ISSN:
1573-9171
Schlagwort(e):
cinnamyl dithiocarboxylates
;
tetracyanoethylene
;
2,2,3,3-tetracyano7,8-dithiabicyclo[3.2.1]octanes
;
3,3,4,4-tetracyano-1-dithioacyloxycyclopentanes
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Abstract The reaction of cinnamyl dithiocarboxylates (1) containing electron-donating substituents at the central carbon atom of the dithioester group (R = p-MeOC6H4, EtO, andp-Tol) with tetracyanoethylene affords 2,2,3,3-tetracyano-4-endo-phenyl-7,8-dithiabicyclo[3.2.1]octanes (2) as well as isomeric 3,3,4,4-tetracyano-2-phenyl-trans-1-dithioacyloxycyclopentanes (3). Dithiabicyclooctanes2 rearrange to the corresponding cyclopentanes3 upon thermolysis.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF01151301
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