ALBERT

Description: The piston velocity for the tropical Atlantic Ocean has been determined from 29 radon profiles measured during the TTO Tropical Atlantic Study. By combining these data with the pCO2 data measured in the surface water and air samples, the net flux of CO2 across the sea-air interface has been calculated for the tropical Atlantic. The dependence of the piston velocity on wind speed is discussed, and possible causes for the high sea-to-air CO2 flux observed in the equatorial zone are examined.

Description: Between 1996 and 1998, a concerted effort was made to study the deep open ocean convection in the Labrador Sea. Both in situ observations and numerical models were employed with close collaboration between the researchers in the fields of physical oceanography, boundary layer meteorology, and climate. A multitude of different methods were used to observe the state of ocean and atmosphere and determine the exchange between them over the experiment's period. The Labrador Sea Deep Convection Experiment data collection aims to assemble the observational data sets in order to facilitate the exchange and collaboration between the various projects and new projects for an overall synthesis. A common file format and a browsable inventory have been used so as to simplify the access to the data.

Description: Global ship-based programs, with highly accurate, full water column physical and biogeochemical observations repeated decadally since the 1970s, provide a crucial resource for documenting ocean change. The ocean, a central component of Earth’s climate system, is taking up most of Earth’s excess anthropogenic heat, with about 19% of this excess in the abyssal ocean beneath 2,000 m, dominated by Southern Ocean warming. The ocean also has taken up about 27% of anthropogenic carbon, resulting in acidification of the upper ocean. Increased stratification has resulted in a decline in oxygen and increase in nutrients in the Northern Hemisphere thermocline and an expansion of tropical oxygen minimum zones. Southern Hemisphere thermocline oxygen increased in the 2000s owing to stronger wind forcing and ventilation. The most recent decade of global hydrography has mapped dissolved organic carbon, a large, bioactive reservoir, for the first time and quantified its contribution to export production (∼20%) and deep-ocean oxygen utilization. Ship-based measurements also show that vertical diffusivity increases from a minimum in the thermocline to a maximum within the bottom 1,500 m, shifting our physical paradigm of the ocean’s overturning circulation.

Description: Chlorofluorocarbon (component CFC-11) and hydrographic data from 1997, 1999, and 2001 are presented to track the large-scale spreading of the Upper Labrador Sea Water (ULSW) in the subpolar gyre of the North Atlantic Ocean. ULSW is CFC rich and comparatively low in salinity. It is located on top of the denser “classical” Labrador Sea Water (LSW), defined in the density range σΘ = 27.68–27.74 kg m−3. It follows spreading pathways similar to LSW and has entered the eastern North Atlantic. Despite data gaps, the CFC-11 inventories of ULSW in the subpolar North Atlantic (40°–65°N) could be estimated within 11%. The inventory increased from 6.0 ± 0.6 million moles in 1997 to 8.1 ± 0.6 million moles in 1999 and to 9.5 ± 0.6 million moles in 2001. CFC-11 inventory estimates were used to determine ULSW formation rates for different periods. For 1970–97, the mean formation rate resulted in 3.2–3.3 Sv (Sv ≡ 106 m3 s−1). To obtain this estimate, 5.0 million moles of CFC-11 located in 1997 in the ULSW in the subtropical/tropical Atlantic were added to the inventory of the subpolar North Atlantic. An estimate of the mean combined ULSW/LSW formation rate for the same period gave 7.6–8.9 Sv. For the years 1998–99, the ULSW formation rate solely based on the subpolar North Atlantic CFC-11 inventories yielded 6.9–9.2 Sv. At this time, the lack of classical LSW formation was almost compensated for by the strongly pronounced ULSW formation. Indications are presented that the convection area needed in 1998–99 to form this amount of ULSW exceeded the available area in the Labrador Sea. The Irminger Sea might be considered as an additional region favoring ULSW formation. In 2000–01, ULSW formation weakened to 3.3–4.7 Sv. Time series of layer thickness based on historical data indicate that there exists considerable variability of ULSW and classical LSW formation on decadal scales.

Description: In the autumn of 1996 the field component of an experiment designed to observe water mass transformation began in the Labrador Sea. Intense observations of ocean convection were taken in the following two winters. The purpose of the experiment was, by a combination of meteorological and oceanographic field observations, laboratory studies, theory, and modeling, to improve understanding of the convective process in the ocean and its representation in models. The dataset that has been gathered far exceeds previous efforts to observe the convective process anywhere in the ocean, both in its scope and range of techniques deployed. Combined with a comprehensive set of meteorological and air-sea flux measurements, it is giving unprecedented insights into the dynamics and thermodynamics of a closely coupled, semienclosed system known to have direct influence on the processes that control global climate.

Description: Measurements of chlorofluorocarbon inventories during 1997–2003 allow the detection and quantification of significant changes in the formation rates of two modes of Labrador Sea Water (LSW): Upper (ULSW) and deep LSW, both here defined in fixed density intervals. Both modes contribute to the cold limb of the Meridional Overturning Circulation. Results reveal that the lighter ULSW formed since the mid-1990s has started to replace the large pool of the deep LSW stored in the western North Atlantic. Formation of deep LSW was absent in 1997–2003. Formation of ULSW compensated for this absence during 1998/99 (7.9 Sv), but afterwards significantly declined to 2.5 Sv. The decrease of the overall LSW formation throughout 1997–2003 correlates with a declining eastward baroclinic mass transport between the centers of the subpolar and subtropical gyres since 1997, a warming of LSW, and a gradually decreasing North Atlantic Oscillation index after 1999.

Description: In 1997, a unique hydrographic and chlorofluorocarbon (CFC: component CFC-11) dataset was obtained in the subpolar North Atlantic. To estimate the synopticity of the 1997 data, the recent temporal evolution of the CFC and Labrador Sea Water (LSW) thickness fields are examined. In the western Atlantic north of 50°N, the LSW thickness decreased considerably from 1994–97, while the mean CFC concentrations did not change much. South of 50°N and in the eastern Atlantic, the CFC concentration increased with little or no change in the LSW thickness. On shorter timescales, local anomalies due to the presence of eddies are observed, but for space scales larger than the eddies the dataset can be treated as being synoptic over the 1997 observation period. The spreading of LSW in the subpolar North Atlantic is described in detail using gridded CFC and LSW thickness fields combined with Profiling Autonomous Lagrangian Circulation Explorer (PALACE) float trajectories. The gridded fields are also used to calculate the CFC-11 inventory in the LSW from 40° to 65°N, and from 10° to 60°W. In total, 2300 ± 250 tons of CFC-11 (equivalent to 16.6 million moles) were brought into the LSW by deep convection. In 1997, 28% of the inventory was still found in the Labrador Sea west of 45°W and 31% of the inventory was located in the eastern Atlantic. The CFC inventory in the LSW was used to estimate the lower limits of LSW formation rates. At a constant formation rate, a value of 4.4–5.6 Sv (Sv ≡ 106 m3 s−1) is obtained. If the denser modes of LSW are ventilated only in periods with intense convection, the minimum formation rate of LSW in 1988–94 is 8.1–10.8 Sv, and 1.8–2.4 Sv in 1995–97

Description: The Arctic Ocean constitutes a large body of water that is still relatively poorly surveyed because of logistical difficulties, although the importance of the Arctic Ocean for global circulation and climate is widely recognized. For instance, the concentration and inventory of anthropogenic CO2 (C ant) in the Arctic Ocean are not properly known despite its relatively large volume of well-ventilated waters. In this work, we have synthesized available transient tracer measurements (e.g., CFCs and SF6) made during more than two decades by the authors. The tracer data are used to estimate the ventilation of the Arctic Ocean, to infer deep-water pathways, and to estimate the Arctic Ocean inventory of C ant. For these calculations, we used the transit time distribution (TTD) concept that makes tracer measurements collected over several decades comparable with each other. The bottom water in the Arctic Ocean has CFC values close to the detection limit, with somewhat higher values in the Eurasian Basin. The ventilation time for the intermediate water column is shorter in the Eurasian Basin (∼200 years) than in the Canadian Basin (∼300 years). We calculate the Arctic Ocean C ant inventory range to be 2.5 to 3.3 Pg-C, normalized to 2005, i.e., ∼2% of the global ocean C ant inventory despite being composed of only ∼1% of the global ocean volume. In a similar fashion, we use the TTD field to calculate the Arctic Ocean inventory of CFC-11 to be 26.2 ± 2.6 × 106 moles for year 1994, which is ∼5% of the global ocean CFC-11 inventory