ISSN:
0009-2940
Schlagwort(e):
1λ4,3λ4,5λ4-Trithiatriazines
;
Anomeric effect
;
Antiaromaticity
;
Calculations, ab initio, MNDO
;
Chemistry
;
Inorganic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The Structure of TrithiatriazinesMNDO and ab initio calculations have shown that the structure of trithiatriazines [(RSN)3, where R = F, Cl, {H}] is influenced by the anomeric effect and by antiaromaticity of the ring for electron pairs in axial positions. These calculations are supported by a joint electron diffraction and microwave structure determination of (NSF)3 in the gas phase.
Zusätzliches Material:
2 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/cber.19901231106
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