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  • 1
    Publikationsdatum: 2022-03-21
    Beschreibung: The Chew Bahir Drilling Project (CBDP) aims to test possible linkages between climate and evolution in Africa through the analysis of sediment cores that have recorded environmental changes in the Chew Bahir basin. In this statistical project we consider the Chew Bahir palaeolake to be a dynamical system consisting of interactions between its different components, such as the waterbody, the sediment beneath lake, and the organisms living within and around the lake. Recurrence is a common feature of such dynamical systems, with recurring patterns in the state of the system reflecting typical influences. Identifying and defining these influences contributes significantly to our understanding of the dynamics of the system. Different recurring changes in precipitation, evaporation, and wind speed in the Chew Bahir basin could result in similar (but not identical) conditions in the lake (e.g., depth and area of the lake, alkalinity and salinity of the lake water, species assemblages in the water body, and diagenesis in the sediments). Recurrence plots (RPs) are graphic displays of such recurring states within a system. Measures of complexity were subsequently introduced to complement the visual inspection of recurrence plots, and provide quantitative descriptions for use in recurrence quantification analysis (RQA). We present and discuss herein results from an RQA on the environmental record from six short (〈 17 m) sediment cores collected during the CBDP, spanning the last 45 kyrs. The different types of variability and transitions in these records were classified to improve our understanding of the response of the biosphere to climate change, and especially the response of humans in the area.
    Materialart: info:eu-repo/semantics/article
    Format: application/pdf
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Publikationsdatum: 2022-03-21
    Beschreibung: The use of cyclostratigraphy to reconstruct the timing of deposition of lacustrine deposits requires sophisticated tuning techniques that can accommodate continuous long-term changes in sedimentation rates. However, most tuning methods use stationary filters that are unable to take into account such long-term variations in accumulation rates. To overcome this problem we present herein a new multiband wavelet age modeling (MUBAWA) technique that is particularly suitable for such situations and demonstrate its use on a 293 m composite core from the Chew Bahir basin, southern Ethiopian rift. In contrast to traditional tuning methods, which use a single, defined bandpass filter, the new method uses an adaptive bandpass filter that adapts to changes in continuous spatial frequency evolution paths in a wavelet power spectrum, within which the wavelength varies considerably along the length of the core due to continuous changes in long-term sedimentation rates. We first applied the MUBAWA technique to a synthetic data set before then using it to establish an age model for the approximately 293 m long composite core from the Chew Bahir basin. For this we used the 2nd principal component of color reflectance values from the sediment, which showed distinct cycles with wavelengths of 10–15 and of ∼40 m that were probably a result of the influence of orbital cycles. We used six independent 40Ar/39Ar ages from volcanic ash layers within the core to determine an approximate spatial frequency range for the orbital signal. Our results demonstrate that the new wavelet-based age modeling technique can significantly increase the accuracy of tuned age models.
    Materialart: info:eu-repo/semantics/article
    Format: application/pdf
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Publikationsdatum: 2023-03-23
    Beschreibung: The Chew Bahir Drilling Project (CBDP) aims to test possible linkages between climate and hominin evolution in Africa through the analysis of sediment cores that have recorded environmental changes in the Chew Bahir basin (CHB). In this statistical project we used recurrence plots (RPs) together with a recurrence quantification analysis (RQA) to distinguish two types of variability and transitions in the Chew Bahir aridity record and compare them with the ODP Site 967 wetness index from the eastern Mediterranean. The first type of variability is one of slow variations with cycles of ∼20 kyr, reminiscent of the Earth’s precession cycle, and subharmonics of this orbital cycle. In addition to these cyclical wet-dry fluctuations in the area, extreme events often occur, i.e. short wet or dry episodes, lasting for several centuries or even millennia, and rapid transitions between these wet and dry episodes. The second type of variability is characterized by relatively low variation on orbital time scales, but significant century-millennium-scale variations with progressively increasing frequencies. Within this type of variability there are extremely fast transitions between dry and wet within a few decades or years, in contrast to those within Type 1 with transitions over several hundreds of years. Type 1 variability probably reflects the influence of precessional forcing in the lower latitudes at times with maximum values of the long (400 kyr) eccentricity cycle of the Earth’s orbit around the sun, with the tendency towards extreme events. Type 2 variability seems to be linked with minimum values of this cycle. There does not seem to be a systematic correlation between Type 1 or Type 2 variability with atmospheric CO2 concentration. The different types of variability and the transitions between those types had important effects on the availability of water, and could have transformed eastern Africa’s environment considerably, which would have had important implications for the shaping of the habitat of H. sapiens and the direct ancestors of this species.
    Materialart: info:eu-repo/semantics/article
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Springer
    Fresenius' Zeitschrift für analytische Chemie 162 (1958), S. 345-356 
    ISSN: 1618-2650
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Zusammenfassung Es wird ein papierchromatographisches Verfahren zur quantitativen Bestimmung des von Oxydkathoden abdampfenden Bariums und Strontiums angegeben. Unter den bekannten Lösungsmittelgemischen eignet sich Salzsäure-Methanol-Wasser am besten für die papierchromatographische Trennung der Abdampfprodukte. Die günstigsten Bedingungen zur Anfärbung des Chromatogramms mit Natriumrhodizonat werden angegeben. Die Chromatogramme werden bei 510 mμ, d. h. im Absorptionsmaximum des Strontiumrhodizonats bzw. in der Nähe des Absorptionsmaximums des Bariumrhodizonats photometriert. Die Auswertung ergibt eine gute Proportionalität zwischen den Barium-bzw. Strontiumkonzentrationen und den Extinktionsflächenwerten.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Springer
    Fresenius' Zeitschrift für analytische Chemie 109 (1937), S. 204-209 
    ISSN: 1618-2650
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Publikationsdatum: 2020-02-12
    Beschreibung: Terrestrial cosmogenic nuclide (TCN) concentrations in fluvial sediment, from which denudation rates are commonly inferred, can be affected by hillslope processes. TCN concentrations in gravel and sand may differ if localized, deep‐excavation processes (e.g. landslides, debris flows) affect the contributing catchment, whereas the TCN concentrations of sand and gravel tend to be more similar when diffusional processes like soil creep and sheetwash are dominant. To date, however, no study has systematically compared TCN concentrations in different detrital grain‐size fractions with a detailed inventory of hillslope processes from the entire catchment. Here we compare concentrations of the TCN 10Be in 20 detrital sand samples from the Quebrada del Toro (southern Central Andes, Argentina) to a hillslope‐process inventory from each contributing catchment. Our comparison reveals a shift from low‐slope gullying and scree production in slowly denuding, low‐slope areas to steep‐slope gullying and landsliding in fast‐denuding, steep areas. To investigate whether the nature of hillslope processes (locally excavating or more uniformly denuding) may be reflected in a comparison of the 10Be concentrations of sand and gravel, we define the normalized sand‐gravel index (NSGI) as the 10Be‐concentration difference between sand and gravel divided by their summed concentrations. We find a positive, linear relationship between the NSGI and median slope, such that our NSGI values broadly reflect the shift in hillslope processes from low‐slope gullying and scree production to steep‐slope gullying and landsliding. Higher NSGI values characterize regions affected by steep‐slope gullying or landsliding. We relate the large scatter in the relationship, which is exhibited particularly in low‐slope areas, to reduced hillslope‐channel connectivity and associated transient sediment storage within those catchments. While high NSGI values in well‐connected catchments are a reliable signal of deep‐excavation processes, hillslope excavation processes may not be reliably recorded by NSGI values where sediment experiences transient storage.
    Sprache: Englisch
    Materialart: info:eu-repo/semantics/article
    Format: application/pdf
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Publikationsdatum: 2020-02-12
    Beschreibung: Advances in cosmogenic nuclide exposure dating have made moraines valuable terrestrial recorders of palaeoclimate. A growing number of moraine chronologies reported from the Central Andes show that tropical glaciers responded sensitively to past changes in precipitation and temperature over timescales ranging from 103 to 105 years. However, the causes of past glaciation in the Central Andes remain uncertain. Explanations have invoked insolation-modulated variability in the strength of the South American Summer Monsoon, teleconnections with the North Atlantic Ocean, and/or cooling in the Southern Hemisphere. The driver for these past climate changes is difficult to identify, partly due to a lack of dated moraine records, especially in climatically sensitive areas of the southern Central Andes. Moreover, new constraints are needed on precisely where and when glaciers advanced. We use cosmogenic 10Be produced in situ to determine exposure ages for three generations of moraines at the Sierra de Aconquija, situated at 27°S on the eastern flank of the southern Central Andes. These moraines record glacier advances at approximately 22 ka and 40 ka, coincident with summer insolation maxima in the sub-tropics of the Southern Hemisphere, as well as at 12.5 ka and 13.5 ka during the Younger Dryas and the Antarctic Cold Reversal, respectively. We also identify minor glaciation during Bond Event 5, also known as the 8.2 ka event. These moraines register past climate changes with high fidelity, and currently constitute the southernmost dated record of glaciation on the eastern flank of the Central Andes. To contextualise these results, we compile 10Be data reported from 144 moraines in the eastern Central Andes that represent past glacier advances. We re-calculate exposure ages from these data using an updated reference production rate, and we re-interpret the moraine ages by taking the oldest clustered boulder age (after the exclusion of outliers attributed to nuclide inheritance) as closest to the timing of glacier advance—an approach for which we provide empirical justification. This compilation reveals that Central Andean glaciers have responded to changes in temperature and precipitation. We identify cross-latitude advances in phase with insolation cycles, the last global glacial maximum, and episodes of strengthened monsoonal moisture transport including the Younger Dryas and Heinrich Stadials 1 and 2. Our results from the Sierra de Aconquija allow us to constrain the southerly limit of enhanced precipitation associated with Heinrich Stadials at ∼25°S. More broadly, our findings demonstrate at both local and regional scales that moraines record past climate variability with a fine spatial and temporal resolution.
    Sprache: Englisch
    Materialart: info:eu-repo/semantics/article
    Format: application/pdf
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Publikationsdatum: 2021-09-07
    Beschreibung: Carbon dioxide is the most abundant, non-condensable gas in volcanic systems, released into the atmosphere through either diffuse or advective fluid flow. The emission of substantial amounts of CO2 at Earth’s surface is not only controlled by volcanic plumes during periods of eruptive activity or fumaroles, but also by soil degassing along permeable structures in the subsurface. Monitoring of these processes is of utmost importance for volcanic hazard analyses, and is also relevant for managing geothermal resources. Fluid-bearing faults are key elements of economic value for geothermal power generation. Here, we describe for the first time how sensitively and quickly natural gas emissions react to changes within a deep hydrothermal system due to geothermal fluid reinjection. For this purpose, we deployed an automated, multi-chamber CO2 flux monitoring system within the damage zone of a deep-rooted major normal fault in the Los Humeros Volcanic Complex (LHVC) in Mexico and recorded data over a period of five months. After removing the atmospheric effects on variations in CO2 flux, we calculated correlation coefficients between residual CO2 emissions and reinjection rates, identifying an inverse correlation of ρ = -0.51 to -0.66. Our results indicate that gas emissions respond to changes in reinjection rates within 24 hours, proving an active hydraulic communication between the hydrothermal system and Earth’s surface. This finding is a promising indication not only for geothermal reservoir monitoring but also for advanced long-term volcanic risk analysis. Response times allow for estimation of fluid migration velocities, which is a key constraint for conceptual and numerical modelling of fluid flow in fracture-dominated systems.
    Sprache: Englisch
    Materialart: info:eu-repo/semantics/workingPaper
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Publikationsdatum: 2021-09-16
    Beschreibung: Carbon dioxide is the most abundant, non-condensable gas in volcanic systems, released into the atmosphere through either diffuse or advective fluid flow. The emission of substantial amounts of CO2 at Earth’s surface is not only controlled by volcanic plumes during periods of eruptive activity or fumaroles, but also by soil degassing along permeable structures in the subsurface. Monitoring of these processes is of utmost importance for volcanic hazard analyses, and is also relevant for managing geothermal resources. Fluid-bearing faults are key elements of economic value for geothermal power generation. Here, we describe for the first time how sensitively and quickly natural gas emissions react to changes within a deep hydrothermal system due to geothermal fluid reinjection. For this purpose, we deployed an automated, multi-chamber CO2 flux monitoring system within the damage zone of a deep-rooted major normal fault in the Los Humeros Volcanic Complex (LHVC) in Mexico and recorded data over a period of five months. After removing the atmospheric effects on variations in CO2 flux, we calculated correlation coefficients between residual CO2 emissions and reinjection rates, identifying an inverse correlation of ρ = − 0.51 to − 0.66. Our results indicate that gas emissions respond to changes in reinjection rates within 24 h, proving an active hydraulic communication between the hydrothermal system and Earth’s surface. This finding is a promising indication not only for geothermal reservoir monitoring but also for advanced long-term volcanic risk analysis. Response times allow for estimation of fluid migration velocities, which is a key constraint for conceptual and numerical modelling of fluid flow in fracture-dominated systems.
    Materialart: info:eu-repo/semantics/article
    Format: application/pdf
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Publikationsdatum: 2020-06-18
    Sprache: Englisch
    Materialart: info:eu-repo/semantics/conferenceObject
    Standort Signatur Erwartet Verfügbarkeit
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