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  • 1995-1999  (307)
  • 1975-1979  (49)
  • 1960-1964  (22)
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  • 11
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Annals of the New York Academy of Sciences 797 (1996), S. 0 
    ISSN: 1749-6632
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Natural Sciences in General
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  • 12
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 197 (1963), S. 1040-1040 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] THE only objects seen on a 200-in. plate near the positions of the components of the radio source 3(7 273 reported by Hazard, Mackey and Shimmins in the preceding article are a star of about thirteenth magnitude and a faint wisp or jet. The jet has a width of 1*2* and extends away from the ...
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  • 13
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 103 (1995), S. 211-218 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We report measurements of the absolute cross sections for the electron-impact ionization of SO2 from threshold to 200 eV. Absolute cross sections for the formation of the SO+2 parent ions and of the SO+, S+, O+, and O+2 fragment ions were obtained independently in two different laboratories using two different experimental techniques with uncertainties ranging from ±18% to ±25%. The level of agreement between the absolute cross sections (at 70 eV) obtained by the two techniques ranges from about 10% for SO+2 and SO+ to 20% for (S++O+2) and O+, which in all cases is well within the combined error margins of the two measurements. The high resolution capability of the mass spectrometer employed in one experiment enabled the separation of the S+ and O+2 fragment ions, which are separated by only 0.017 76 atomic mass units (amu), for the first time. The single positive ion formation is the dominant process for all observed product ions. The total single SO2 ionization cross section obtained by the two techniques agreed to within 8%. A comparison of the experimentally determined total SO2 single ionization cross sections with calculated cross sections based on a modified additivity rule revealed agreement to within 20%. © 1995 American Institute of Physics.
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  • 14
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    FEMS microbiology letters 170 (1999), S. 0 
    ISSN: 1574-6968
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology
    Notes: We have explored the nature of the sudden viral amplification observed during the ageing of P22-infected lysogenic colonies of Salmonella typhimurium [Ramı́rez, E, and Villaverde, A. (1997) Gene 202, 147–149]. By a comparative analysis of the wild-type P22 and a P22 integration mutant, it has been shown that the conditions promoting prophage induction occur in only a small portion of the bacterial population and briefly during the transition between the exponential growth and the stationary phase. The viral burst is RecA-dependent and cannot be reproduced in continuous culture by a mere decrease of the growth rate. This suggests that the limited viral propagation in colonies is probably linked to heterogeneous physiological conditions within colonial populations, distinct from those of the homogeneous liquid cultures.
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  • 15
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 383 (1996), S. 401-401 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] SIR á€" Microhardness measurements on synthesized samples of stishovite, a high-pressure phase of silica, show that it is the hardest oxide yet discovered. Among polycrystalline materials, its hardness (33 gigapascals, GPa) rivals those of the hardest materials. Despite many ...
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  • 16
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 106 (1997), S. 1676-1686 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: In this paper, new experimental results using UV spectroscopy of the small benzene–Arn clusters are presented. We have found evidence for the vibrational predissociation of the S1 state of some of these species on a nanosecond time scale and we propose a new assignment for the UV spectral features of this system. This assignment is consistent with other experimental data and it accounts additionally for the previously reported spectral anomalies, in particular the ionization potential measurements of these species. The two-color R2PI spectra performed can thus be considered as nanosecond pump–probe experiments that allow us to estimate the relaxation rate of the S1state of these clusters. The vibrational relaxation is found to be strongly size and structure dependent: The two isomers [(1/1) and (2/0)] of the n=2 species exhibit different lifetimes differing by at least one order of magnitude. The size dependence of the relaxation process within the one-sided isomer series appears also paradoxical since the relaxation rates of the (3/0) and (4/0) species are found to be smaller than that of the (2/0). These properties are discussed in relationship with the symmetry of these species. © 1997 American Institute of Physics.
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  • 17
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 104 (1996), S. 2438-2445 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have used the large electric fields at the interface of a Pt(111) electrode and an acetonitrile electrolyte solution to tune the interaction between adsorbed CO and the Pt(111) surface. The electrode potential is varied over a 2.5 Volt range. As the electrode potential is made more positive, the CO vibrational frequency increases and the vibrational lifetime decreases. Over the potential range investigated, the tuning is about 35–40 cm−1 and the lifetime varies from ≈2.1 to ≈1.5 ps. Ab initio calculations performed for CO/Cu(100) predicted the opposite trend for the lifetimes for that system [M. Head-Gordon and J. C. Jully, Chem. Phys. 175, 37 (1993)]. Within an empirical model of nonadiabatic charge transfer [B. N. J. Persson and M. Persson, Solid State Commun. 36, 175 (1980)], our observations can be explained by a decreasing 2π-derived density of states of the Pt/CO complex at the Fermi level. © 1996 American Institute of Physics.
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  • 18
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    European journal of soil science 50 (1999), S. 0 
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Standard procedure for dispersing natural soils for particle size fractionation can be too aggressive for soil containing coal and other organic particles from coal industries. We have investigated ultrasonic dispersion for the latter in four soils differing in pedogenesis (Phaeozem, Podzol, reclaimed mine soils), carbon content (27.5–138.6 g kg–1), clay content (80–153 g kg–1) and sources of particles (airborne coal dust, combustion residues, lignite particles). As we found previously for natural soils, the ultrasonic energy needed for complete dispersion varies between 450 and 500 J ml–1, but the resulting particle size distributions differ from those obtained by standard textural analysis. This is probably related to the different properties of native soil organic matter and coal and combusted particles. Coal and soot particles may partly resist oxidation with hydrogen peroxide, depending on material and particle size. The diameter of lignite particles, remaining after oxidation, is overestimated in sedimentation analysis by a factor of 1.66. Sand-sized lignite particles can be disrupted by ultrasonication and redistributed to finer particle size fractions. The ultrasonic dispersion and particle size fractionation procedure can be applied to soils containing coal and combusted particles, but caution is needed in interpreting the results if they contain large proportions of coal particles.
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  • 19
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    European journal of soil science 50 (1999), S. 0 
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Soil organic matter can be intimately associated with mineral particles of various sizes. For structural studies, soil organic matter can be isolated in particle size fractions after complete dispersion of the aggregates by ultrasonication. The ultrasonic dispersion energy necessary for complete dispersion was investigated in three A and two B horizons originating from four soils differing in pedogenesis (Gleysol, Phaeozem, Podzol, Alisol), organic C (4.2–34.5 g kg–1) and clay content (24–294 g kg–1). Calorimetric calibration of five probe-type ultrasonifiers revealed that the actual energy output from an instrument can depart widely from its nominal output, and that this discrepancy varies from instrument to instrument. Calorimetric calibration is therefore essential for consistency and comparisons between laboratories. Between 450 and 500 J ml–1 of ultrasonic dispersion energy was enough to disperse completely all samples investigated. The particle size distributions obtained were close to those from standard analysis, except for smaller yields (–20 to –80 g kg–1) of sand size fractions, which suggests that dispersion by ultrasound is more effective. Based on total C, C:N ratio and distribution of dissolved C, no detachment of soil organic matter from primary organomineral complexes and no redistribution between particle size fractions could be detected in the range 30–590 J ml–1 of dispersion energy.
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  • 20
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    European journal of soil science 50 (1999), S. 0 
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Burning vegetation produces partly charred plant material which subsequently could contribute to the highly refractory proportion of soil organic matter. The presence of charred organic carbon (COC) was investigated in 17 horizons originating from nine soils from Germany and the Netherlands using a suite of complementary methods (high-energy ultraviolet photo-oxidation, scanning electron microscopy, solid-state 13C nuclear magnetic resonance, lignin analysis by CuO oxidation). Charred organic carbon could not be detected in the A horizons of an Alisol and a Gleysol, but it contributed up to 45% of the organic carbon and up to about 8 g kg–1 of the soil in a range of grey to black soils (Cambisol, Luvisol, Phaeozem, Chernozem and Greyzem). All these soils have chernozemic soil properties (dark colour, A–C profile, high base saturation, bioturbation). A 10-km colour sequence of four chernozemic soils, which were very similar in chemical and physical properties, showed a strong relation between colour and the content of COC. This suggests that the COC affects mainly soil colour in the sequence studied. Finely divided COC seems to be a major constituent of many chernozemic soils in Germany. These results suggest that besides climate, vegetation and bioturbation, fire has played an important role in the pedogenesis of chernozemic soils.
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