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  • 1
    Publication Date: 2023-12-19
    Description: The shale gas potential of Ediacaran and Lower Silurian shales from the Upper Yangtze platform is assessed in this study with a focus on the contributions of clay minerals and organic matter to sorption capacity. For this purpose, a multidisciplinary assessment was carried out using petrophysical, mineralogical, petrographic and geochemical methods. In terms of TOC contents (4.2%), brittle mineral contents (68.6%) and maximum gas storage capacities (0.054–0.251 mmol/g) Ediacaran shales from this study show comparable properties to other producing shale gas systems although the thermal maturity is extremely high (VRr = 3.6%). When compared to lower Silurian shales from the same region, it is evident that (1) deeper maximum burial and (2) a lack of silica-associated preservation of the pores resulted in a relatively lower mesopore volume, higher micropore volume fraction and lower overall porosity (Ediacaran shales: 1.4–4.6%; Silurian shales: 6.2–7.4%). Gas production is therefore retarded by poor interconnectivity of the pore system, which was qualitatively demonstrated by comparing experimental gas uptake kinetics. TOC content exhibits a prominent control on sorption capacity and micropore volume for both shales. However, different contributions of clay minerals to sorption capacity were identified. This can partly be attributed to different clay types but is likely also related to burial-induced recrystallisation and different origins of illite. Additionally, it was shown that variations in sorption capacity due to incorrect estimates of clay mineral contribution are in the same range as variations due to differences in thermal maturity. Article highlights Pore structure and gas storage characteristics are evaluated for the first time for Ediacaran Shales from the Upper Yangtze platform Due to a lower free gas storage capacity and diffusivity, the Ediacaran shale can be regarded as a less favorable shale gas prospect when compared to the Silurian shale Clay mineral contribution to sorption capacity is evaluated taking clay mineralogy into consideration Maturity-related changes of organic matter sorption capacity have been discussed on the basis of a compiled data set
    Description: RWTH Aachen University (3131)
    Keywords: ddc:552 ; Ediacaran ; Silurian ; Sorption capacity ; Pore structure ; Mineralogy ; Thermal maturity
    Language: English
    Type: doc-type:article
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  • 2
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    Geological Society
    In:  In: Mesozoic Resource Potential in the Southern Permian Basin. , ed. by Kilhams, B., Kukla, P. A., Mazur, S., McKie, T., Mijnlieff, H. F. and van Ojikk, K. Geological Society Special Publication, 469 . Geological Society, London, Chapter 21.
    Publication Date: 2018-06-29
    Description: A high-resolution three-dimensional (3D) numerical basin model, incorporating the eastern part of the Lower Saxony Basin (LSB), the Gifhorn Trough and parts of the southern Pompeckj Block, was built to reconstruct the thermal and structural evolution of this area. The estimation and calculation of the unconventional oil and gas resource density within the Posidonia Shale source-rock unit was the main objective of this study. Incorporating organic–geochemical data for the Posidonia Shale source-rock units, such as compositional petroleum generation kinetics data, allowed a more accurate prediction of hydrocarbon potential compared to large-scale models of the area, as well as a better prediction of bulk adsorption capacity and adsorbed gas content. For the accurate calculation of oil and gas contents within the source-rock lithologies, mineralogy and physical properties of the rocks, such as compressibility, sorption capacity and porosity, are important as well as organic matter quantity, quality and thermal maturity. These properties in turn are strongly dependent on the vastly different burial/uplift histories within the LSB, Gifhorn Trough and the Pompeckj Block. The Gifhorn Trough, large parts of the Pompeckj Block and the flanks of the LSB are interesting concerning the unconventional oil potential, with current source-rock maturities between 0.65% and 1.2% vitrinite reflectance. Central parts of the LSB and small parts of the Pompeckj Block show inherent unconventional gas potential. Methane adsorption capacity is influenced by the burial/uplift history of the basin, which stresses the importance of structural and geochemical interlocking in understanding unconventional hydrocarbon systems.
    Type: Book chapter , NonPeerReviewed
    Format: text
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  • 3
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    Springer International
    In:  Springer International, Cham, X, 150 pp. ISBN 978-331991229-5; 978-331991228-8
    Publication Date: 2021-02-08
    Description: This is the first book that analyses the future raw materials supply from the demand side of a society that chiefly relies on renewable energies, which is of great significance for us all. It addresses primary and secondary resources and substitution, not only from technical but also socioeconomic and ethical points of view. The "Energiewende" (Energy Transition) will change our consumption of natural resources significantly. When in future our energy requirements will be covered mostly by wind, solar power and biomass, we will need less coal, oil and natural gas. However, the consumption of minerals, especially metallic resources, will increase to build wind generators, solar panels or energy storage facilities. Besides e.g. copper, nickel or cobalt, rare earth elements and other high-tech elements will be increasingly used. With regard to primary metals, Germany is 100 % import dependent; only secondary material is produced within Germany. Though sufficient geological primary resources exist worldwide, their availability on the market is crucial. The future supply of the market is dependent on the development of prices, the transparency of the market and the question of social and ethical standards in the raw materials industry, as well as the social license to operate, which especially applies to mining. The book offers a valuable resource for everyone interested in the future raw material supply of our way of life, which will involve more and more renewable energies.
    Type: Book , NonPeerReviewed
    Format: text
    Format: text
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  • 4
    Publication Date: 2021-10-12
    Description: Stratigraphic forward modelling was used to simulate the deposition of Upper Cretaceous, Eocene and Oligo-Miocene source rocks in the Eastern Mediterranean Sea and, thus, obtain a process-based 3D prediction of the quantity and quality distribution of organic matter (OM) in the respective intervals. Upper Cretaceous and Eocene models support the idea of an upwelling-related source rock formation along the Levant Margin and the Eratosthenes Seamount (ESM). Along the margin, source rock facies form a narrow band of 50 km parallel to the palaeo shelf break, with high total organic carbon (TOC) contents of about 1% to 11%, and HI values of 300–500 mg HC/g TOC. On top of the ESM, TOC contents are mainly between 0.5% and 3% and HI values between 150 and 250 mg HC/g TOC. At both locations, TOC and HI values decrease rapidly towards the deeper parts of the basin. In the Oligo-Miocene intervals, terrestrial OM makes up the highest contribution to the TOC content, as marine organic matter (OM) is diluted by high-sedimentation rates. In general, TOC contents are low (〈1%), but are distributed relatively homogenously throughout the whole basin, creating poor quality, but very thick source rock intervals of 1–2 km of cumulative thickness. The incorporation of these source rock models into a classic petroleum system model could identify several zones of thermal maturation in the respective source rock intervals. Upper Cretaceous source rocks started petroleum generation in the late Palaeocene/early Eocene with peak generation between 20 and 15 Ma ca. 50 km offshore northern Lebanon. Southeast of the ESM, generation started in the early Eocene with peak generation between 18 and 15 Ma. Eocene source rocks started HC generation ca. 25 Ma ago between 50 and 100 km southeast of the ESM and reached the oil to wet gas window at present day. However, until today they have converted less than 20% of their initial kerogen. Although the Miocene source rocks are mostly immature, Oligocene source rocks lie within the oil window in the southern Levant Basin and reached the onset of the wet gas window in the northern Levant Basin. However, only 10%–20% of their initial kerogen have been transformed to date.
    Keywords: 553.2 ; Eastern Mediterranean ; source rock distribution ; petroleum system modelling
    Language: English
    Type: map
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