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  • 1
    Publication Date: 2023-06-08
    Description: Purpose: Pesticide contamination of river waters is a global problem, and therefore, authorities regularly monitor the water quality status. Especially, flood events might transport large pesticide loads downstream and impact adjacent areas such as sensible floodplain environments by deposing particle bound pesticides or by contaminating the environments by dissolved substances directly. Unfortunately, only little attempts were made to quantify the pesticide pollution of such environments, as the monitoring of soil and sediment contamination is by far more time consuming and complicated compared to the analysis of water samples.
    Description: Materials and methods: In the study presented, we therefore used a holistic approach starting with the reconstruction of the inundation characteristics of a floodplain located in the upper part of the river Elbe, Germany, by using nearby gauging data, screened databases for pesticide concentrations and calculated pesticide loads, and finally, sampled the floodplain soils along an elevation (inundation) gradient.
    Description: Results: As expected, the reconstructed inundation characteristics showed that the low-lying areas of the backwater inflow of the floodplain were flooded more frequently compared to the areas at higher elevation, whereby even the highest elevations sampled were at least flooded during each decade. Furthermore, pesticide concentrations of the river waters and calculated pesticide loads revealed that 13 pesticides can be found regularly, whereby atrazine, terbuthylazine, metazachlor, metolachlor, isoproturon, and chlorotoluron are the main contaminants.
    Description: Conclusion: Concluding, a spatial pattern in the contamination could be detected. High residues of simazine and ethofumesate were associated with areas of less and more frequent inundations, respectively. The transformation products of atrazine and terbuthylazine (2-hydroxy-atrazine and 2-hydroxy-terbuthylazine) were detected, whereby the quantity could be well explained by the inundation characteristics and pesticide loads of the river water.
    Description: Forschungszentrum Jülich GmbH (4205)
    Keywords: ddc:363.73 ; Floodplain soil ; Pesticide ; Contamination ; Simazine ; Ethofumesate ; 2-Hydroxy-atrazine ; 2-Hydroxy-terbuthylazine ; Metazachlor ; Metolachlor ; Isoproturon ; Chlorotoluron
    Language: English
    Type: doc-type:article
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  • 2
    Publication Date: 2024-02-07
    Description: Modular Observation Solutions of Earth Systems (MOSES) is a novel observation system that is specifically designed to unravel the impact of distinct, dynamic events on the long-term development of environmental systems. Hydrometeorological extremes such as the recent European droughts or the floods of 2013 caused severe and lasting environmental damage. Modeling studies suggest that abrupt permafrost thaw events accelerate Arctic greenhouse gas emissions. Short-lived ocean eddies seem to comprise a significant share of the marine carbon uptake or release. Although there is increasing evidence that such dynamic events bear the potential for major environmental impacts, our knowledge on the processes they trigger is still very limited. MOSES aims at capturing such events, from their formation to their end, with high spatial and temporal resolution. As such, the observation system extends and complements existing national and international observation networks, which are mostly designed for long-term monitoring. Several German Helmholtz Association centers have developed this research facility as a mobile and modular “system of systems” to record energy, water, greenhouse gas, and nutrient cycles on the land surface, in coastal regions, in the ocean, in polar regions, and in the atmosphere—but especially the interactions between the Earth compartments. During the implementation period (2017–21), the measuring systems were put into operation and test campaigns were performed to establish event-driven campaign routines. With MOSES’s regular operation starting in 2022, the observation system will then be ready for cross-compartment and cross-discipline research on the environmental impacts of dynamic events.
    Type: Article , PeerReviewed
    Format: text
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  • 3
    Publication Date: 2021-07-21
    Description: In the last decade, time‐domain crosshole ground‐penetrating radar full‐waveform inversion has been applied to several different test sites and has improved the resolution and reconstruction of subsurface properties. The full‐waveform inversion requires several diligent executed pre‐processing steps to guarantee a successful inversion and to minimize the risk of being trapped in a local minimum. Thereby, one important aspect is the starting models of the full‐waveform inversion. Generally, adequate starting models need to fulfil the half‐wavelength criterion, which means that the modelled data based on the starting models need to be within half of the wavelength of the measured data in the entire investigation area. Ray‐based approaches can provide such starting models, but in the presence of high contrast layers, such results do not always fulfil this criterion and need to be improved and updated. Therefore, precise and detailed data processing and a good understanding of experimental ground‐penetrating radar data are necessary to avoid erroneous full‐waveform inversion results. Here, we introduce a new approach, which improves the starting model problem and is able to enhance the reconstruction of the subsurface medium properties. The new approach tames the non‐linearity issue caused by high contrast complex media, by applying bandpass filters with different passband ranges during the inversion to the modelled and measured ground‐penetrating radar data. Thereby, these bandpass filters are considered for a certain number of iterations and are progressively expanded to the selected maximum frequency bandwidth. The resulting permittivity full‐waveform inversion model is applied to update the effective source wavelet and is used as an updated starting model in the full‐waveform inversion with the full bandwidth data. This full‐waveform inversion is able to enhance the reconstruction of the permittivity and electrical conductivity results in contrast to the standard full‐waveform inversion results. The new approach has been applied and tested on two synthetic case studies and an experimental data set. The field data were additionally compared with cone penetration test data for validation.
    Keywords: 550.83 ; 2D ; Data processing ; Ground‐penetrating radar ; Inversion
    Type: article
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  • 4
    Publication Date: 2021-07-04
    Description: Modeling soil hydraulic properties requires an effective representation of capillary and noncapillary storage and conductivity. This is made possible by using physically comprehensive yet flexible soil hydraulic property models. Such a model (Brunswick [BW] model) was introduced by Weber et al. (2019, https://doi.org/10.1029/2018WR024584), and it overcomes some core deficiencies present in the widely used van Genuchten‐Mualem (VGM) model. We first compared the performance of the BW model to that of the VGM model in its ability to describe water retention and hydraulic conductivity data on a set of measurements of 402 soil samples with textures covering the entire range of classes. Second, we developed a simple transfer function to predict BW parameters based on VGM parameters. Combined with our new function, any existing pedotransfer function for the prediction of the VGM parameters can be extended to predict BW model parameters. Based on information criteria, the smaller variance of the residuals, and a 40% reduction in mean absolute error in the hydraulic conductivity over all samples, the BW model clearly outperforms VGM. This is possible as the BW model explicitly accounts for hydraulic properties of dry soils. With the new pedotransfer function developed in this study, better descriptions of water retention and hydraulic conductivities are possible. We are convinced that this will strengthen the utility of the new model and enable improved field‐scale simulations, climate change impact assessments on water, energy and nutrient fluxes, as well as crop productivity in agroecosystems by soil‐crop and land‐surface modeling. The models and the pedotransfer function are included in an R package spsh (https://cran.r‐project.org/package=spsh).
    Description: Plain Language Summary: Soil hydraulic property models are mathematical functions, which describe the relationship between the soil water pressure head and the state of soil water saturation, on the one hand, and the soil water pressure head and the unsaturated soil hydraulic conductivity, on the other. These types of mathematical functions are flexible by adjustable parameters. With one set of model equations, the hydraulic properties of soils which may have very different properties due to their vast natural variability can be described. The models treated in this work are (i) the van Genuchten‐Mualem model, a model with well‐known problems, but still frequently applied, and (ii) a relatively new physical comprehensive model, named the Brunswick model. First of all, in a data‐based comparison of model performance, we demonstrate that the Brunswick model has systematic advantages. Second, knowledge about these above‐mentioned parameters can be determined through other mathematical functions, so‐called hydro‐pedotransfer functions, which empirically relate these parameters to observed soil properties. The information about these soil properties can be measured in the laboratory and is also recorded in soil maps. We created a new pedotransfer function to facilitate the prediction of model parameters for the new Brunswick model.
    Description: Key Points: A pedotransfer function is established to relate van Genuchten‐Mualem (VGM) to Brunswick (BW) soil hydraulic property model parameters. The BW model overcomes the structural deficiencies in VGM and leads to considerably better descriptions of retention and conductivity data. With the new pedotransfer function, soil properties and information in soil maps can be used to predicted BW model parameters.
    Description: German Research Foundation http://dx.doi.org/10.13039/501100007450
    Description: Collaborative Research Center 1253 CAMPOS
    Keywords: 551 ; hydraulic conductivity ; model comparison ; model improvement ; pedotransfer functions ; soil hydraulic properties ; water retention
    Type: article
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  • 5
    Publication Date: 2021-07-21
    Description: Modeling of the land surface water‐, energy‐, and carbon balance provides insight into the behavior of the Earth System, under current and future conditions. Currently, there exists a substantial variability between model outputs, for a range of model types, whereby differences between model input parameters could be an important reason. For large‐scale land surface, hydrological, and crop models, soil hydraulic properties (SHP) are required as inputs, which are estimated from pedotransfer functions (PTFs). To analyze the functional sensitivity of widely used PTFs, the water fluxes for different scenarios using HYDRUS‐1D were simulated and predictions compared. The results showed that using different PTFs causes substantial variability in predicted fluxes. In addition, an in‐depth analysis of the soil SHPs and derived soil characteristics was performed to analyze why the SHPs estimated from the different PTFs cause the model to behave differently. The results obtained provide guidelines for the selection of PTFs in large scale models. The model performance in terms of numerical stability, time‐integrated behavior of cumulative fluxes, as well as instantaneous fluxes was evaluated, in order to compare the suitability of the PTFs. Based on this, the Rosetta, Wösten, and Tóth PTF seem to be the most robust PTFs for the Mualem van Genuchten SHPs and the PTF of Cosby for the Brooks Corey functions. Based on our findings, we strongly recommend to harmonize the PTFs used in model inter‐comparison studies to avoid artifacts originating from the choice of PTF rather from different model structures.
    Description: Plain Language Summary: Hydrological models need information about the soil physical characteristics (soil hydraulic parameters), which are in general not available if the models are applied at larger scales (region to global scale). Therefore, pedotransfer functions (PTFs) are classically used, which relate easily available soil properties such as sand‐, silt‐, clay‐content, soil organic carbon content, and soil bulk density, which are available from soil maps, to the soil hydraulic parameters. Unfortunately, there are many different PTFs available in literature. In the study presented, we analyzed the impact of different PTFs on the simulation results of water fluxes and found, that the choice of PTF impacts the simulation results. Further, some PTFs were identified as being less robust compared to others. In general, the study shows that harmonizing PTFs in model‐inter‐comparisons is needed to avoid artifacts originating from the choice of PTF rather from different model structures.
    Description: Key Points: Using different PTFs in hydrological models causes substantial variability in predicted fluxes. We strongly recommend to harmonize the PTFs used in model inter‐comparison studies.
    Keywords: 551.3 ; crop models ; hydrological models ; land surface models ; LSM ; model ensemble mean ; model inter‐comparison ; pedotransfer functions
    Type: article
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  • 6
    Publication Date: 2022-03-25
    Description: Fast and accurate large‐scale localization and quantification of harmfully compacted soils in recultivated post‐mining landscapes are of particular importance for mining companies and the following farmers. The use of heavy machinery during recultivation imposes soil stress and can cause irreversible subsoil compaction limiting crop growth in the long term. To overcome or guide classical point‐scale methods to determine compaction, fast methods covering large areas are required. In our study, a recultivated field of the Garzweiler mine in North Rhine‐Westphalia, Germany, with known variability in crop performance was intensively studied using non‐invasive electromagnetic induction (EMI) and electrode‐based electrical resistivity tomography (ERT). Additionally, soil bulk density, volumetric soil water content and soil textures were analysed along two transects covering different compaction levels. The results showed that the measured EMI apparent electrical conductivity (ECa) along the transects was highly correlated (R2 〉 .7 for different dates and depths below 0.3 m) to subsoil bulk density. Finally, the correlations established along the transects were used to predict harmful subsoil compaction within the field, whereby a spatial probabilistic map of zones of harmful compaction was developed. In general, the results revealed the feasibility of using the EMI derived ECa to predict harmful compaction. They can be the basis for quick monitoring of the recultivation process and implementation of necessary melioration to return a well‐structured soil with good water and nutrient accessibility, and rooting depths for increased crop yields to the farmers.
    Description: BonaRes (Module A)
    Keywords: ddc:631.4
    Language: English
    Type: doc-type:article
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  • 7
    Publication Date: 2021-10-07
    Description: To investigate transient dynamics of soil water redistribution during infiltration, we conducted horizontal borehole and surface ground penetrating radar measurements during a 4-day infiltration experiment at the rhizontron facility in Selhausen, Germany. Zero-offset ground penetrating radar profiling in horizontal boreholes was used to obtain soil water content information at specific depths (0.2, 0.4, 0.6, 0.8 and 1.2 m). However, horizontal borehole ground penetrating radar measurements do not provide accurate soil water content estimates of the top soil (0–0.1 m depth) because of interference between direct and critically refracted waves. Therefore, surface ground penetrating radar data were additionally acquired to estimate soil water content of the top soil. Due to the generation of electromagnetic waveguides in the top soil caused by infiltration, a strong dispersion in the ground penetrating radar data was observed in 500 MHz surface ground penetrating radar data. A dispersion inversion was thus performed with these surface ground penetrating radar data to obtain soil water content information for the top 0.1 m of the soil. By combining the complementary borehole and surface ground penetrating radar data, vertical soil water content profiles were obtained, which were used to investigate vertical soil water redistribution. Reasonable consistency was found between the ground penetrating radar results and independent soil water content data derived from time domain reflectometry measurements. Because of the improved spatial representativeness of the ground penetrating radar measurements, the soil water content profiles obtained by ground penetrating radar better matched the known water storage changes during the infiltration experiment. It was concluded that the combined use of borehole and surface ground penetrating radar data convincingly revealed spatiotemporal soil water content variation during infiltration. In addition, this setup allowed a better quantification of water storage, which is a prerequisite for future applications, where, for example, the soil hydraulic properties will be estimated from ground penetrating radar data.
    Keywords: 550.724 ; Ground-penetrating radar ; Hydrogeophysics ; Data processing
    Language: English
    Type: map
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