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  • 1985-1989  (17)
Collection
Publisher
Years
Year
  • 11
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 101 (1989), S. 261-276 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die überwiegende Anzahl der heute in der Technik verwendeten Kunststoffe besteht aus flexiblen Makromolekülen, bei denen die aufeinanderfolgenden Grundeinheiten einen von 180° abweichenden Winkel bilden und gegeneinander verdrehbar sind. Kettensteife Polymere, die im Idealfall Stäbchengestalt aufweisen, sind bisher weit weniger gut untersucht worden. Der Grund hierfür liegt in der extremen Schwerlöslichkeit oder oft sogar der völligen Unlöslichkeit und Unschmelzbarkeit dieser Makromoleküle. In letzter Zeit haben aber gerade diese Materialien großes technisches Interesse gefunden, da sich daraus hochzugfeste Fasern und Formkörper herstellen lassen. Diese ungewöhnlichen mechanischen Eigenschaften leiten sich aus der nahezu parallelen Anordnung der stäbchenförmigen Kettenmoleküle im Festkörper ab, die durch Formgebung aus einer flüssigkristallinen (nematischen) Phase erhalten wird. Eine umfassende technische Nutzung dieser Materialien bedingt daher ein weitgehendes Verständnis des Phasenverhaltens und der Struktur der kettensteifen Polymere. Die Methodenvielfalt, die dem Polymerforscher heute zur Verfügung steht, hat dabei zu wichtigen Erkenntnissen geführt, die zusammen mit den Resultaten theoretischer Modelle zum Phasenverhalten direkt für die Praxis nutzbar gemacht werden können.
    Additional Material: 19 Ill.
    Type of Medium: Electronic Resource
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  • 12
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 100 (1988), S. 775-775 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 28 (1989), S. 253-267 
    ISSN: 0570-0833
    Keywords: Stiff-chain polymers ; Polymers ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Most of the industrial plastics used up to now consist of flexible macromolecules in which the repeat units are joined together in a nonlinear fashion by rotating bonds. Stiff-chain polymers, which in the ideal case have a rodlike shape, have received much less attention. The reason for this is that such polymers usually exhibit an exceedingly low solubility. Very often, they are absolutely insoluble and do not melt. However, in recent years these polymers have aroused technical interest because high-modulus fibers and moldings can be fabricated from them. These favorable mechanical properties are directly related to the nearly parallel arrangement of the rodlike macromolecules in the solid state which is achieved through spinning or extrusion from a liquid crystalline (nematic) state. It is therefore evident that a thorough understanding of the phase behavior and the structure is required for a universal technical utilization of these materials. The great variety of methods used in polymer science today has led to a deeper understanding of stiff-chain polymers. Experimental results together with theoretical modeling of the phase behavior have direct implications for the practical use of these macromolecular materials.
    Additional Material: 19 Ill.
    Type of Medium: Electronic Resource
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  • 14
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 28 (1989), S. 383-383 
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 15
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 28 (1989), S. 382-382 
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 16
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 27 (1988), S. 753-753 
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 17
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 28 (1989), S. 1130-1131 
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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