ALBERT

Description: Large igneous provinces (LIPs) are proposed to have caused a number of episodes of abrupt environmental change by increasing atmospheric CO 2 levels, which were subsequently alleviated by drawdown of CO 2 via enhanced continental weathering and burial of organic matter. Here the sedimentary records of two such episodes of environmental change, the Toarcian oceanic anoxic event (T-OAE) and preceding Pliensbachian–Toarcian (Pl-To) event (both possibly linked to the Karoo-Ferrar LIP), are investigated using a new suite of geochemical proxies that have not been previously compared. Stratigraphic variations in osmium isotope ( 187 Os/ 188 Os) records are compared with those of mercury (Hg) and carbon isotopes ( 13 C) in samples from the Mochras core, Llanbedr Farm, Cardigan Bay Basin, Wales. These sedimentary rocks are confirmed as recording an open-marine setting by analysis of molybdenum/uranium enrichment trends, indicating that the Os isotope record in these samples reflects the isotopic composition of the global ocean. The Os isotope data include the first results across the Pl-To boundary, when seawater 187 Os/ 188 Os increased from ~0.40 to ~0.53, in addition to new data that show elevated 187 Os/ 188 Os (from ~0.42 to ~0.68) during the T-OAE. Both increases in 187 Os/ 188 Os correlate with negative carbon isotope excursions and increased mercury concentrations, supporting an interplay between terrestrial volcanism, weathering, and climate that was instrumental in driving these distinct episodes of global environmental change. These observations also indicate that the environmental impact of the Karoo-Ferrar LIP was not limited solely to the T-OAE.

Description: : The Steptoean Positive Carbon Isotope Excursion (SPICE) of earliest late Cambrian (Furongian) age is identified in England. The excursion is found within a c . 145 m thick siliciclastic succession within the middle and higher part of the Outwoods Shale Formation of Warwickshire, and reaches a maximum 13 C org amplitude of 4.1 at values of –25.6. Biostratigraphical data show that the excursion occupies the greater part of the Olenus Biozone, an equivalent of the Glyptagnostus reticulatus Biozone that marks the base of the Furongian and coeval base of the Steptoean in North America. The amplitude of the excursion approaches that recorded in limestone-dominated Laurentian successions, and is greater than that recently documented for organic-rich mudstones of palaeocontinental Baltica in southern Sweden. A minor positive excursion above the SPICE may equate with a similar excursion recognized in Siberia. The SPICE in the Outwoods Shale Formation seems closely linked to the widely recognized early Furongian eustatic sea-level rise. There is no evidence in the English succession for slightly later regression, elsewhere considered coincident with the peak of the excursion and pivotal to some previous models explaining the SPICE. Supplementary material: Analytical results, including total organic carbon (TOC) values for each sample, are available at www.geolsoc.org.uk/SUP18455 .

Description: A multiproxy record from Lake Parishan, SW Iran, shows human impact on the lake and its catchment over the last 4000 years. The Parishan record provides evidence of changes in lake hydrology, from ostracod, diatom and isotope analyses, that are directly linked to human activity in the catchment; recorded by pollen and charcoal and supported by regional archaeological and historical data. The lake ostracod fauna is particularly sensitive to human-induced catchment alterations and allows us to identify changes in catchment hydrology that are due to more than a simple change in precipitation: evaporation state. Oxygen isotope data from endogenic carbonates follow these faunal changes but also display a longer trend to more positive values through the period, coincident with regional patterns of water balance for the late-Holocene in the eastern Mediterranean.

Description: Understanding the mid-Holocene dynamics of the East Asian monsoon (EAM) is integral to improving models of the Holocene development of the global climate system. Here we reconstruct the mid-Holocene EAM history from the Pearl River estuary, southern China, using bulk organic carbon isotopes ( 13 C), total carbon to total nitrogen (C/N) ratios and total organic carbon (TOC) concentration. Sedimentary 13 C, C/N and TOC are potentially good indicators of changes in monsoonal precipitation strength. Sediments buried during a period of high precipitation exhibit a high proportion of terrigenous material, and have low 13 C and high C/N, and vice versa during a period of low precipitation. Results suggest a general decreasing trend in monsoonal precipitation from 6650 to 2150 cal. yr BP because of the weakening Northern Hemisphere insolation most likely related to the current precession circle. Superimposed on this trend are apparent dry–wet oscillations at centennial to millennial timescales most likely in response to solar activity. Mismatches between our 13 C record and results from the Dongge Cave in southern China at millennial timescales may indicate that the 13 C from the Pearl River estuary reveals changes in precipitation over a broader area than the 18 O from Dongge Cave.

Description: : Three dated (U–Pb, zircon) ash beds from biostratigraphically constrained Avalonian successions of Shropshire (England) and Pembrokeshire (Wales) delimit the traditional ‘Lower'–‘Middle' Cambrian boundary and resolve a problematic regional correlation. In Shropshire, a date of 514.45 ± 0.36 [0.81 including tracer calibration and 238 U decay constant errors] Ma from near the top of the Lower Comley Sandstone Formation provides a maximum age for the boundary between Cambrian Stages 3 and 4, and a date of 509.10 ± 0.22 [0.77 including tracer calibration and 238 U decay constant errors] Ma from the basal Quarry Ridge Grits, Upper Comley Sandstone Formation, provides a minimum age for the boundary between Cambrian Stages 4 and 5 (and thus Series 2 and 3). These dates offer a calibration of early metazoan evolution by directly constraining the age of the intervening Comley Limestones, which contain diverse small shelly fossils in addition to trilobites, and also a key early occurrence of exceptional, three-dimensionally preserved arthropods. In Pembrokeshire, an ash bed from the Caerfai Bay Shales Formation dates to 519.30 ± 0.23 [0.77 including tracer calibration and 238 U decay constant errors] Ma, equivalent to a horizon low in the Lower Comley Sandstone Formation of Shropshire, possibly around the level at which trilobites make their first local appearance. Supplementary material: Appendix 1, a table of isotope data, is available at http://www.geolsoc.org.uk/SUP18444 .

Description: Late Cenozoic climate history in Africa was punctuated by episodes of variability, characterized by the appearance and disappearance of large freshwater lakes within the East African Rift Valley. In the Baringo-Bogoria basin, a well-dated sequence of diatomites and fluviolacustrine sediments documents the precessionally forced cycling of an extensive lake system between 2.70 Ma and 2.55 Ma. One diatomite unit was studied, using the oxygen isotope composition of diatom silica combined with X-ray fluorescence spectrometry and taxonomic assemblage changes, to explore the nature of climate variability during this interval. Data reveal a rapid onset and gradual decline of deepwater lake conditions, which exhibit millennial-scale cyclicity of ~1400–1700 yr, similar to late Quaternary Dansgaard-Oeschger events. These cycles are thought to reflect enhanced precipitation coincident with increased monsoonal strength, suggesting the existence of a teleconnection between the high latitudes and East Africa during this period. Such climatic variability could have affected faunal and floral evolution at the time.

Description: The Paleocene–Eocene Thermal Maximum (PETM), ca. 56 Ma, was a major global environmental perturbation attributed to a rapid rise in the concentration of greenhouse gases in the atmosphere. Geochemical records of tropical sea-surface temperatures (SSTs) from the PETM are rare and are typically affected by post-depositional diagenesis. To circumvent this issue, we have analyzed oxygen isotope ratios ( 18 O) of single specimens of exceptionally well-preserved planktonic foraminifera from the PETM in Tanzania (~19°S paleolatitude), which yield extremely low 18 O, down to 〈–5. After accounting for changes in seawater chemistry and pH, we estimate from the foraminifer 18 O that tropical SSTs rose by 〉3 °C during the PETM and may have exceeded 40 °C. Calcareous plankton are absent from a large part of the Tanzania PETM record; extreme environmental change may have temporarily caused foraminiferal exclusion.

Description: The dispersal of human populations out of Africa into Arabia was most likely linked to episodes of climatic amelioration, when increased monsoon rainfall led to the activation of drainage systems, improved freshwater availability, and the development of regional vegetation. Here we present the first dated terrestrial record from southeast Arabia that provides evidence for increased rainfall and the expansion of vegetation during both glacial and interglacial periods. Findings from extensive alluvial fan deposits indicate that drainage system activation occurred during Marine Isotope Stage (MIS) 6 (ca. 160–150 ka), MIS 5 (ca. 130–75 ka), and during early MIS 3 (ca. 55 ka). The development of active freshwater systems during these periods corresponds with monsoon intensity increases during insolation maxima, suggesting that humid periods in Arabia were not confined to eccentricity-paced deglaciations, and providing paleoenvironmental support for multiple windows of opportunity for dispersal out of Africa during the late Pleistocene.

Description: We present measurements of Sr/Ca, 18 O, and spectral luminescence ratios (G/B) from a mid-Holocene Porites sp. microatoll recovered from the nearshore Great Barrier Reef (GBR). These records were used as proxies to reconstruct sea surface temperature (SST), the 18 O of surrounding seawater ( 18 O sw ), and riverine influence, respectively, and compared with records from a modern Porites sp. microatoll growing in the same environment. Strong riverine influence in the mid-Holocene record is indicated by (1) an increased annual 18 O sw range in the mid-Holocene record, (2) negative peaks in 18 O characteristic of flood events, and (3) a higher G/B luminescence ratio. Seasonal cycles in G/B suggest that humic acid inputs were elevated for a longer portion of the year during the mid-Holocene. The seasonal cycle of 18 O sw peaked earlier in the year in the mid-Holocene record relative to the modern, while mean 18 O sw values from the mid-Holocene record were similar to modern values. These records provide an insight into the oceanographic conditions the nearshore GBR experienced during mid-Holocene climatic shifts and are consistent with a strong Australian–Indonesian Summer Monsoon (AISM) system at ~ 4700 cal. yr BP.

Description: A BSTRACT :  Deep-water mudstones from ancient epicontinental settings are significant repositories for organic matter, but the detailed temporal variations of, and controls on, the abundance and type of organic matter (OM) is little studied. Using micro-petrographic and geochemical data from late Mississippian mudstones of the Widmerpool Gulf, UK, the processes that delivered fine-grained sediment to this basin during a glacioeustatic sea-level cycle are interpreted from detailed lithofacies analysis. Seven primary lithofacies are identified from core, which show specific and systematic variations in total organic carbon (TOC) content and bulk carbon isotope composition of organic material ( 13 C org ). During sea-level highstands, thin-bedded carbonate-bearing mudstones are the dominant facies deposited, contain up to 6.6% TOC (average 4.6 ± 1.3%), and have mean 13 C org of –28.5 ± 0.9. During phases of lower sea level, thin-bedded silt-bearing clay-rich mudstones with up to 4.1% TOC (average 2.3 ± 0.8%; mean 13 C org : –28.2 ± 1.0) were interbedded with more organic-lean graded silt-bearing mudstones and sand-bearing silt-rich mudstones (average TOC: 1.7 ± 0.6%) derived from turbidity currents. The latter (mean 13 C org : –26.2 ± 0.7) are closely linked to significant proportions of terrestrial plant material, while some rare plant debris- and sand-bearing mudstones produced from debris flows have more than 7.0% TOC and 13 C org ≥ –26.0. The 13 C values of wood fragments ranged from –27.1 to –24.0 and therefore the 13 C org is interpreted as a function of the ratio of marine and terrestrial organic matter. More negative values in the carbonate-bearing and the clay-rich mudstones indicate marine planktonic algae whereas the least negative values reflect greater contribution of terrestrial plant material. The data suggest that the marine conditions prevailed and supported marine planktonic algae throughout different sea-level stages. Marine OM was delivered to the sea floor by continuous hemipelagic settling whereas terrestrial OM was delivered by sediment density flows. Variations in bioproductivity and dilution by siliciclastics influenced the burial rate of marine OM. Organic-rich mudstones preserved in these marine basins are potential hydrocarbon source rocks, especially as unconventional (shale gas) reservoirs. Detailed microtextural and compositional analysis coupled with rigorous geochemical parameters as used in this study are important for the understanding of the source-rock potential of basinal mudstones, and of fine-grained organic-rich sediments in general.