ISSN:
1573-0662
Schlagwort(e):
Fourier-transform infrared spectroscopy
;
stratospheric trace gases
;
ozone depletion
;
remote sensing
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
,
Geologie und Paläontologie
Notizen:
Abstract During SESAME phase I ground-based FTIR measurements were performed atEsrange near Kiruna, Sweden, from 28 January to 26 March 1994. Zenith columnamounts of ClONO2, HCl, HF, HNO3,O3, N2O, CH4, and CFC-12 werederived from solar absorption spectra. Time series of ClONO2and HCl indicate a chlorine activation at the end of January and around 1March. On 1 March a very low amount of HCl of 2.09times; 1015molec. cm-2 was detected, probably caused by a second chlorineactivation phase starting from an already decreased amount of HCl. The ratioof column amounts of HCl to ClONO2 decreased inside the vortexfrom about 1 in January to 0.4 in late March compared to values of about 2outside the vortex. Although the Arctic stratosphere was rather warm in winter1993/94 and PSCs occurred seldom, chlorine partitioning into its reservoirspecies HCl and ClONO2 changed during that winter andClONO2 is the major chlorine reservoir at the end of thewinter as in cold winters like 1991/92 and 1994/95.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1023/A:1005728713762
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