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  • 1
    Publication Date: 2011-08-24
    Description: Measurements of ozone retrieved from satellite instruments over the 1979-1991 period are compared. The instruments used are the total ozone mapping spectrometer (TOMS), the solar backscattered ultraviolet experiment (SBUV), and stratospheric aerosol and gas experiments (SAGE) I and II. Although there is good agreement between the absolute densities of ozone as measured by the various instruments, the long-term changes (1979-1990) disagree sharply as a function of pressure and in the integrated ozone amount. In the upper stratosphere, SBUV trends are negative with maximum values of about -1.5%/year at high latitudes. Combined SAGE I and II trends are slightly positive in this region and peak near 0.5%/year at equatorial latitudes. In the lower stratosphere, SBUV trends reflect small decreases in ozone, generally less than -0.4%/year except at high southern latitudes where the trends rearch values of approximately -1.5%/year. SAGE ozone trends exhibit large decreases particularly in the equatorial regions where decreases of 3-6%/year are seen at pressures between 60 and 90 mbar. At higher latitudes, SAGE trends are more comparable to SBUV trends in the lower stratosphere. Total ozone trends from TOMS and SBUV agree within their uncertainties. Near-zero trends are indicated at low latitudes, and larger, negative trends (approximately -0.5%/year) are indicated near the poles. The SAGE column ozone trends depend upon the base level altitude of integration but do not exhibit a strong latitude dependence.
    Keywords: ENVIRONMENT POLLUTION
    Type: Journal of Geophysical Research (ISSN 0148-0227); 99; D10; p. 20,501-20,511
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  • 2
    Publication Date: 2011-08-24
    Description: The concept of the well-known Langley plot technique, used for the calibration of ground-based instruments, has been generalized for application to satellite instruments. In polar regions, near summer solstice, the solar backscattered ultraviolet (SBUV) instrument on the Nimbus 7 satellite samples the same ozone field at widely different solar zenith angles. These measurements are compared to assess the long-term drift in the instrument calibration. Although the technique provides only a relative wavelength-to-wavelength calibration, it can be combined with existing techniques to determine the drift of the instrument at any wavelength. Using this technique, we have generated a 12-year data set of ozone vertical profiles from SBUV with an estimated accuracy of +/- 5% at 1 mbar and +/- 2% at 10 mbar (95% confidence) over 12 years. Since the method is insensitive to true changes in the atmospheric ozone profile, it can also be used to compare the calibrations of similar SBUV instruments launched without temporal overlap.
    Keywords: INSTRUMENTATION AND PHOTOGRAPHY
    Type: Journal of Geophysical Research (ISSN 0148-0227); 100; D2; p. 2997-3004
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  • 3
    Publication Date: 2011-08-24
    Description: The development of the springtime (September-November) Antarctic ozone hole was observed by the Meteor 3/total ozone mapping spectromter (TOMS) to result in the lowest ozone value, 85 DU (Dobson units) on October 8, 1993, ever measured by TOMS. During late September and early October the region of extremely low ozone values was centered on the geographical pole between 85 deg S and 90 deg S. The geographical extent of the ozone hole region, the area within the 220-DU contour, reached a maximum during the first week in October at a near-circular area covering 24 x 10(exp 6) sq km reaching to the southern tip of South America. This approximately matched the 1992 area record. After the maximum area was reached in early October, the 1993 ozone hole region was significantly larger than during 1992 throughout the remainder of the month of October. The very low ozone values over the Antarctic continent have been confirmed by independent ground-based data. Unlike 1992, the formation of the 1993 Antarctic ozone hole does not coincide with unusually low ozone values observed over most of the globe for the past 2 years. The most recent ozone data from Meteor 3/TOMS show that there has been a recovery at all latitudes from the extraordinarily low values observed during 1992 and part of 1993 after the June 1991 eruption of Mount Pinatubo. Meteor 3/TOMS is described and compared with Nimbus 7/TOMS during the 1991 to May 1993 overlap period. Observations of the 1992 ozone hole are presented from both instruments and are shown to agree within 5 DU.
    Keywords: ENVIRONMENT POLLUTION
    Type: Journal of Geophysical Research (ISSN 0148-0227); 100; D2; p. 2973-2983
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  • 4
    Publication Date: 2011-08-24
    Description: The 1992 global average total ozone, measured by the Total Ozone Mapping Spectrometer (TOMS) on the Nimbus-7 satellite, was 2 to 3 percent lower than any earlier year observed by TOMS (1979 to 1991). Ozone amounts were low in a wide range of latitudes in both the Northern and Southern Hemispheres, and the largest decreases were in the regions from 10 to 20 deg S and 10 to 60 deg N. Global ozone in 1992 is at least 1.5 percent lower than would be predicted by a statistical model that includes a linear trend and accounts for solar cycle variation and the quasi-biennial oscillation. These results are confirmed by comparisons with data from other ozone monitoring instruments: the SBUV/2 instrument on the NOAA-11 satellite, the TOMS instrument on the Russian Meteor-3 satellite, the World Standard Dobson Instrument 83, and a collection of 22 ground-based Dobson instruments.
    Keywords: GEOPHYSICS
    Type: Science (ISSN 0036-8075); 260; 5107; p. 523-526.
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  • 5
    Publication Date: 2011-08-24
    Description: Total Ozone Mapping Spectrometer (TOMS) measurements of equatorial total ozone following the eruption of Mt. Pinatubo show a decrease of up to 6 percent over climatology. Ozone losses begin approximately a month following the eruption, consistent with the time required for the SO2 to convert to sulfuric acid aerosol. The thick aerosol layer interferes with the TOMS retrieval, but this interference is small and easily accounted for in the retrieval. Ozone values remain below climatology until December, 1991. Ozonesonde data from Natal, Brazil taken before and two months after the eruption support TOMS observations of ozone loss. These sondes show that the ozone loss region is confined to a 2-3 km thick layer between 24 and 28 km.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 20; 1; p. 29-32.
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  • 6
    Publication Date: 2011-08-24
    Description: Results of a simulation study on the effects of optically thick stratospheric sulfate aerosol layers on the backscattered ultraviolet radiation (buv) in the range 256-340 nm are presented. In general, the increased Mie scattering produced by the aerosols results in an enhancement of the buv radiation. The increase is approximately linear with optical depth and strongly depends on solar zenith angle and aerosol layer altitude in relation to the ozone maximum. The effect is greatest at those wavelenghts whose contribution functions peak in the vicinity of the densest part of the aerosol layer. The aerosol induced perturbation of the buv field affects the ozone profile retrieval from space measurements by the Solar Backscatter Ultraviolet Experiment (SBUV) experiment. In the tropical stratosphere, the retrieved ozone between 25 and 45 km is underestimated as a result of increased Mie scattering. On the other hand, an algorithm related effect causes the retrieved ozone below 25 km to be overestimated by an amount similar to the stratospheric deficit.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Geopysical Research Letters (ISSN 0094-8276); 22; 3; p. 235-238
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  • 7
    Publication Date: 2009-05-20
    Description: A new method of estimating the downward ozone flux across the midlatitude tropopause is introduced. The algorithm derives the estimate from total column ozone observations. Vertical information is given by analysis potential vorticity fields. This method yields an annual estimate of 500 +/- 140 Tg/yr stratospheric injection of ozone into the northern hemisphere, midlatitude troposphere. The downward ozone flux exhibits the expected spring maximum and autumn minimum. The annual distribution of the cross-tropopause ozone, transport by latitude is consistent with the seasonal frequency and (list distribution) of baroclinic systems. This algorithm also produces localized results and call thus be applied to a single case or global studies.
    Keywords: Environment Pollution
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  • 8
    Publication Date: 2011-08-24
    Description: A comparison of Umkehr ozone profile data with the reprocessed solar backscatter ultraviolet (SBUV) ozone data in the northern middle-latitude region, 30 deg to 50 deg N, is reported. Although significant biases exist between the two types of observations, the long-term variations and least squares linear regression trends agree remarkably well over the comparison period of 1979 to 1990. The ozone trend in the upper stratosphere is of the order of -0.9%/yr. Near 25 km, little if any trend appears, but a larger negative trend is seen in the lower stratosphere near 15 km. Comparisons show that the average annual ozone cycles in the profiles also agree well. The upper stratospheric ozone results are consistent with photochemical model predictions of ozone depletion near 40 km that are due to the release of anthropogenically produced chlorofluorocarbons. The lower stratospheric ozone trend results are in reasonable agreement with published ozonesonde data trends. It is shown that the ozone trends in the lower stratospheric layers impact significantly on the total ozone trend of the order of -0.47%/yr. The good agreement now seen between the two types of observations suggest that the combined ground-based and satellite approach could provide a valuable database for long-term monitoring of stratospheric ozone for trends and extraordinary variations.
    Keywords: ENVIRONMENT POLLUTION
    Type: Journal of Geophysical Research (ISSN 0148-0227); 99; D9; p. 18,901-18,908
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  • 9
    Publication Date: 2011-08-19
    Description: The ozone profiles measured by SBUV in the region of the Antarctic ozone minimum are in error as archived for altitudes below the 7 mb level in the atmosphere because of the lack of a reasonable climatology to use for the initial guess profile. The ozone profile error in this region is examined, and it is shown that use of a reasonable climatology in this unusual region results in ozone profiles that agree substantially better with the balloon observations available from the Syowa station. The corrected profiles show that by 1984 there was 35 percent less ozone in the 15 to 30 km region than in 1979, and 14 percent less even in the 40 to 50 km region.
    Keywords: GEOPHYSICS
    Type: (ISSN 0094-8276); 13; 1213-121
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  • 10
    Publication Date: 2011-08-19
    Description: Until recently, Umkehr data taken by 20 Dobson stations around the world have been the principal source of information about the behavior of upper stratospheric ozone. Umkehr results are used also for detecting drifts in satellite instruments and for determining intersatellite biases. However, a systematic evaluation of the quality of Umkehr data taken by the various stations has been lacking. Five years of ozone profile data from the Solar Backscattered Ultraviolet (SBUV) have been used to examine and intercompare the quality of Umkehr stations, and to assess the degradation of their performance after the El Chichon volcano eruption in southern Mexico. In contrast to Umkehr, the SBUV ozone measurments in layers 7 through 9 (1-8 mb) were unaffected by the massive amounts of dust and gases ejected by El Chichon.
    Keywords: GEOPHYSICS
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