ALBERT

Description: Telemetry data are presented for two communications hybrid satellites, Spacenet I and Spacenet II, collected to determine the long-term temperature trend and associated solar absorptance degradation of the optical solar reflectors (OSRs). A thermal model was used to calculate the thermal sensitivity of various OSR components to changes in the solar absorptance and to determine absolute values of solar absorptance. The separation of the data into sunlit and nonsunlit periods made it possible to confirm the hypothesis that degradation occurs under the catalytic activity of direct sunlight on the spacecraft contaminants. The differences found between the degradation rates for Spacenet-I and Spacenet-II satellites and between the present results and published reports on other satellites are considered to be related to variations in the volume of spacecraft contaminants.

Description: The focus of this study was on the autoxidation kinetics of deposit precursor formation in jet fuels. The objectives were: (1) to demonstrate that laser-induced fluorescence is a viable kinetic tool for measuring rates of deposit precursor formation in jet fuels; (2) to determine global rate expressions for the formation of thermal deposit precursors in jet fuels; and (3) to better understand the chemical mechanism of thermal stability. The fuels were isothermally stressed in small glass ampules in the 120 to 180 C range. Concentrations of deposit precursor, hydroperoxide and oxygen consumption were measured over time in the thermally stressed fuels. Deposit precursors were measured using laser-induced fluorescence (LIF), hydroperoxides using a spectrophotometric technique, and oxygen consumption by the pressure loss in the ampule. The expressions, I.P. = 1.278 x 10(exp -11)exp(28,517.9/RT) and R(sub dp) = 2.382 x 10(exp 17)exp(-34,369.2/RT) for the induction period, I.P. and rate of deposit precursor formation R(sub dp), were determined for Jet A fuel. The results of the study support a new theory of deposit formation in jet fuels, which suggest that acid catalyzed ionic reactions compete with free radical reactions to form deposit precursors. The results indicate that deposit precursors form only when aromatics are present in the fuel. Traces of sulfur reduce the rate of autoxidation but increase the yield of deposit precursor. Free radical chemistry is responsible for hydroperoxide formation and the oxidation of sulfur compounds to sulfonic acids. Phenols are then formed by the acid catalyzed decomposition of benzylic hydroperoxides, and deposit precursors are produced by the reaction of phenols with aldehydes, which forms a polymer similar to Bakelite. Deposit precursors appear to have a phenolic resin-like structure because the LIF spectra of the deposit precursors were similar to that of phenolic resin dissolved in TAM.

Description: The effect of fuel variations at the same hydrogen content on the formation of soot in a gas turbine combustor was studied. Six fuels were burned to a combustor over a matrix of about 50 test conditions with test conditions ranging over 500-1800 kPa (5-18 atm) pressure and 500-1000 K burner inlet temperature; fuel-air ratios were varied from 0.008-0.024. Flame radiation measurements were made through a sapphire window toward the end of the primary zone. The hydrogen content of the six test fuels ranged from 12.80 to 12.88%. Five fuels emphasized hydrocarbon types: (mono, di, and tricyclic), naphthenes (decalin) and partially hydrogenated aromatics (tetralin); the sixth fuel emphasized final boiling point.

Description: An extensive, low-perigee orbital aerodynamic heating study was undertaken in support of the Atmosphere Explorer-C Temperature Alarm. State of the art of low-density, high-speed flows, some models of the earth's atmosphere, external flow-field definition, thermodynamic and transport properties of atmospheric gases, the accommodation coefficient orbital thermal environment, and correlation of theory and measurements are discussed. Aerodynamic heating rates are determined for eight selected orbits by means of a reduced, analytical model verified by both ground test and flight data. These heating rates are compared with classical free-molecule and first-order collision regime values.

Description: A high pressure research combustor operating over a wide range of burner inlet conditions was used to determine the effects of fuel molecular structure on soot formation. Six test fuels with equal hydrogen content (12.8%) were blended to stress different molecular components and final boiling points. The fuels containing high concentrations (20%) of polycyclic aromatics and partially saturated polycyclic structures such as tetralin, produced more soot than would be expected from a hydrogen content correlation for typical petroleum based fuels. Fuels containing naphthenes such as decalin agreed with the hydrogen content correlation. The contribution of polycyclic aromatics to soot formation was equivalent to a reduction in fuel hydrogen content of about one percent. The fuel sensitivity to soot formation due to the polycyclic aromatic contribution decreased as burner inlet pressure and fuel/air ratio increased.

Description: A high-pressure research combustor operating over a wide range of burner inlet conditions was used to determine the effects of fuel molecular structure on soot formation. Six test fuels with equal hydrogen content (12.8 percent) were blended to stress different molecular components and final boiling points. The fuels containing high concentrations (20 percent) of poly-cyclic aromatics and partially saturated polycyclic structures such as tetralin, produced more soot than would be expected from a hydrogen content correlation for typical petroleum based fuels. However, fuels containing naphthenes, such as decalin, agreed with the hydrogen content correlation. The contribution of polycylic aromatics to soot formation was equivalent to a reduction in fuel hydrogen content of about 1%. The fuel sensitivity to soot formation due to the polycyclic aromatic contribution decreased as burner inlet pressure and fuel/air ratio increased.

Description: This document presents the results of an extensive, low perigee, orbital aerodynamic heating study undertaken in support of the Atmosphere Explorer-C Temperature Alarm. Based upon in-flight orbital temperature data from the Temperature Alarm tungsten resistance wire thermometer, aerodynamic heating rates have been determined for eight selected orbits by means of a reduced thermal analytical model verified by both ground test and flight data. These heating rates are compared with the classical free molecular and first order collision regime values. It has been concluded that, for engineering purposes, the aerodynamic heating rate of atmospheric gases at perigee altitudes between 170 and 135 km on pure tungsten wire is 30 to 60% of the value set by the classical free molecular limit. Relative to the more usual orbital thermal input attributable to direct solar radiation, the aerodynamic heating rate at the lowest altitude attempted with the spacecraft despun (135 km) is the equivalent of about 1.2 solar constants incident on a tungsten wire with a solar absorptivity of 0.85.

Description: Marine acoustic data are used to map and characterize submarine slope failure along the accretionary prism of Cascadia. Two main styles of slope failure are identified: (1) failures with curved head scarps, which are predominantly associated with incoherent debris-flow deposits; and (2) failures with rectangular head scarps, which are predominantly associated with intact sediment blocks. Rectangular head scarps mostly occur on thrust ridges with slope angles 〈16° and ridge heights 〈650 m, whereas curved head scarps occur predominantly on steeper and higher ridges. Off Vancouver Island, failure style and head-scarp geometry also change with ridge azimuth. We propose that the curved head scarps and debris flows may be a result of higher kinetic forcing of the downsliding sediments and a higher degree of mixing. At the more gently sloped, less elevated ridges, the kinetic forcing may be smaller, which leads to intact failure masses. Extensional faults at ridges with curved scarps may result from oversteepening and collapse of the sediments that cannot withstand their own weight due to limited internal shear strength. The slide geometries and potential controls on failure style may inform subsequent studies in assessing the risks for tsunami generation from submarine slope failures along the Cascadia margin.

Description: Multibeam bathymetric data acquired off Vancouver Island across the accretionary prism of the Cascadia subduction zone reveal a prominent segmentation of the deformation front with dominant azimuths of the ridges at ~120° and ~150° and abundant submarine landslides. Both these ridge-orientations are oblique to the direction of subduction (~45°). Ridges at a strike of ~120° show dominantly rectangular-shaped failure head-scarps and intact blocks of sediments within the failed sediment mass, whereas ridges with an azimuth of ~150° show curved head-scarps and incoherent debris in the failure mass. We propose that this systematic change in failure-style is related to the underlying thrust fault system producing steeper and taller ridges for azimuths around 150°, but less steep and tall ridges at 120°. Thus, debris-flow style failure is simply a result of higher kinetic forcing of the down-sliding sediment mass: more mixing and destruction of the coherent blocks for taller and steeper ridges, and blocks of intact sediment for gentle slopes and less elevated ridges. A segmentation of the deformation front and ridge alignment into two dominant azimuths could be a result of: a) complex interaction and competing forces from overall slab-pull (45°), b) re-activated faults orientated almost N-S (~175°) on the oceanic plate and overlying sediment cover (reflected in the magnetic stripes and abyssal plain strike-slip faulting), and c) relative orientation of the back-stop off Vancouver Island and accreted terranes (at ~127° following the coastline between Nootka Island and Port Renfrew). Extensional faulting is observed only at ridges with debris-flow style failure, which also are the ridges with larger height and steeper slopes. These extensional faults may be the result of over-steepening of the ridges and collapse of the sediment pile that can no longer withstand its own weight due to limited internal shear strength.