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1

Digitale Medien

Acrylonitrile–butadiene–styrene-toughened polysulphone of bisphenol A blends: influence of processing temperature and composition (1997)

RUIZ DE GAUNA, B. E ; GAZTELUMENDI, M ; NAZABAL, J

Springer

Journal of materials science 32 (1997), S. 971-977

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ISSN: 1573-4803

Quelle: Springer Online Journal Archives 1860-2000

Thema: Maschinenbau

Notizen: Abstract Polysulphone of bisphenol A (PSU)/acrylonitrile–butadiene–styrene (ABS) blends have been obtained by direct injection moulding at different temperatures and for compositions in the PSU-rich range. Direct injection moulding provided a mixing level similar to that of kneading. The blends were almost fully immiscible with the exception of the polybutadiene (PBD) phase where some PSU appeared to be present. Only a very small amount of ABS was required to greatly improve the tracking index of PSU. The mechanical properties, however, were those of a compatible material, and did not depend on the injection temperature. Moreover, with the exception of the ductility, they were in fairly good proportion to the blend composition, and provided the most balanced set of properties at an ABS content near 5%.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1023/A:1018566019772

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2

Digitale Medien

Influence of migration of plasticizer during melt mixing on the transitions and properties of PC/CAB blends (1990)

Jurado, M. J. ; Gaztelumendi, M. ; Nazabal, J. ; [weitere]

Bognor Regis [u.a.] : Wiley-Blackwell

Journal of Polymer Science Part B: Polymer Physics 28 (1990), S. 1015-1031

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ISSN: 0887-6266

Schlagwort(e): Chemistry ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Physik

Notizen: Static and dynamic mechanical properties, morphology, and thermal behavior of polycarbonate (PC)/plasticized cellulose acetobutyrate (CAB) blends were investigated to determine whether the plasticizer of the CAB modifies the miscibility of the blend and the mechanical properties of this essentially incompatible blend. In spite of the lack of transparency of the blends, both dynamic mechanical and thermal analysis results show the presence, at all blend compositions studied, of a single glass transition temperature which varies with the composition of the blend. Considering the ternary nature of the blends, we propose that plasticizer migration and the difficulty of discerning the presence of one or two peaks in a narrow temperature range may account for the observed behavior. Scanning electron microscopy confirms the immiscibility of the blends. The blends show large positive deviations of the tensile moduli from linearity and very low ductility. The reported tensile strength data are discussed in terms of several different equations for composites. This mechanical behavior is explained as a consequence of the migration of the plasticizer and of its subsequent antiplasticizing effect on the properties of the blend.

Zusätzliches Material: 8 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/polb.1990.090280703

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3

Digitale Medien

Effects of injection temperature on the mixing level and properties of injection-mixed PMMA-phenoxy blends (1992)

Erro, R. ; Gaztelumendi, M. ; Nazabal, J.

New York, NY [u.a.] : Wiley-Blackwell

Journal of Applied Polymer Science 45 (1992), S. 339-348

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ISSN: 0021-8995

Schlagwort(e): Chemistry ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Maschinenbau , Physik

Notizen: Polymethyl methacrylate-phenoxy blends have been obtained in an injection machine at different injection temperatures in order to determine the possibility of direct blending in these processing machines and also the effect that different blending levels have in the mechanical properties of these miscible blends. High injection temperatures, but in the range used in production of the components, provided fairly well homogenized blends comparable both in transparency and mechanical properties to those obtained by kneading and subsequent compression molding. Very good mechanical properties, although less transparent, were obtained when processing at low injection temperatures.

Zusätzliches Material: 12 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/app.1992.070450216

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4

Digitale Medien

Polycarbonate/phenoxy blends: Physical behavior and development of interchange reactions in melt-processing conditions (1986)

Mondragón, I. ; Gaztelumendi, M. ; Nazábal, J.

Stamford, Conn. [u.a.] : Wiley-Blackwell

Polymer Engineering and Science 26 (1986), S. 1478-1482

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ISSN: 0032-3888

Schlagwort(e): Chemistry ; Chemical Engineering

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Maschinenbau , Physik

Notizen: The miscibility of the polycarbonate of bisphenol A with the polyhydroxyether of bisphenol A was analyzed using differential scanning calorimetry and the, results are compared with the torque data obtained using a Brabender Plasticorder. The possibility of interchange reactions was analyzed by means of the observation of the melt-viscosity variation versus processing time in the mixer-bowl. These reactions form graft-copolymers that develop into crosslinked copolymers at higher residence times. It was also shown that the speed of these reactions depends on the processing temperature. The variation produced on the glass-transition temperature because of branching was also analyzed.

Zusätzliches Material: 6 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pen.760262103

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5

Digitale Medien

Mechanical behavior of polycarbonate/phenoxy blends before and after interchange reactions (1988)

Mondragón, I. ; Gaztelumendi, M. ; Nazábal, J.

Stamford, Conn. [u.a.] : Wiley-Blackwell

Polymer Engineering and Science 28 (1988), S. 1126-1131

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ISSN: 0032-3888

Schlagwort(e): Chemistry ; Chemical Engineering

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Maschinenbau , Physik

Notizen: Melt-mixed blends of polycarbonate/phenoxy were obtained before and after Interchange reactions by controlling the processing time. The dynamic mechanical analysis of the physical and reacted blends confirmed the immiscibility of the pair and the displacement of the glass-transition temperatures of the mixtures; this displacement was seen more clearly in the reacted mixtures, and at phenoxy-rich contents, even a single phase can appear. The exchange reactions resulted in a mechanical behavior that showed both a higher modulus and greater tensile strength in the reacted blends. The ductility was close to linearity for the physical blends and probably would be improved in the reacted mixture with a lower processing time.

Zusätzliches Material: 9 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pen.760281707

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6

Digitale Medien

Transitions and mechanical properties in polyoxymethylene/phenoxy blends (1996)

Erro, R. ; Gaztelumendi, M. ; Nazabal, J.

Bognor Regis [u.a.] : Wiley-Blackwell

Journal of Polymer Science Part B: Polymer Physics 34 (1996), S. 1055-1062

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ISSN: 0887-6266

Schlagwort(e): polyoxymethylene ; phenoxy ; transitions ; miscibility ; mechanical properties ; Chemistry ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Physik

Notizen: Blends of polyoxymethylene (POM) and phenoxy were obtained by melt-blending to determine their phase behavior and to determine, among others, their dynamic and static mechanical properties. The dynamic mechanical spectrum of POM showed an unusually wide peak below the melting temperature that was attributed to amorphous POM close to, and hindered by, the predominant crystalline phase. The Tg of phenoxy was constant with composition, as was probably that of POM, proving their complete immiscibility. The overall mechanical properties of the blends, however, were those of a compatible blend. The synergism in ductility observed in POM-poor blends was partially attributed to their lesser crystalline character. © 1996 John Wiley & Sons, Inc.

Zusätzliches Material: 9 Ill.

Materialart: Digitale Medien

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7

Digitale Medien

Phase behavior and miscibility limits in PC/hytrel blends (1995)

Gaztelumendi, M. ; Nazabal, J.

Bognor Regis [u.a.] : Wiley-Blackwell

Journal of Polymer Science Part B: Polymer Physics 33 (1995), S. 603-610

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ISSN: 0887-6266

Schlagwort(e): copolyetherester ; polycarbonate ; miscibility ; phase separation ; Chemistry ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Physik

Notizen: Polycarbonate of bisphenol-A (PC)/copolyetherester (Hy) blends have been obtained by melt mixing over the complete composition range. After testing the lack of interchange reactions and degradation under the conditions studied, the miscibility state was studied by DSC and DMTA. The blends appeared to be miscible in the melt state. A fairly complex phase behavior was obtained in the solid state with Tg-composition plots showing a single Tg at most of the compositions but very different after the first and second scans. This was attributed to the different crystalline content of the blends before the two scans. The presence of a Hy crystalline phase and a single PC/Hy amorphous phase in all the blends, with the exception of the 20/80 composition, was verified by DMTA. Several thermal treatments showed the presence of an immiscibility range and, thus, the presence of a UCST. A LCST, which in the case of the 50/50 and 40/60 blends would be at roughly 75°C, will also probably exist. © 1995 John Wiley & Sons, Inc.

Zusätzliches Material: 9 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/polb.1995.090330410

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