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  • American Institute of Physics (AIP)  (22)
  • Geological Society of London  (10)
  • American Meteorological Society (AMS)
  • Amsterdam : Elsevier
  • 2000-2004  (14)
  • 1990-1994  (19)
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  • 11
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 63 (1992), S. 856-858 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The assessment of signal to noise (S/N) values in x-ray absorption spectroscopy is important for a number of reasons. Two methods will be described that remove the signal to give the noise. The first uses polynomials and the second Fourier filtering. Having extracted the noise the signal can then be used to calculate the S/N ratio. The method described operates on a background subtracted spectrum and is quick so it can be done on line in an experimental situation.
    Type of Medium: Electronic Resource
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  • 12
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 73 (2002), S. 1367-1367 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: This talk will describe proposed studies of atomic- and nanoscale dynamics in condensed matter which take advantage of the high coherent x-ray flux to be produced by future x-ray free-electron laser (FEL) sources, such as the Linac Coherent Light Source at Stanford. In particular, I will focus on the current status and future prospects for photon correlation spectroscopy using coherent x-rays (XPCS), and the use of the ultrashort pulse structure of the x-ray FEL to observe dynamics into the femtosecond range. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 61 (1990), S. 2214-2219 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A high-power proportional temperature controller, using a fast infrared pyrometer, has been developed to change and control the temperature of metallic ribbon samples with microsecond response. The apparatus provides uniform and controlled heating for time-resolved x-ray scattering studies of structural phase transitions. When high-power pulse heating is used, the system is capable of increasing the sample temperature at rates in excess of 106 K/s, without overshoot and with subsequent control to ±1 K at temperatures as low as 650 K.
    Type of Medium: Electronic Resource
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  • 14
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 65 (1994), S. 3793-3798 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: We describe a highly sensitive new type of calorimeter based on the deflection of a "bimetallic'' micromechanical sensor as a function of temperature. The temperature changes can be due to ambient changes, giving a temperature sensor or, more importantly, due to the heat absorbed by a coating on the sensor, giving a heat sensor. As an example we show the results of using the sensor as a photothermal spectrometer. The small dimensions and low thermal mass of the sensor make it highly sensitive and we demonstrate a sensitivity of roughly 100 pW. By applying a simple model of the system the ultimate sensitivity is expected to be of the order of 10 pW. The thermal response time of the cantilever can also be determined, giving an estimate of the minimum detectable energy of the sensor. This we find to be 150 fJ and again from our model, expect a minimum value of the order of 20 fJ.
    Type of Medium: Electronic Resource
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  • 15
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 60 (1992), S. 2610-2612 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: In situ surface x-ray scattering studies of the GaAs(001) surface were used to determine whether specific surface reconstructions occur during organometallic vapor-phase epitaxy. Prior to growth, we find that surfaces heated in the presence of As form a c(4×4) structure, while those heated in the absence of organometallics or in Ga form two similar fourfold reconstructions. We find no evidence for the presence of any surface reconstruction during the actual layer-by-layer growth process.
    Type of Medium: Electronic Resource
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  • 16
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 80 (2002), S. 1809-1811 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We present in situ surface x-ray scattering measurements of PbTiO3 epitaxy by metal–organic chemical-vapor deposition. Oscillations in crystal truncation rod intensity corresponding to layer-by-layer growth are observed under a variety of growth conditions. At lower PbO overpressures, we observe a transition to step-flow growth and an increased rate of recovery after growth, indicating a higher surface mobility. © 2002 American Institute of Physics.
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  • 17
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A technique for selective characterization of the structure of free and buried thin-film interfaces by vibrationally resonant sum frequency generation spectroscopy is described. Manipulation of Fresnel coefficients by choice of film thickness on a reflecting substrate allows simultaneous optimization of the signal from the desired interface and minimization of the signal from other interfacial sources. This technique is demonstrated for the free polystyrene (PS)/air and the buried PS/spin-on glass interfaces. Our spectra show that the pendant phenyl group orientation is similar at the buried and free interfaces, with the phenyls pointing away from the bulk PS at each interface.
    Type of Medium: Electronic Resource
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  • 18
    Electronic Resource
    Electronic Resource
    New York, NY : American Institute of Physics (AIP)
    Physics of Fluids 3 (1991), S. 1461-1461 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: An experimental study was carried out to investigate turbulent mixing and entrainment across a density interface subjected to velocity shear. The flow configuration consisted of a salinity (stably) stratified two-fluid system with a driven upper turbulent layer and a quiescent lower layer. The experiments were performed in an Odell–Kovasznay tank and the mean flow in the upper layer was generated by using a conventional disk pump. The velocity and salinity measurements were made using a laser-Doppler anemometer and conductivity probes, respectively, and (quantitative) flow visualization was performed using the laser-induced fluorescence LIF technique. The refractive indices of upper and lower layers were matched, using salt and alcohol, to facilitate the use of laser-based flow diagnostic techniques. The measurements show that the rms velocity fluctuation u in bulk of the mixed layer scales well with the mean velocity jump Δu across the interface. The Thorpe, buoyancy, overturning, and integral length scales, as well as the maximum Thorpe displacement in the mixed layer, were also found to be proportional to the depth h of the upper mixed layer.The structure of the entrainment interface was found to depend strongly on the bulk Richardson number Ri (=Δb h/u2), where Δb is the buoyancy jump across the interfacial layer. At lower Ri, the entrainment occurred rapidly, as in a nonstratified fluid, but as Ri increases, the entrainment rate becomes a strong function of Ri: under the latter conditions, the interfacial wave breaking and Kelvin–Helmholtz instabilities were common features. At still higher Ri, the entrainment rate becomes vanishingly small and the interfacial mixing events were found to be controlled by the molecular diffusive effects. The measurement of the interfacial-layer thickness using LIF shows that it is much thinner than that measured using less-accurate techniques such as traversing probes. The nondimensional rms amplitude of the interfacial distortions at moderate and high Ri was found to be a strong function of Ri. The interfacial instabilities cause the formation of isolated mixing patches within the interface, which, when collapsed, form horizontal intrusions. The experimental measurements were in agreement with theoretical formulations based on scaling arguments.
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  • 19
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 101 (1994), S. 1704-1716 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The response of the molecular stretch mode of CO/Cu(100) near 2086 cm−1 (ν1) to resonant infrared, and nonresonant visible and ultraviolet pumping is measured on a picosecond time scale. Fourier transform infrared measurements establish that ν1 is anharmonically coupled to the frustrated translation near 32 cm−1 (ν4), so that transient shifts in ν1 indicate population changes in ν4. The ν1 response to visible and ultraviolet pumping is characterized by a spectral shift near zero delay time, which decays with a ≈2 ps time constant to an intermediate value, which then decays on a ≈200 ps time scale. The data agree well with a model whereby ν4 couples to both the photogenerated hot electrons and to the heated phonons. The characteristic coupling times to these two heat baths are found to both be a few picoseconds.
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  • 20
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 112 (2000), S. 2265-2273 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Quantum mechanical calculations on the vibrational predissociation dynamics of NeBr2 in the B electronic state have been performed and the results compared with both experimental data and other computational studies. For vibrational levels with v≤20 we find that the vibrational state dependence of the predissociation lifetimes is in qualitative agreement with experimental measurements, as are the calculated Br2 fragment rotational distributions. For higher vibrational levels, the B←X excitation profiles are well represented by a sum of two Lorentzian line shapes. We attribute this result to the presence of long-lived resonances in the dissociative continuum that are reminiscent of long-lived dissociative trajectories in previous classical studies of NeBr2. © 2000 American Institute of Physics.
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