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  • 1
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    Extraction processes for the production of aluminum, titanium, iron, magnesium, and oxygen and nonterrestrial sources (1979)
    In:  CASI
    Details
    Publication Date: 2006-01-12
    Description: The suitability of existing terrestrial extractive metallurgical processes for the production of Al, Ti, Fe, Mg, and O2 from nonterrestrial resources is examined from both thermodynamic and kinetic points of view. Carbochlorination of lunar anorthite concentrate in conjunction with Alcoa electrolysis process for Al; carbochlorination of lunar ilmenite concentrate followed by Ca reduction of TiO2; and subsequent reduction of Fe2O3 by H2 for Ti and Fe, respectively, are suggested. Silicothermic reduction of olivine concentrate was found to be attractive for the extraction of Mg becaue of the technological knowhow of the process. Aluminothermic reduction of olivine is the other possible alternative for the production of magnesium. The large quantities of carbon monoxide generated in the metal extraction processes can be used to recover carbon and oxygen by a combination of the following methods: (1) simple disproportionation of CO,(2) methanation of CO and electrolysis of H2O, and (3) solid-state electrolysis of gas mixtures containing CO, CO2, and H2O. The research needed for the adoption of earth-based extraction processes for lunar and asteroidal minerals is outlined.
    Keywords: ASTRONAUTICS (GENERAL)
    Type: NASA. Ames Res. Center Space Resources and Space Settlements; p 257-274
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  • 2
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    Mining and beneficiation of lunar ores (1979)
    In:  CASI
    Details
    Publication Date: 2006-01-12
    Description: The beneficiation of lunar plagioclase and ilmenite ores to feedstock grade permits a rapid growth of the space manufacturing economy by maximizing the production rate of metals and oxygen. A beneficiation scheme based on electrostatic and magnetic separation is preferred over conventional schemes, but such a scheme cannot be completely modeled because beneficiation processes are empirical and because some properties of lunar minerals have not been measured. To meet anticipated shipping and processing needs, the peak lunar mining rate will exceed 1000 tons/hr by the fifth year of operation. Such capabilities will be best obtained by automated mining vehicles and conveyor systems rather than trucks. It may be possible to extract about 40 kg of volatiles (60 percent H2O) by thermally processing the less than 20 micron ilmenite concentrate extracted from 130 tons of ilmenite ore. A thermodynamic analysis of an extraction process is presented.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Space Resources and Space Settlements; p 275-288
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  • 3
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    A geologic assessment of potential lunar ores (1979)
    In:  CASI
    Details
    Publication Date: 2006-01-12
    Description: Although bulk lunar soil is not a suitable feedstock for extracting metals, certain minerals such as anorthite and ilmenite can be separated and concentrated. These minerals can be considered as potential ores of aluminum, silicon, titanium, andiron. A separation and metal extraction plant could also extract large amounts of oxygen and perhaps hydrogen from these minerals. Anorthie containing 19 percent aluminum and 20 percent silicon can be concentrated from some highland soils where it is present in amounts up to 60 percent. Ilmenite containing 32 percent titanium and 37 percent iron can be concentrated from some mare soils where it is present in amounts up to 10 percent. The ideal mining site would be located at the boundary between a high-titanium mare and a high-aluminum highlands. Such area may exist around the rims of some eastern maria, particularly Tranquilitatis. A location on Earth with raw materials as described above would be considered an economically valuable ore deposit if conventional terrestrial resources were not available.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: NASA. Ames Res. Center Space Resources and Space Settlements; p 243-255
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  • 4
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    A refractory glass chondrule in the Vigarano chondrite (1974)
    In:  Other Sources
    Details
    Publication Date: 2011-08-16
    Description: Vigarano, a type 3 carbonaceous chondrite, contains a chondrule composed of highly refractory Ca- and Al-rich glass with minor spinel. The chondrule formed from material similar to the Ca-, Al-, Ti-rich aggregates that are common in Vigarano and other type 3 chondrites and formation of these refractory aggregates must predate formation of some Vigarano chondrules. Experiments with synthetic analogs and a comparison with studies in the system CaO-MgO-Al2O3-SiO2 indicate a temperature for formation of the chondrule at or above 1700 C followed by very rapid cooling.
    Keywords: SPACE SCIENCES
    Type: Meteoritics; 9; Mar. 30
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  • 5
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    Oxygen extraction from lunar materials - An experimental test of an ilmenite reduction process (1985)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: The reaction of ilmenite with hydrogen to produce water has been studied experimentally in order to evaluate the effectiveness of using a cold trap to improve yields in a continuous flow process. Yields were enhanced, but not to the degree observed in batch processing systems. The terrestrial simulant used in these studies contained traces of iron sulfide, which released H2S during processing with a deleterious effect on several components of the test system. More sophisticated testing should be undertaken to obtain kinetic data and attention given to the removal of sulfides in the pre-process beneficiation.
    Keywords: INORGANIC AND PHYSICAL CHEMISTRY
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  • 6
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    The lithification and metamorphism of lunar breccias. (1972)
    In:  Other Sources
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    Publication Date: 2011-08-16
    Description: Investigations regarding the textural and mineralogical classification of Apollo 14 breccias are considered together with some related experimental studies. The experiments can be used to construct a temperature scale which may be called the 'petrogenetic line' for lunar breccias. A model for the Fra Mauro formation is also discussed. The most interesting facts revealed by the discussion are the intensity of heating involved and the short times necessary to develop the physical properties of the Apollo 14 breccias. The purpose of the studies is to construct a scale of lunar metamorphic temperatures which is consistent with experimentally determined conditions necessary for the acquisition of certain properties by the lunar breccias.
    Keywords: SPACE SCIENCES
    Type: Earth and Planetary Science Letters; 16; Oct. 197
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  • 7
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    Activity-composition relations in the fayalite-forsterite solid solution between 900 and 1300 C at low pressures. (1972)
    In:  Other Sources
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    Publication Date: 2011-08-16
    Keywords: GEOPHYSICS
    Type: Earth and Planetary Science Letters; 15; July 197
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  • 8
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    The origin and stability of lunar goethite, hematite and magnetite. (1972)
    In:  Other Sources
    Details
    Publication Date: 2011-08-16
    Description: Extra-lunar contamination, fumarolic activity, and exposure to oxidizing gases from comet or carbonaceous meteorite impacts have been previously proposed as the causes of magnetite, hematite, and goethite in lunar materials. However, these minerals can occur in the stable low-temperature gas-solid equilibrium assemblages of lunar rocks. Below 600 C magnetite is in equilibrium with C-O-H gases with compositions compatible with high-temperature equilibrium with metallic iron; below 150 C hematite is stable in these same gases. Goethite is not stable in carbonaceous gases at low total pressure, and thus gases from impacting carbonaceous material cannot have produced it. Goethite is stable at low temperatures and pressures in almost pure H2-H2O gases. Its minimum stability against hematite is 2 bars total pressure at 130 C and 0.001 bars at 30 C for H2 to H2O ratios compatible with the high-temperature redox state of lunar materials. Thus the traces of magnetite, hematite, and goethite in lunar materials may be the result of normal low-temperature processes indigenous to the moon and not special processes.
    Keywords: SPACE SCIENCES
    Type: Earth and Planetary Science Letters; 17; Dec. 197
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  • 9
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    Dynamic crystallization experiments on chondrule melts in reduced gravity (1987)
    In:  CASI
    Details
    Publication Date: 2013-08-31
    Description: Chondrules crystallized during the earliest formational history of the solar system; and, if crystal settling and flotation are indicators of crystallization in the presence of gravity, they formed without the influence of gravity. In fact, attempts to duplicate the crystallization history of chondrules in the laboratory have met with limited success, because of the difficulty of comparing objects formed under the influence of gravity with objects that did not. These comparisons are difficult because there are several recognized features introduced by the presence of gravity and no doubt some which are not yet recognized. As a result there are several microscale and macroscale aspects of chondrule petrology which are difficult to understand quantitatively. Most of the features relate to the settling or flotation of early formed crystals. The proposed experiments are briefly described.
    Keywords: MATERIALS PROCESSING
    Type: Experiments in Planetary and Related Sciences and the Space Station; 2 p
    Format: application/pdf
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  • 10
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    Experimental temperature distribution and heat load characteristics of rotating heat pipes (1978)
    In:  Other Sources
    Details
    Publication Date: 2011-08-17
    Description: Experimental results show conclusively that the presence of a small quantity of a noncondensable gas (NCG) mixed with the working fluid has a considerable effect on the condensation process in a rotating heat pipe. The temperature distribution in the condenser shows the blanketing effect of the NCG and the ratio of the molecular weight of the working fluid to that of the NCG has a very definite effect on the shape of this distribution. Some of the effects are quite similar to the well-established data on stationary heat pipes.
    Keywords: FLUID MECHANICS AND HEAT TRANSFER
    Type: International Journal of Heat and Mass Transfer; 21; Feb. 197
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