ISSN:
1420-9071
Schlagwort(e):
1-Aminocyclopropanecarboxylic acid
;
ACC-synthase
;
PLP-catalyzed reaction
;
stereochemistry
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Biologie
,
Medizin
Notizen:
Summary Under the action of the appropriate synthase from ripe tomatoes a 1∶1 mixture of (3S, 4R)-[3,4-2H2] and (3R, 4S)-[3,4-2H2]-(2S)-adenosylmethionine is transformed into a 1∶1 mixture of the two meso forms of [2H2]-1-aminocyclopropanecarboxylic acid, a result which proves the operation of an inversion mechanism and which is consistent with direct nucleophilic displacement of the leaving group in the substrate.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF01952472
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