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  • 1
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Macromolecular Rapid Communications 17 (1996), S. 447-454 
    ISSN: 1022-1336
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: Quenched nematic films of a liquid crystalline polyester were crystallized either thermally or by solvent induced crystallization, and their structural organization was analyzed. All techniques show that the thermal crystallization transforms part of the nematic phase into a crystalline one, the remaining part leaving unchanged. By contrast, the solvent induced crystallization does transform a part of the nematic phase into a crystalline phase, leaving the residual part in a much more disordered state resembling the amorphous state.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Macromolecular Chemistry and Physics 195 (1994), S. 735-741 
    ISSN: 1022-1352
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: The crystallization from the glassy state of different samples of syndiotactic polystyrene (sPS) was investigated with different techniques, such as differential scanning calorimetry, infrared analysis, and polarized optical microscopy. The different samples of sPS were obtained by ageing the glassy sPS films at room temperature and at 70°C; the behaviour of these films was compared with that of the fresh sample, put at the crystallization temperature as soon as prepared. The temperature of crystallization was 120°C; at this temperature, besides the crystalline phase, a fraction of mesophase is formed. All the techniques investigated to follow the crystallization phenomenon show that the fresh sample crystallizes much sooner than the others; the sample aged at 70°C takes the longest time to crystallize, whereas an intermediate behaviour characterizes the sample aged at room temperature. This result was correlated with the initial structural organization of the glassy amorphous samples.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Basel : Wiley-Blackwell
    Die Makromolekulare Chemie, Rapid Communications 9 (1988), S. 765-769 
    ISSN: 0173-2803
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Basel : Wiley-Blackwell
    Die Makromolekulare Chemie, Rapid Communications 9 (1988), S. 761-764 
    ISSN: 0173-2803
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Basel : Wiley-Blackwell
    Die Makromolekulare Chemie, Rapid Communications 11 (1990), S. 199-203 
    ISSN: 0173-2803
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Basel : Wiley-Blackwell
    Die Makromolekulare Chemie, Rapid Communications 12 (1991), S. 295-299 
    ISSN: 0173-2803
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 189 (1988), S. 815-821 
    ISSN: 0025-116X
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: Preliminary results regarding the physical behaviour of a stereoblock-isotactic polypropylene are reported. The polymer was obtained using a soluble Ziegler-Natta catalyst and films were prepared by pressure molding. The particular steric configuration is responsible of low crystallinity and small crystal size; the bulk structure can be represented by a fringed micellar model in which small crystallites act as physical crosslinks. The observed behaviour being typical of a thermoplastic elastomer well agrees with the suggested model.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 58 (1995), S. 1701-1706 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The structural organization and the physical properties of a new copolymer styrene-ethylene have been analyzed. The composition was 80% of ethylene units, corresponding to 52% in weight, with a distribution of styrene units in the chain implying the absence of styrene-styrene sequences. The length of the polyethylene chains, limited by the insertion of the phenyl group, is not sufficient to allow good crystallization, and in fact the copolymer shows a very low crystailinity, of the order of 5-10%, and a broad melting range, with a peak centered at 120°C. The small crystalline domains are segregated into an amorphous matrix, producing a thermoplastic elastomer. The mechanical properties at large deformation were analyzed at different temperatures. The copolymer shows good elastic properties, in terms of deformation reversibility as well as of energy dissipation in the hysteresis cycles. Also the stress level and the elastic recovery are very good, if compared with others thermoplastic elastomers. © 1995 John Wiley & Sons, Inc.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Macromolecular Chemistry and Physics 199 (1998), S. 2671-2675 
    ISSN: 1022-1352
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: Amorphous films of syndiotactic polystyrene were crystallized in dichloromethane, to obtain samples in the clathrate δ form; successively the samples were either annealed at temperatures below the glass transition temperature (Tg) or extracted with acetone. The samples obtained show, in the X-ray analysis, crystalline structures tending toward the “emptied” δ form, free of solvent molecules, as already described for sPS. The study of the transport properties, diffusion and sorption of dichloromethane vapor, shows that the annealed samples are characterized by a slightly lower diffusion coefficient, but much higher sorption at low activity of the vapour. This high sorption is explained by the penetration of solvent molecules both into the amorphous and the “emptied” crystalline phase, producing again the clathrate form at low vapour activity. The high sorption capability makes these samples promising as sorption media to remove traces of polluting chlorinated solvents both in the liquid and in the vapour phase.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 175 (1974), S. 2983-2989 
    ISSN: 0025-116X
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Beschreibung / Inhaltsverzeichnis: In der vorliegenden Arbeit wurde die Kristallisationskinetik von zwei verschiedenen Netzwerken aus Naturkautschuk untersucht. Diese Netzwerke wurden durch Vulkanisation unter gewöhnlichen Bedingungen bzw. im gequollenen Zustand erhalten.Die Ergebnisse werden auf molekularer Ebene diskutiert und geben wertvolle Aufschlüsse über die bekannten Abweichungen von der Gaußschen Theorie der Gummielastizität.
    Notizen: In the present paper the crystallization kinetics of two networks of natural rubber was analyzed. The two networks were prepared following two different vulcanization techniques, as usual the first, and under swelling conditions the second.The results are discussed at the molecular level and give some important information about the well known deviations from the Gaussian theory on rubber elasticity.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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