ISSN:
0449-2951
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Two all-aromatic polyhydrazides have been investigated with respect to their propensity to form metal-chelate bulk polymer, films, and fibers. The aromatic polyhydrazide derived from isophthalic acid was found to give chelate bulk polymer with Ni+2, Ca+2, Ag+1, Hg+2, Pb+2, Zn+2, Cd+2, and Cu+2 which analyze for a 1:1 ratio of hydrazide link:metal ion. Films of the polyhydrazide-metal chelate were prepared by soaking polyhydrazide films in dimethylformamide solutions of metal salts. Tough fibers of the polyhydrazide-metal chelates with such metal ions as Cr+3, Co+2, and Ag+1 were prepared by passing polyhydrazide fiber through dimethylformamide solutions of these metal salts.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1964.100020423
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