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  • 1
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    Aircraft measurements of NO(x) over the eastern Pacific and continental United States and implications for ozone production (1990)
    In:  Other Sources
    Details
    Publication Date: 2011-08-19
    Description: Results are reported from airborne measurements of NO, NO2, O3, and CO obtained in the free troposphere (FT) and boundary layer (BL) over the western U.S. and eastern Pacific during the NASA Global Tropospheric Experiment Chemical Instrumentation Test and Evaluation 2 (CITE 2) in summer 1986. The aircraft instrumentation and the CITE 2 flight protocols are described, and the results are presented in extensive tables and graphs. Over the ocean the median mixing ratios for NO and NO2 were found to be 4.0 and 10.4 parts per trillion by volume (pptv), respectively, in the BL and 12.4 and 18.0 pptv in the FT; the corresponding values over land were 34.5 and 75.0 pptv in the BL and 13.0 and 36.0 pptv in the FT. in continental air masses. NO(x) is shown to be positively correlated with O3 and CO and negatively correlated with dewpoint over the ocean, whereas over land NO(x) was positively correlated with O3, CO, and dewpoint.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 95; 10205-10
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  • 2
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    Ratios of peroxyacetyl nitrate to active nitrogen observed during aircraft flights over the eastern Pacific Ocean and continental United States (1990)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 95; 10179-10
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  • 3
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    An intercomparison of airborne nitrogen dioxide instruments (1990)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: Results on NO2 instruments are reported from the NASA Global Tropospheric Experiment Chemical Instrumentation Test and Evaluation 2 (CITE 2) program in summer 1986. The instruments tested were (1) a two-photon LIF system using a laser for NO2-NO photolysis, (2) a chemiluminescence (CL) detector using FeSO4 for NO2-NO conversion, (3) a CL detector using an arc lamp for NO2-NO photolysis, and (4) a tunable-laser-diode multipath-absorption system. The procedures for the CITE 2 ground-based and flight tests are described in detail, and the results are presented in extensive graphs. Instrument (2) was eliminated because the FeSO4 converted atmospheric PAN to NO, resulting in spuriously high NO2 values. The remaining instruments gave readings in 30-40-percent agreement at NO2 mixing ratios of 100-200 parts per trillion by volume (pptv). At ratios below 50 pptv, the correlation among the measurements was very poor, with a tendency for system (4) to give higher values than (1) or (3).
    Keywords: AIRCRAFT INSTRUMENTATION
    Type: Journal of Geophysical Research (ISSN 0148-0227); 95; 10103-10
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  • 4
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    An intercomparison of results from ferrous sulphate and photolytic converter techniques for measurements of NO(x) made during the NASA GTE/CITE 1 aircraft program (1988)
    In:  Other Sources
    Details
    Publication Date: 2011-08-19
    Description: Two techniques designed for measurements of NO(x (NO + NO2) were intercompared during aircraft flights made in the spring of 1984 in the middle free troposphere over the eastern Pacific Ocean and southwestern U.S. One NO chemiluminescence instrument was equipped with a ferrous sulphate converter, another with a photolytic converter. The ferrous sulphate-equipped instrument was apparently much less specific for NO2. It registered levels about three times larger than the photolytic converter and gave NO2/NO ratios that were much larger than photochemical calculations would indicate as reasonable. Additionally, the results imply that active NO(x) was only 10-20 percent of the total odd nitrogen in the middle free troposphere.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 93; 15803-15
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  • 5
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    Redistribution of reactive odd nitrogen in the lower arctic stratosphere (1990)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: In-situ measurements of total reactive odd nitrogen NO(y), were made from the NASA DC-8 aircraft in the lower arctic stratosphere during the 1989 Airborne Arctic Stratospheric Expedition. Throughout January and February, NO(y) mixing ratios were typically between 0.5 and 3 parts per billion by volume (ppbv) at altitudes between 10 and 12.5 km. During several flights late in the mission, events of unusually light NO(y) occurred with mixing ratios up to 12 ppbv at these altitudes. Simultaneous measurements of N2O, O3, and H2O during these events suggest that large changes in NO(y) are not expected. The elevated NO(y) values are interpreted as a vertical redistribution of NO(y) in the lower stratosphere resulting from gravitational sedimentation of aerosol particles containing HNO3. No evidence of the redistribution of H2O is noted, consistent with observations of denitrification without dehydration higher in the stratosphere.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters, Supplement (ISSN 0094-8276); 17; 453-456
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  • 6
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    An intercomparison of carbon monoxide, nitric oxide, and hydroxyl measurement techniques - Overview of results (1984)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: Results from an intercomparison of methods to measure carbon monoxide (CO), nitric oxide (NO), and the hydroxyl radical (OH) are discussed. The intercomparison was conducted at Wallops Island, Virginia, in July 1983 and included a laser differential absorption and three grab sample/gas chromatograph methods for CO, a laser-induced fluorescence (LIF) and two chemiluminescence methods for NO, and two LIF methods and a radiocarbon tracer method for OH. The intercomparison was conducted as a field measurement program involving ambient measurements of CO (150-300 ppbv) and NO (10-180 pptv) from a common manifold with controlled injection of CO in incremental steps from 20 to 500 ppbv and NO in steps from 10 to 220 pptv. Only ambient measurements of OH were made. The agreement between the techniques was on the order of 14 percent for CO and 17 percent for NO. Hardware difficulties during the OH tests resulted in a data base with insufficient data and uncertanties too large to permit a meaningful intercomposition.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 89; 11819-11
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  • 7
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    Ground-based measurements of O3, NO2, OClO, and BrO during the 1987 Antarctic ozone depletion event (1988)
    In:  CASI
    Details
    Publication Date: 2013-08-31
    Description: Near-ultraviolet absorption spectroscopy in the wavelength range from 330 to 370 nm was used to measure O3, NO2, OClO, and BrO at McMurdo Station (78S) during 1987. Visible absorption measurements of O3, NO2, and OClO were also obtained using the wavelength range from about 403 to 453 nm. These data are described and compared to observations obtained in 1986. It is shown that comparisons of observations in the two wavelength ranges provide a sensitive measure of the altitude where the bulk of atmospheric absorption takes place.
    Keywords: ENVIRONMENT POLLUTION
    Type: NASA, Goddard Space Flight Center, Polar Ozone Workshop. Abstracts; p 118
    Format: application/pdf
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  • 8
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    Observations of diurnal variations of BrO and OClO at McMurdo Station, Antarctica (78S) (1988)
    In:  CASI
    Details
    Publication Date: 2013-08-31
    Description: Observations of the diurnal variations of OClO and BrO during austral spring, 1987 using long-path visible and near-ultraviolet absorption spectroscopy are presented and compared to simplified model calculations. It is shown that care must be taken to compare model calculations and measurements along the line of sight of the instrument. Evening twilight observations of OClO are shown to be broadly consistent with current photochemical schemes, assuming ClO and BrO levels near 50 mb of about 0.5 ppbv and 7 pptv, respectively, throughout the observing period from late Aug. to mid-Oct. Nighttime observations of OClO obtained using the moon as a light source display evidence for growth through the night in late-Aug., but not in late-Sept. Further, the observed morning twilight OClO abundances are in agreement with model calculations in late August, but generally fall below in late September and October. Observations of BrO in mid-Sept. systematically show far greater evening twilight than morning twilight abundances.
    Keywords: ENVIRONMENT POLLUTION
    Type: NASA, Goddard Space Flight Center, Polar Ozone Workshop. Abstracts; p 139
    Format: application/pdf
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  • 9
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    Characterization of Adhesives for Attaching Reusable Surface Insulation on Space Shuttle Vehicles (1973)
    In:  CASI
    Details
    Publication Date: 2014-09-09
    Description: An extensive development and testing program on adhesive systems shows that: (1) A closed cell silicone rubber sponge bonded to substrates with thin bond lines of glass filled adhesive exhibits density and modulus values approximately one third that of solid silicone adhesives; (2) utilization of glass or phenolic microballoons as fillers in silicone adhesives reduces density but increases moduli of the vulcanized materials; (3) the silicone elastomer based adhesives appear to be complex systems rather than homogeneous, isotropic materials. Tensile, shear, and compression properties plotted versus temperature verify this conjecture; and (4) constant strain-stress relaxation tests on glass-filled adhesive show that stress relaxation is most pronounced near the glass transition temperature.
    Keywords: MATERIALS, NONMETALLIC
    Type: NASA. Ames Res. Center Symp. on Reusable Surface Insulation for Space Shuttle, Vol. 3; p 935-964
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  • 10
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    Measurements of nitric oxide in the boundary layer and free troposphere over the Pacific Ocean (1987)
    In:  Other Sources
    Details
    Publication Date: 2011-08-19
    Description: Measurements of NO and O3 are presented from 13 aircraft flights made over the Pacific Ocean in the autumn of 1983 during one phase of the NASA Global Tropospheric Experiment. All of the flights were made between 15 deg and 42 deg N and from the coast of California to west of the Hawaiian Islands. Within the upper marine boundary layer the median daytime mixing ratio of NO was near 1 part per trillion by volume (pptv). Values of NO less than 10 pptv were often observed up to altitudes near 6 km. Thus for the location and season of the measurements, a net photochemical destruction of O3 would be anticipated for the boundary layer region and to altitudes of 2-3 km. At higher altitudes of 7-11 km in the free troposphere, larger mixing ratios and greater variability were usually observed for NO. Both features are consistent with observed examples of injection of NO and O3 from the lower stratosphere and with the injection of NO from towering, electrically active, cumulonimbus clouds.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 92; 2025-204
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