carbon cycle at global level, both in terms of absolute values and variability.

Description: Silica, SiO2, in dissolved (DSi) and particulate (PSi) form, is both a major product of continental weathering as well as an essential nutrient in terrestrial and aquatic systems. Here we present estimates of the spatial distribution of riverine silica fluxes under natural conditions, i.e. without human influence, to ~140 segments of the global coastal zone. Focussing on the construction of the DSi budget, natural DSi concentration is multiplied with discharge of rivers for each segment for documented basins and segments. Segments with no documentation available are estimated using clustered information based mainly on considerations of local lithology, climate, and lake retention. We approximate fluxes of particulate silica in various forms (PSi) from fluxes of suspended matter, calculated from existing models. Results have been established for silica fluxes, concentrations and yields for drainage basins of the different continents, oceans basins as well as coastal segment basins. For the continental surfaces actually draining into the oceans (exorheic regions, representing 114.7 M km2), 371 M t y−1 of DSi and 8835 M t y−1 of PSi are transported, corresponding to a mean concentration of 9.5 mg l−1 and 226 mg l−1, and to a mean yield of 3.3 t km−2 y−1 and 77 t km−2 y−1, respectively. DSi yields exceeding 6.6 t km−2 y−1, i.e. 〉2× the global average, represent 17.4% of the global continental ice-free exorheic area but correspond to 56.0% of DSi fluxes. Pacific catchments hold most of the hyper-active areas (〉5× global average), suggesting a close connection between tectonic activity and DSi fluxes resulting from silicate weathering. The macro-filters of regional and marginal seas intercept 33% and 46% of the total dissolved and particulate silica fluxes.

Description: This regional study quantifies the CO2 exchange at the air–water interface along the land-ocean aquatic continuum (LOAC) of the North East American coast, from streams to the shelf break. Our analysis explicitly accounts for spatial and seasonal variability in the CO2 fluxes. The yearly integrated budget reveals the gradual change in the intensity of the CO2 exchange at the air–water interface, from a strong source towards the atmosphere in streams and rivers (3.0 ± 0.5 Tg C yr−1) and estuaries (0.8 ± 0.5 Tg C yr−1) to a net sink in continental shelf waters (−1.7 ± 0.3 Tg C yr−1). Significant differences in flux intensity and their seasonal response to climate variations is observed between the North and South sections of the study area, both in rivers and coastal waters. Ice cover, snow melt and estuarine surface area are identified as important control factors of the observed spatio-temporal variability in CO2 exchange along the LOAC.

Description: The quantification of emissions of the greenhouse gas methane is essential for attributing the roles of anthropogenic activity and natural phenomena in global climate change. Our current measurement systems and networks whilst having improved during the last decades, are deficient in many respects. For example, the emissions from localised and point sources such as landfills or fossil fuel exploration sites are not readily assessed. A tool developed to better understand point sources of the greenhouse gases carbon dioxide and methane is the optical remote sensing instrument MAMAP, operated from aircraft. After a recent instrument modification, retrievals of the column averaged dry air mole fractions for methane XCH4 (or for carbon dioxide XCO2) derived from MAMAP data, have a precision of about 0.4% or better and thus can be used to infer emission rate estimates using an optimal estimation inverse Gaussian plume model or a simple integral approach. CH4 emissions from two coal mine ventilation shafts in Western Germany surveyed during the AIRMETH 2011 measurement campaign are used as examples to demonstrate and assess the value of MAMAP data for quantifying CH4 from point sources. While the knowledge of the wind is an important input parameter in the retrieval of emissions from point sources and is generally extracted from models, additional information from a turbulence probe operated on-board the same aircraft was utilised to enhance the quality of the emission estimates. Although flight patterns were optimised for remote sensing measurements, data from an in-situ analyser for CH4 were found to be in good agreement with retrieved dry columns of CH4 from MAMAP and could be used to investigate and refine underlying assumptions for the inversion procedures. With respect to the total emissions of the mine at the time of the overflight, the inferred emission rate of 50.4 kt CH4 yr−1 has a difference of less than 1% compared to officially reported values by the mine operators, while the uncertainty, which reflects variability of the sources and conditions as well as random and systematic errors, is about ±13.5%.

Description: We present the first study of the influence of line mixing among CO2 lines on the remote sensing retrieval of atmospheric carbon dioxide. This is done in the bands near 1.6 and 2.1 μm which have been retained by the Orbiting Carbon Observatory (OCO) and Greenhouse Gases Observatory Satellite (GOSAT) instruments. A purely theoretical analysis is first made, based on simulations of atmospheric spectra. It shows that line mixing cannot be neglected since disregarding this process induces significant errors in the calculated absorption coefficients, leading to systematic structures in the spectral fit residuals and airmass-dependent biases in the retrieved CO2 amounts. These theoretical predictions are then confirmed by using atmospheric solar-absorption spectra measured by a ground-based Fourier transform spectrometer. Indeed, it is first shown that including line mixing in the forward model used for the inversion leads to a very significant reduction of the residuals in the 2.1 μm region. Secondly, the inclusion of line mixing reduces the dependence of the retrieved CO2 on the airmass and greatly improves the consistency between values obtained independently from spectra in the 1.6 and 2.1 μm bands. These results open very promising prospects for various ground-based and space-borne experiments monitoring the carbon dioxide atmospheric amounts.

Description: This REgional Carbon Cycle Assessment and Processes regional study provides a synthesis of the carbon balance of terrestrial ecosystems in East Asia, a region comprised of China, Japan, North and South Korea, and Mongolia. We estimate the current terrestrial carbon balance of East Asia and its driving mechanisms during 1990–2009 using three different approaches: inventories combined with satellite greenness measurements, terrestrial ecosystem carbon cycle models and atmospheric inversion models. The magnitudes of East Asia's terrestrial carbon sink from these three approaches are comparable: −0.293±0.033 PgC yr−1 from inventory–remote sensing model–data fusion approach, −0.413±0.141 PgC yr−1 (not considering biofuel emissions) or −0.224±0.141 PgC yr−1 (considering biofuel emissions) for carbon cycle models, and −0.270±0.507 PgC yr−1 for atmospheric inverse models. Here and in the following, the numbers behind ± signs are standard deviations. The ensemble of ecosystem modeling based analyses further suggests that at the regional scale, climate change and rising atmospheric CO2 together resulted in a carbon sink of −0.289±0.135 PgC yr−1, while land-use change and nitrogen deposition had a contribution of −0.013±0.029 PgC yr−1 and −0.107±0.025 PgC yr−1, respectively. Although the magnitude of climate change effects on the carbon balance varies among different models, all models agree that in response to climate change alone, southern China experienced an increase in carbon storage from 1990 to 2009, while northern East Asia including Mongolia and north China showed a decrease in carbon storage. Overall, our results suggest that about 13–27% of East Asia's CO2 emissions from fossil fuel burning have been offset by carbon accumulation in its terrestrial territory over the period from 1990 to 2009. The underlying mechanisms of carbon sink over East Asia still remain largely uncertain, given the diversity and intensity of land management processes, and the regional conjunction of many drivers such as nutrient deposition, climate, atmospheric pollution and CO2 changes, which cannot be considered as independent for their effects on carbon storage.

Description: Globally, terrestrial ecosystems have absorbed about 30% of anthropogenic greenhouse gas emissions over the period 2000–2007 and inter-hemispheric gradients indicate that a significant fraction of terrestrial carbon sequestration must be north of the Equator. We present a compilation of the CO2, CO, CH4 and N2O balances of Europe following a dual constraint approach in which (1) a land-based balance derived mainly from ecosystem carbon inventories and (2) a land-based balance derived from flux measurements are compared to (3) the atmospheric data-based balance derived from inversions constrained by measurements of atmospheric GHG (greenhouse gas) concentrations. Good agreement between the GHG balances based on fluxes (1294 ± 545 Tg C in CO2-eq yr−1), inventories (1299 ± 200 Tg C in CO2-eq yr−1) and inversions (1210 ± 405 Tg C in CO2-eq yr−1) increases our confidence that the processes underlying the European GHG budget are well understood and reasonably sampled. However, the uncertainty remains large and largely lacks formal estimates. Given that European net land to atmosphere exchanges are determined by a few dominant fluxes, the uncertainty of these key components needs to be formally estimated before efforts could be made to reduce the overall uncertainty. The net land-to-atmosphere flux is a net source for CO2, CO, CH4 and N2O, because the anthropogenic emissions by far exceed the biogenic sink strength. The dual-constraint approach confirmed that the European biogenic sink removes as much as 205 ± 72 Tg C yr−1 from fossil fuel burning from the atmosphere. However, This C is being sequestered in both terrestrial and inland aquatic ecosystems. If the C-cost for ecosystem management is taken into account, the net uptake of ecosystems is estimated to decrease by 45% but still indicates substantial C-sequestration. However, when the balance is extended from CO2 towards the main GHGs, C-uptake by terrestrial and aquatic ecosystems is offset by emissions of non-CO2 GHGs. As such, the European ecosystems are unlikely to contribute to mitigating the effects of climate change.

Description: This paper, developed under the framework of the RECCAP initiative, aims at providing improved estimates of the carbon and GHG (CO2, CH4 and N2O) balance of continental Africa. The various components and processes of the African carbon and GHG budget are considered, existing data reviewed, and new data from different methodologies (inventories, ecosystem flux measurements, models, and atmospheric inversions) presented. Uncertainties are quantified and current gaps and weaknesses in knowledge and monitoring systems described in order to guide future requirements. The majority of results agree that Africa is a small sink of carbon on an annual scale, with an average value of −0.61 ± 0.58 Pg C yr−1. Nevertheless, the emissions of CH4 and N2O may turn Africa into a net source of radiative forcing in CO2 equivalent terms. At sub-regional level, there is significant spatial variability in both sources and sinks, due to the diversity of biomes represented and differences in the degree of anthropic impacts. Southern Africa is the main source region; while central Africa, with its evergreen tropical forests, is the main sink. Emissions from land-use change in Africa are significant (around 0.32 ± 0.05 Pg C yr−1), even higher than the fossil fuel emissions: this is a unique feature among all the continents. There could be significant carbon losses from forest land even without deforestation, resulting from the impact of selective logging. Fires play a significant role in the African carbon cycle, with 1.03 ± 0.22 Pg C yr−1 of carbon emissions, and 90% originating in savannas and dry woodlands. A large portion of the wild fire emissions are compensated by CO2 uptake during the growing season, but an uncertain fraction of the emission from wood harvested for domestic use is not. Most of these fluxes have large interannual variability, on the order of ±0.5 Pg C yr−1 in standard deviation, accounting for around 25% of the year-to-year variation in the global carbon budget. Despite the high uncertainty, the estimates provided in this paper show the important role that Africa plays in the global carbon cycle, both in terms of absolute contribution, and as a key source of interannual variability.