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  • 1
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 45 (1992), S. 1783-1788 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A procedure is described for preparing fairly uniform spheres of three different nylon polymers by phase separation. The mean diameter and polydisperse index were 5 μm and 1.056 for Griltex nylon, 5.7 μm and 1.046 for nylon 6/6, and 12.9 μm and 1.016 for nylon 6. The phase separation is done by taking a 1 wt % solution in a theta solvent above the theta temperature and cooling it rapidly. The spheres of the three nylons have various degrees of roughness. Formation of highly uniform particles during phase separation is discussed in a preliminary way. © 1992 John Wiley & Sons, Inc.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 175 (1974), S. 2483-2488 
    ISSN: 0025-116X
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Beschreibung / Inhaltsverzeichnis: Es wird über den Beginn einer Untersuchung zur Kristallisationskinetik von Polycaprolacton (Poly(1-oxy-6-oxohexamethylene) (1)) berichtet. Die primäre Keimbildung und das primäre Sphärolith-Wachstum aus der Polymerschmelze werden bei hinreichend hohen Temperaturen verfolgt, wodurch sichergestellt ist, daß das Wachstum der Kristallite durch Keimbildung bestimmt ist. Die kinetischen Daten werden weitgehend mit Hilfe des Avrami-Modells interpretiert, welches sich gut auf die Kristallisation von 1 anwenden ließ.
    Notizen: A kinetic crystallization study of polycaprolactone (poly(1-oxy-6-oxohexamethylene) (1)) has been initiated to investigate the primary nucleation and primary spherulitic growth from a polymer melt at temperatures that are high enough to insure nucleation-limited crystallite growth. The analysis of the kinetic data is largely made on the basis of an Avrami model which proved to be well suited for the interpretation of the crystallization of 1.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 7 (1969), S. 1705-1719 
    ISSN: 0449-2978
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: The temperature dependence of relative modulus observed in filled thermoset, thermoplastic, and polyelectrolyte salt matrices is explained on the basis of induced stresses produced by the differences in the thermal expansion coefficients of the constituent materials. The analysis is based on the assumption that the modulus of the matrix in a filled polymer is less than that of the unfilled polymer. The temperature dependence of relative modulus is expressed as a function of the difference in thermal expansion coefficients, the volume fraction, the relative modulus in the unstressed state, and mechanical properties of the phases. Agreement is good between the analysis and experimental results for three systems: epoxy and glass, polyethylene and wollastonite, and a polyelectrolyte salt with mica and asbestos.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 58 (1995), S. 291-296 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The “three-liquid” contact angle procedure of Good et al. was applied to polymer films of varying Lewis acidic and basic nature to test the procedure. Surface energy parameters with the units of mJ/m2 are determined for the surfaces. These are γLWs (Lifshitz-van der Waals or apolar), γ+s (acidic), and γ-s (basic). Very little has yet been published on this new method, and this study found it to be promising. More research on the procedure is warranted. The study included films of basic polymethylmethacrylate (PMMA), and predominately acidic chlorinated polyvinylchloride (CPVC) and polyvinylfluoride (PVF) as well as the series: polyethylene (PE) and PE copolymerized with 1.8% and 7.0% acrylic acid. In some of the experiments receding contact angles were measured, and the surface energy parameters determined in order to cast more light on the mechanism of contact angle hysteresis. © 1995 John Wiley & Sons, Inc.
    Zusätzliches Material: 6 Tab.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A: General Papers 3 (1965), S. 2400-2400 
    ISSN: 0449-2951
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Propellants, Explosives, Pyrotechnics 17 (1992), S. 99-105 
    ISSN: 0721-3115
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Fast thermolysis studies of ammonium nitrate (AN) and its mixtures with magnesium and activated charcoal have been carried out by the Fourier transform infrared spectroscopy/temperature profiling technique. When subjected to rapid heating (ca. 80°C/s), AN Sublimes/decomposes around 300°. Sublimation dominates at ambient pressures. The IR-active products of decomposition are NH3, NO2, N2O and H2O. Reaction schemes accounting for the products are proposed which involve proton transfer leading to NH3 by the decomposition products of HNO3. The decomposition of AN is significantly enhanced when AN is mixed with magnesium powder or charcoal, and occurs at as low a temperature as 135°C. Whereas NH3 is the major product of decomposition of AN—Mg mixtures, no NH3 is observed from AN—C mixtures. The results are explained by the reaction of HNO3 and NH3 with Mg or C.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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