ISSN:
0947-3440
Schlagwort(e):
Tetrathiafulvalene
;
Cyclophanes
;
Macrocycles
;
Donor-acceptor systems
;
Supramolecular chemistry
;
Chemistry
;
Organic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The syntheses and some physical properties (redox potentials) of cyclic tetrathiafulvalenes (TTF) are reviewed. The ring closure is generally performed in one of two different ways: (i) by coupling of 1,3-dithiol derivatives thereby forming the central fulvene bond, or (ii) by cyclization of a preformed TTF derivative. The second route is very efficient when using the cyanoethyl protection/deprotection method and has made possible the preparation of a number of two- and three-dimensional macrocycles, e.g. mono-, bis- and tetramacrocycles, oligomeric macrocycles and cage-type molecules. The use of tetrathiafulvalenophanes in supramolecular chemistry is also exemplified in this microreview.
Zusätzliches Material:
2 Tab.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/jlac.199719971103
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