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  • 1
    Publication Date: 2022-12-10
    Description: Faults and fractures can be permeable pathways for focused fluid flow in structurally controlled ore‐forming hydrothermal systems. However, quantifying their role in fluid flow on the scale of several kilometers with numerical models typically requires high‐resolution meshes. This study introduces a modified numerical representation of m‐scale fault zones using lower‐dimensional elements (here, one‐dimensional [1D] elements in a 2D domain) to resolve structurally controlled fluid flow with coarser mesh resolutions and apply the method to magmatic‐hydrothermal ore‐forming systems. We modeled horizontal and vertical structure‐controlled magmatic‐hydrothermal deposits to understand the role of permeability and structure connectivity on ore deposition. The simulation results of vertically extended porphyry copper systems show that ore deposition can occur along permeable vertical structures where ascending, overpressured magmatic fluids are cooled by downflowing ambient fluids. Structure permeability and fault location control the distribution of ore grades. In highly permeable structures, the mineralization can span up to 3 km vertically, resulting in heat‐pipe mechanisms that promote the ascent of a magmatic vapor phase to an overlying structurally controlled epithermal system. Simulations for the formation of subhorizontal vein‐type deposits suggest that the major control on fluid flow and metal deposition along horizontal structures is the absence of vertical structures above the injection location but their presence at greater distances. Using a dynamic permeability model mimicking crack‐seal mechanisms within the structures leads to a pulsating behavior of fracture‐controlled hydrothermal systems and prevents the inflow of ambient fluids under overpressured conditions.
    Description: Plain Language Summary: Faults and fractures can serve as permeable pathways for focused fluid flow in the subsurface and therefore be essential geological features for the formation of economic mineral deposits. However, quantifying their role in the hydrothermal systems on the scale of several kilometers with numerical models typically requires high‐resolution meshes. This study presents a modified numerical representation of m‐scale fault zones with variable orientations to understand the hydrology of magmatic‐hydrothermal ore‐forming systems. The vertically extended systems simulation results show that ore deposition can occur along permeable vertical structures where ascending magmatic fluids are cooled by downflowing ambient fluids. Structure permeability and fault location can directly control the distribution of ore grades. In contrast, mineralization in horizontal structures requires the absence of vertical structures above the injection location of metal‐bearing magmatic volatiles but their presence at greater distances. Our model also shows how dynamic opening and closing of the structures in response to magmatic degassing can lead to a pulsating behavior and prevent the downflow of ambient fluids.
    Description: Key Points: We describe structurally controlled fluid flow by representing faults and fractures as one‐dimensional line elements within a 2D modeling domain. Vertical structures are efficient pathways for focused fluid flow and formation of high‐grade mineralization. Ore formation in horizontal fractures requires a hydraulic connection to distal vertical fault zones.
    Description: German Federal Ministry of Education and Research
    Description: Deutsche Forschungsgemeinschaft, DFG http://dx.doi.org/10.13039/501100001659
    Description: Helmholtz Recruitment Initiative
    Keywords: ddc:551 ; magmatic‐hydrothermal systems ; ore deposits ; fluid flow ; numerical simulations ; faults and fractures
    Language: English
    Type: doc-type:article
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  • 2
    Publication Date: 2023-01-21
    Description: Closure of the Central American Seaway (CAS) and hydrology of the Caribbean Sea triggered Northern Hemisphere Glaciation and played an important role in the Pliocene to modern‐day climate re‐establishing the deep and surface ocean currents. New data on Mn/Ca obtained with femtosecond laser ablation inductively coupled plasma mass spectrometry on well‐preserved tests of the epibenthic foraminifer Cibicidoides wuellerstorfi and infaunal C. mundulus contribute to the interpretation of paleoenvironmental conditions of the Caribbean Sea between 5.2 and 2.2 Ma (million years) across the closure of the CAS. Hydrothermal activity at the Lesser Antilles may be a primary source of Mn in the well‐oxygenated Plio‐Pleistocene Caribbean Sea. Incorporation of Mn in the benthic foraminifer shell carbonate is assumed to be affected by surface ocean nutrient cycling, and may hence be an indicator of paleoproductivity.
    Description: Plain Language Summary: The closure of the Panama Isthmus caused the expansion of ice sheets in the Northern Hemisphere and changed the water current dynamics and climate in the Caribbean Sea since the Pliocene (∼5.3 million years ago). New Mn/Ca data measured using femtosecond laser ablation inductively coupled plasma mass spectrometry on the deep‐sea benthic foraminifer species Cibicidoides wuellerstorfi and Cibicidoides mundulus help us understand past environmental conditions of the Caribbean Sea prevailed between 5.2 and 2.2 million years ago. While manganese might be sourced from the surrounding hydrothermal vents, its incorporation in the foraminifer shell carbonate might be related to nutrient cycling and may indicate past biological productivity in the ocean.
    Description: Key Points: Femtosecond‐laser ablation inductively coupled plasma mass spectrometry provides a new approach on distinguishing Mn of the ontogenetic shell calcite from Mn of the authigenic coatings. Ontogenetic Mn within the foraminifer shell calcite may result from the regional nutrient cycle. Mn in the deep eastern Caribbean Sea may mainly derive from hydrothermal sources along the Antilles Island Arc.
    Description: MPIC
    Description: https://doi.org/10.17632/bps7nw7922.1
    Keywords: ddc:560 ; manganese ; Cibicidoides wuellerstorfi ; Cibicidoides mundulus ; Central American Seaway ; trace elements ; hydrothermal ; paleoproductivity
    Language: English
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  • 3
    Publication Date: 2024-02-21
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The Mg/Ca of marine calcareous Planktic Foraminifera (PF) shells is commonly used for sea surface temperature reconstructions. However, compared to open marine environments, hypersaline (>40) oligotrophic seas have been shown to accommodate PF with higher Mg/Ca and divergent temperature to Mg/Ca relationships. To investigate influencing factors of PF Mg uptake in hypersaline regions, we measured the Mg/Ca of two flux‐dominating PF species, 〈italic〉Globigerinoides ruber albus〈/italic〉 and 〈italic〉Turborotalita clarkei〈/italic〉, derived from a monthly resolved time series of sediment traps in the Gulf of Aqaba, northern Red Sea as well as the corresponding temperature, salinity, and 〈italic〉p〈/italic〉H values. The PF exhibit elevated Mg/Ca which cannot be explained by post‐deposition or interstitial sediment diagenetic processes. 〈italic〉G. ruber albus〈/italic〉 displays Mg/Ca trends that strongly follow seasonal mixed layer temperature changes. Conversely, 〈italic〉T〈/italic〉. 〈italic〉clarkei〈/italic〉 Mg/Ca trends do not follow temperature but rather show significant Mg/Ca enrichment following mixing of the surface water column. We present a framework for incorporating elevated Mg/Ca into global Mg/Ca‐T calibrations for 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉 and present a new Mg/Ca‐T calibration suitable for hypersaline marine environments.〈/p〉
    Description: Plain Language Summary: Past seawater temperature is reconstructed from the magnesium‐to‐calcium ratio (Mg/Ca) in the calcareous shells of a group of marine microplankton called foraminifera. Two foraminifer species, 〈italic〉Globigerinoides ruber albus〈/italic〉 and 〈italic〉Turborotalita clarkei〈/italic〉, are abundant in the Gulf of Aqaba, northern Red Sea, at year‐round high temperatures and salinities. The shells of these foraminifera have elevated Mg/Ca relative to other marine regions, and here, we explore the factors causing this. The Mg/Ca values of both 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉 and 〈italic〉T〈/italic〉. 〈italic〉clarkei〈/italic〉 reflect the environmental conditions of the water column. For 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉, temperature and salinity appear to be factors responsible for the Mg/Ca trends and elevated values. We incorporate the new Mg/Ca data for 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉 to calibrate elevated Mg/Ca with temperature for high‐salinity (>40) marine environments. The Mg/Ca of the deeper dwelling 〈italic〉T〈/italic〉. 〈italic〉clarkei〈/italic〉 show higher ratios following deep mixing of the surface water column and may indicate annually recurring phytoplankton blooms caused by nutrient input into the sunlit ocean surface.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉A new Mg/Ca temperature calibration for high salinity environments is presented for 〈italic〉Globigerinoides ruber albus〈/italic〉〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉A framework for incorporating high salinity environments into global Mg/Ca‐T calibrations is provided〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Enhanced Mg/Ca in subsurface dwelling 〈italic〉Turborotalita clarkei〈/italic〉 may indicate seasonal deep mixing of the upper water column〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Israel Science Foundation http://dx.doi.org/10.13039/501100003977
    Description: Minerva PhD Fellowship Stipend
    Description: Advance School for Environmental Studies
    Description: https://doi.org/10.1594/PANGAEA.959629
    Description: https://doi.org/10.17617/3.EXFQC2
    Keywords: ddc:551.9 ; Gulf of Aqaba ; Planktic Foraminifera shells ; Mg/Ca ; sea surface temperature reconstructions
    Language: English
    Type: doc-type:article
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  • 4
    Publication Date: 2017-07-21
    Description: This paper contains the results of an extensive isotopic study of United States Geological Survey GSD-1G and MPI-DING reference glasses. Thirteen different laboratories were involved using high-precision bulk (TIMS, MC-ICP-MS) and microanalytical (LA-MC-ICP-MS, LA-ICP-MS) techniques. Detailed studies were performed to demonstrate the large-scale and small-scale homogeneity of the reference glasses. Together with previously published isotopic data from ten other laboratories, preliminary reference and information values as well as their uncertainties at the 95% confidence level were determined for H, O, Li, B, Si, Ca, Sr, Nd, Hf, Pb, Th and U isotopes using the recommendations of the International Association of Geoanalysts for certification of reference materials. Our results indicate that GSD-1G and the MPI-DING glasses are suitable reference materials for microanalytical and bulk analytical purposes.
    Type: Article , PeerReviewed
    Format: text
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  • 5
    Publication Date: 2021-07-21
    Description: Amphistegina are common larger benthic foraminifer in coral reefs, with a nearly circumtropical distribution, and are major contributors to the CaCO3 budget of shallow marine environments. The family Amphisteginidae is dominant in Cenozoic carbonates. However, its potential as a proxy for paleoclimate reconstruction has not been completely explored. The intratest variability in trace elements of Amphistegina lessonii has been investigated using femtosecond‐laser ablation‐inductively coupled plasma‐mass spectrometry (fs‐LA‐ICP‐MS). We collected and analyzed adult specimens of A. lessonii in September 2003, November 2003, January 2004, and March 2004, from ∼2 m water depth in the coral reefs of Akajima, Okinawa, Japan. Tests of A. lessonii from these four collections were analyzed for Mg/Ca of the septa to observe Test Size‐Lifespan relationships. The lifespan of a specimen of A. lessonii of 1,200 µm in diameter is estimated at ∼3 and ∼2 months for specimens 900 µm in size. Over the estimated lifespans, Mg/Ca of individual specimens of A. lessonii is highly variable and displays co‐variation with temperature and tidal heights. Future projects may apply and further test this approach for the reconstruction of the tropical shallow marine paleoenvironments.
    Description: Plain Language Summary: Larger Benthic Foraminifera (LBF) have slow growth rates and can be used as a proxy to reconstruct seasonal variations in temperature. Amphistegina, a common genus of LBF found within the Cenozoic era including the past 55 million years, was sampled across four seasons from a modern coral reef of Okinawa, Japan. The trace element concentrations in nine specimens of A. lessonii were measured using femtosecond LA‐ICP‐MS. The intratest variation in Mg/Ca covaried with tidal heights and seawater temperature, assuming the ages of the specimens to be 2–3 months. We provide a temperature calibration equation for A. lessonii for reconstructing paleotemperatures of shallow marine environments of the Cenozoic.
    Description: Key Points: Specimens of Amphistegina lessonii sampled across 4 months from Akajima are used for calibration for Mg/Ca temperature using femtosecond‐laser ablation‐inductively coupled plasma‐mass spectrometry. The Mg/Ca along the septa of A. lessonii covaries with seawater temperature and tidal heights while Na/Ca and Sr/Ca show no correlation. Intratest variations in Mg/Ca of A. lessonii are affected by light intensity attenuation by sediment re‐suspension caused by tidal currents.
    Keywords: 551.9 ; Amphistegina lessonii ; fs‐LA‐ICP‐MS ; sea‐surface temperature ; tidal heights ; trace elements
    Type: article
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  • 6
    Publication Date: 2021-06-30
    Description: This bibliographic review gives an outline of publications in 2019 focusing on reference materials (RMs) used in geochemistry and related fields, such as palaeoclimate and environmental research.
    Description: Key Points: Literature review for 2019 of 6850 geoanalytical publications. Geochemical, environmental, palaeoclimatic and isotopic reference materials. 691 selected articles with summaries of target analytes, and relevant reference materials and producers. image
    Keywords: 551.9 ; Analytical techniques ; Certified values ; In situ techniques ; Mass spectrometry ; Microanalysis ; Reference materials ; Stable isotopes
    Type: article
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  • 7
    Publication Date: 2021-07-01
    Description: Abstract High‐resolution analysis of the late Pliensbachian – early Toarcian belemnite assemblages from the Peniche section (Lusitanian Basin) has enabled, for the first time, recognition of eight taxa of the suborder Belemnitina, previously reported from contemporaneous north‐west Tethyan and Arctic sections. The presence of Bairstowius amaliae sp. nov. in the late Pliensbachian (emaciatum Zone) represents a novelty given that hitherto the genus Bairstowius was known only from late Sinemurian and early Pliensbachian deposits. Additionally, the replacement of Bairstowius amaliae by Catateuthis longiforma, during the latest Pliensbachian, suggests an evolutionary relationship between the two taxa. This relationship suggests a new scenario for the subsequent development of endemic Toarcian Boreal–Arctic faunas, characterized by the occurrence of Catateuthis. Comparison of the Peniche belemnite fauna with coeval faunas from the Mediterranean/Submediterranean and Euro‐Boreal domains indicates taxonomic uniformity during the late Pliensbachian and early Toarcian (emaciatum and polymorphum Zones), in the north‐west Tethys. Despite the lack of a marked taxonomic turnover, the Pliensbachian–Toarcian boundary corresponds to a slight decrease in diversity observed not only in the Lusitanian Basin but also in coeval north‐western European basins. Ordination and cluster analyses indicate that the largest changes in belemnite diversity and palaeogeographical distribution occurred rather during the Toarcian Oceanic Anoxic Event (base of the levisoni Zone). This event is marked by the extinction of taxa, affecting more severely the Mediterranean/Submediterranean domain and resulting in a more pronounced provincial differentiation among north‐western European and Arctic belemnite faunas.
    Description: DFG Research Unit FOR 2332
    Description: IUGS–UNESCO
    Keywords: 564.5 ; belemnite ; diversity ; palaeobiogeography ; Pliensbachian–Toarcian boundary ; Toarcian Oceanic Anoxic Event ; Lusitanian Basin
    Type: article
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  • 8
    Publication Date: 2022-10-19
    Description: Key Points: Literature review of 7200 geoanalytical publications for the year 2020. 628 selected articles with summaries of target analytes, relevant reference materials and producers. Selected publications include data obtained by new analytical developments and improved analytical protocols for established RMs, and identifies recently developed RMs for specific scientific topics. image
    Description: This bibliographic review gives an overview of scientific publications in 2020 that contribute important data for geoanalytical reference materials (RMs).
    Keywords: ddc:551.9
    Language: English
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  • 9
    Publication Date: 2023-11-24
    Description: This GGR Bibliographic Review is a survey of approximately 5200 geoanalytical publications for the year 2021. Selected articles, numbering over 340, containing measurement results for relevant geological and environmental reference materials are listed with individual summaries of target analytes, relevant reference materials and producers. A brief summary of a selection of these publications is included that highlights notable developments in geoanalytical studies, newly developed or characterised RMs, and new datasets of established reference materials that have been re‐analysed using improved or state‐of‐the‐art measurement techniques.
    Description: Key Points: Literature review of 5200 geoanalytical publications for the year 2021. 344 selected articles with summaries of target analytes, relevant reference materials and producers. Selected publications include data obtained by new analytical developments and improved analytical protocols for established RMs, and identifies recently developed RMs for specific scientific topics.
    Description: http://georem.mpch-mainz.gwdg.de/
    Keywords: ddc:550 ; review ; analytical geochemistry ; geochemical reference materials ; reference material data ; GeoReM database ; environmental reference materials
    Language: English
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  • 10
    Publication Date: 2018-06-06
    Description: We present an analysis of the visible through near infrared spectrum of Eta Car and its ejecta obtained during the "Eta Car Campaign with the Ultraviolet and Visual Echelle Spectrograph (UVES) at the ESO Very Large Telescope (VLT)". This is a part of the larger effort to present a complete Eta Car spectrum, and extends the previously presented analyses with the Hubble Space Telescope/Space Telescope Imaging Spectrograph (HST/STIS) in the UV (1240-3159 Angstrom) to 10,430 Angstrom. The spectrum in the mid and near UV is characterized by the ejecta absorption. At longer wavelengths, stellar wind features from the central source and narrow emission lines from the Weigelt condensations dominate the spectrum. However, narrow absorption lines from the circumstellar shells are present. This paper provides a description of the spectrum between 3060 and 10,430 Angstroms, including line identifications of the ejecta absorption spectrum, the emission spectrum from the Weigelt condensations and the P-Cygni stellar wind features. The high spectral resolving power of VLT/UVES enables equivalent width measurements of atomic and molecular absorption lines for elements with no transitions at the shorter wavelengths. However, the ground based seeing and contributions of nebular scattered radiation prevent direct comparison of measured equivalent widths in the VLT/UVES and HST/STIS spectra. Fortunately, HST/STIS and VLT/UVES have a small overlap in wavelength coverage which allows us to compare and adjust for the difference in scattered radiation entering the instruments' apertures. This paper provides a complete online VLT/UVES spectrum with line identifications and a spectral comparison between HST/STIS and VLT/UVES between 3060 and 3160 Angstroms.
    Keywords: Astrophysics
    Format: application/pdf
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