ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Ihre E-Mail wurde erfolgreich gesendet. Bitte prüfen Sie Ihren Maileingang.

Leider ist ein Fehler beim E-Mail-Versand aufgetreten. Bitte versuchen Sie es erneut.

Vorgang fortführen?

Exportieren
Filter
Sammlung
Sprache
Erscheinungszeitraum
  • 1
    Publikationsdatum: 2023-11-23
    Beschreibung: Managed grasslands have the potential to store carbon (C) and partially mitigate climate change. However, it remains difficult to predict potential C storage under a given soil or management practice. To study C storage dynamics due to long-term (1952–2009) phosphorus (P) fertilizer and irrigation treatments in New Zealand grasslands, we measured radiocarbon (〈sup〉14〈/sup〉C) in archived soil along with observed changes in C stocks to constrain a compartmental soil model. Productivity increases from P application and irrigation in these trials resulted in very similar C accumulation rates between 1959 and 2009. The ∆〈sup〉14〈/sup〉C changes over the same time period were similar in plots that were both irrigated and fertilized, and only differed in a non-irrigated fertilized plot. Model results indicated that decomposition rates of fast cycling C (0.1 to 0.2 year〈sup〉−1〈/sup〉) increased to nearly offset increases in inputs. With increasing P fertilization, decomposition rates also increased in the slow pool (0.005 to 0.008 year〈sup〉−1〈/sup〉). Our findings show sustained, significant (i.e. greater than 4 per mille) increases in C stocks regardless of treatment or inputs. As the majority of fresh inputs remain in the soil for less than 10 years, these long term increases reflect dynamics of the slow pool. Additionally, frequent irrigation was associated with reduced stocks and increased decomposition of fresh plant material. Rates of C gain and decay highlight trade-offs between productivity, nutrient availability, and soil C sequestration as a climate change mitigation strategy.
    Beschreibung: European Research Council http://dx.doi.org/10.13039/501100000781
    Beschreibung: GNS Science
    Beschreibung: Max Planck Institute for Biogeochemistry (2)
    Beschreibung: https://github.com/ShaneStoner/Winchmore14C
    Schlagwort(e): ddc:631.4 ; Radiocarbon ; Soil carbon ; Soil modeling ; Carbon sequestration ; Transit time ; SoilR
    Sprache: Englisch
    Materialart: doc-type:article
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 2
    Publikationsdatum: 2019-12-19
    Beschreibung: A widely overlooked source of carbon (C) in the soil environment is organic carbon (OC) of geogenic origin, e.g. graphite, occurring mostly in metamorphic rocks. Appropriate methods are not available to quantify graphite and to differentiate it from other organic and inorganic C sources in soils. This methodological shortcoming also complicates studies on OC in soils formed on graphite-containing bedrock because of the unknown contribution of a very different soil OC source. In this study, we examined Fourier-transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA) and the smart combustion method for their ability to identify and quantify graphitic C in soils. For this purpose, several artificial soil samples with graphite, CaCO3 and plant litter as the usual C components were created. A graphitic standard was mixed with pure quartz and a natural soil for calibration and validation of the methods over a graphitic C range of 0.1 % to 4 %. Furthermore, rock and soil material from a graphite-bearing schist and a schist without natural graphite were used for method validation. FTIR. As specific signal intensities of distinct graphite absorption bands were missing, calibration could only be performed on general effects of graphite contents on the energy transmitted through the samples. The use of samples from different mineral origins yielded significant matrix effects and hampered the prediction of geogenic graphite contents in soils. TGA. Thermogravimetric analysis, based on changes in mass loss due to differences in thermal stabilities, is suggested as a useful method for graphite identification, although (calcium) carbonate and graphitic C have a similar thermal stability. However, the quantitative estimation of the graphite contents was challenging as dehydroxylation (mass loss) of a wide range of soil minerals occurs in a similar temperature range. Smart combustion. The method is based on measuring the release of C during a combustion program, quantified by a non-dispersive infrared detector (NDIR) as part of a commercial elemental analyser, whereby carbonates and graphitic C could be separated by switching between oxic and anoxic conditions during thermal decomposition. Samples were heated to 400 ∘C under oxygen-rich conditions, after which further heating was done under anoxic conditions till 900 ∘C. The residual oxidizable carbon (ROC), hypothesized to be graphitic C, was measured by switching back to oxygenic conditions at 900 ∘C. Test samples showed promising results for quantifying graphitic C in soils. For the purpose of quantifying graphitic C content in soil samples, smart combustion was the most promising method of those which have been examined in this study. However, caution should be taken with carbonate-rich soils as increasing amounts of carbonate resulted in an underestimation of graphitic C content.
    Print ISSN: 2199-3971
    Digitale ISSN: 2199-398X
    Thema: Geologie und Paläontologie
    Publiziert von Copernicus im Namen von European Geosciences Union.
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 3
    Publikationsdatum: 2019-06-20
    Beschreibung: A widely overlooked source of carbon (C) in the soil environment is organic carbon (OC) of geogenic origin, e.g. graphite, occurring mostly in metamorphic rocks. Appropriate methods are not available to quantity graphite and to differentiate it from other organic and inorganic C sources in soils. This methodological shortcoming also complicates studies on OC in soils formed on graphite-containing bedrock, because of the unknown contribution of a very different soil OC source. In this study, we examined Fourier-transform infrared (FTIR) spectroscopy, Thermogravimetric analysis (TGA) and the smart combustion methods for their ability of identifying and quantifying graphitic C in soils. For this purpose, several artificial soil samples with graphite, CaCO3 and plant litter as usual C components were created. A graphitic standard was mixed with pure quartz and a natural soil for calibration and validation of the methods over a graphitic C range of 0.1 to 4 %. Furthermore, rock and soil material from both a graphite bearing schist and a schist without natural graphite were used for method validation. FTIR: As specific signal intensities of distinct graphite absorption bands were missing, calibration could only be performed on general effects of graphite contents on the energy transmitted through the samples. The use of samples from different mineral origin yielded significant matrix effects and hampered the prediction of geogenic graphite contents in soils. TGA: Thermogravimetric analysis, based on changes in mass loss due to differences in thermal stabilities, are suggested as a useful method for graphite identification, although (calcium) carbonate and graphitic C have a similar thermal stability. However, the quantitative estimation of the graphite contents was challenging as dehydroxylation (mass loss) of a wide range of soil minerals occur in a similar temperature range. Smart combustion: The method is based on measuring the release of C during a combustion program, quantified by a non-dispersive infrared detector (NDIR) being part of a commercial elemental analyser, whereby carbonates and graphitic C could be separated by switching between oxic and anoxic conditions during thermal decomposition. Samples were heated to 400 °C under oxygen rich conditions, after which further heating was done under anoxic conditions till 900 °C. The residual oxidizable carbon (ROC), hypothesized to be graphitic C, was measured by switching back to oxygenic conditions at 900 °C. Test samples showed promising results for quantifying graphitic C in soils. For the purpose of quantifying graphitic C content in soil samples, smart combustion was the most promising method of those who have been examined in this study. However, caution should be taken with carbonate rich soils as increasing amounts of carbonate resulted in an underestimation of graphitic C content.
    Digitale ISSN: 2199-3998
    Thema: Geologie und Paläontologie
    Publiziert von Copernicus im Namen von European Geosciences Union.
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 4
    Publikationsdatum: 2021-08-27
    Beschreibung: Managed grasslands have the potential to store carbon (C) and partially mitigate climate change. However, it remains difficult to predict potential C storage under a given soil or management practice. To study C storage dynamics due to long-term (1952–2009) phosphorus (P) fertilizer and irrigation treatments in New Zealand grasslands, we measured radiocarbon (14C) in archived soil along with observed changes in C stocks to constrain a compartmental soil model. Productivity increases from P application and irrigation in these trials resulted in very similar C accumulation rates between 1959 and 2009. The ∆14C changes over the same time period were similar in plots that were both irrigated and fertilized, and only differed in a non-irrigated fertilized plot. Model results indicated that decomposition rates of fast cycling C (0.1 to 0.2 year−1) increased to nearly offset increases in inputs. With increasing P fertilization, decomposition rates also increased in the slow pool (0.005 to 0.008 year−1). Our findings show sustained, significant (i.e. greater than 4 per mille) increases in C stocks regardless of treatment or inputs. As the majority of fresh inputs remain in the soil for less than 10 years, these long term increases reflect dynamics of the slow pool. Additionally, frequent irrigation was associated with reduced stocks and increased decomposition of fresh plant material. Rates of C gain and decay highlight trade-offs between productivity, nutrient availability, and soil C sequestration as a climate change mitigation strategy.
    Print ISSN: 0168-2563
    Digitale ISSN: 1573-515X
    Thema: Chemie und Pharmazie , Geologie und Paläontologie
    Publiziert von Springer
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
Schließen ⊗
Diese Webseite nutzt Cookies und das Analyse-Tool Matomo. Weitere Informationen finden Sie hier...