ISSN:
1434-193X
Schlagwort(e):
Palladium catalysis
;
Homogeneous catalysis
;
Anilines
;
Alkylation
;
Oxazolidinones
;
Chemistry
;
General Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
-Palladium-catalyzed reaction of acidic anilines with (Z)-2-butene-1,4-diyl dicarbonate affords N-aryl-4-vinyloxazolidin-2-ones. The success of the reaction depends on the acidity of the aniline and requires in situ conversion of the dicarbonate into carbamate carbonate by nucleophilic attack of the aniline conjugate base followed by palladium-catalyzed intramolecular cyclization.
Zusätzliches Material:
1 Tab.
Materialart:
Digitale Medien
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