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  • Data  (8)
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  • 1
    Publication Date: 2023-07-14
    Description: We present the first high-resolution trace element (Mg/Ca, Sr/Ca, Ba/Ca) record from a stalagmite in southwestern Romania covering the last 3.6 ka, which provides the potential for quantitative climate reconstruction. Precise age control is based on three independent dating methods, in particular for the last 250 yr, where chemical lamina counting is combined with the identification of the 20th century radiocarbon bomb peak and 230Th/U dating. Long-term cave monitoring and model simulations of drip water and speleothem elemental variability indicate that precipitation-related processes are the main drivers of speleothem Mg/Ca ratios. Calibration against instrumental climate data shows a significant anti-correlation of speleothem Mg/Ca ratios with autumn/winter (October to March) precipitation (r = −0.61, p 〈 0.01), which is statistically robust when considering age uncertainties and auto-correlation. This relationship is used to develop a quantitative reconstruction of autumn/winter precipitation. During the late Holocene, our data suggest a heterogeneous pattern of past regional winter hydroclimate in the Carpathian/Balkan realm, along with intermittent weakening of the dominant influence of North Atlantic forcing. In agreement with other regional paleo-hydrological reconstructions, the observed variability reveals periodically occurring strong NW-SE hydro-climate gradients. We hypothesize, that this pattern is caused by shifts of the eastern edge of the area of influence of the NAO across central-eastern Europe due to the confluence of North Atlantic forcing, and other climatic features such as the East Atlantic/Western Russia (EAWR) pattern.
    Keywords: CC_C09-2; Closani Cave, Romania; North Atlantic forcing; precipitation reconstruction; proxy calibration; Romania; speleothem; Speleothem sample; SPS; Stalagmite C09-2; trace elements
    Type: Dataset
    Format: application/zip, 4 datasets
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  • 2
    Publication Date: 2023-07-14
    Keywords: Age; AGE; Age, error; CC_C09-2; Closani Cave, Romania; DISTANCE; North Atlantic forcing; precipitation reconstruction; proxy calibration; Romania; speleothem; Speleothem sample; SPS; Stalagmite C09-2; trace elements; δ13C, carbonate; δ18O, carbonate
    Type: Dataset
    Format: text/tab-separated-values, 7328 data points
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  • 3
    Publication Date: 2023-07-14
    Keywords: Age; AGE; Barium/Calcium ratio; CC_C09-2; Closani Cave, Romania; DISTANCE; LA-ICP-MS, Laser-ablation inductively coupled plasma mass spectrometer; Magnesium/Calcium ratio; North Atlantic forcing; precipitation reconstruction; proxy calibration; Romania; speleothem; Speleothem sample; SPS; Stalagmite C09-2; Strontium/Calcium ratio; trace elements
    Type: Dataset
    Format: text/tab-separated-values, 136765 data points
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  • 4
    Publication Date: 2023-07-14
    Keywords: Age, 230Th/U Thorium-Uranium; Age, dated; Age, error; CC_C09-2; Closani Cave, Romania; DISTANCE; Laboratory code/label; Multicollector mass spectrometry; North Atlantic forcing; precipitation reconstruction; proxy calibration; Romania; Sample ID; speleothem; Speleothem sample; SPS; Stalagmite C09-2; Thorium-230/Thorium-232 activity ratio; Thorium-230/Thorium-232 activity ratio, error; Thorium-230/Uranium-238 activity ratio; Thorium-230/Uranium-238 activity ratio, error; Thorium-232; Thorium-232, error; trace elements; Uranium-234/Uranium-238 activity ratio; Uranium-234/Uranium-238 activity ratio, error; Uranium-238; Uranium-238, error
    Type: Dataset
    Format: text/tab-separated-values, 164 data points
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  • 5
    Publication Date: 2023-07-14
    Keywords: Age; AGE; CC_C09-2; Closani Cave, Romania; Magnesium/Calcium ratio; Magnesium/Calcium ratio, standard deviation; North Atlantic forcing; Precipitation, Oct-Mar; Precipitation, Oct-Mar, maximum; Precipitation, Oct-Mar, minimum; precipitation reconstruction; proxy calibration; Reconstructed; Romania; speleothem; Speleothem sample; SPS; Stalagmite C09-2; trace elements
    Type: Dataset
    Format: text/tab-separated-values, 21015 data points
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  • 6
    Publication Date: 2024-03-25
    Description: In this study, the dead carbon fraction (DCF) variations in stalagmite M1-5 from Socotra Island in the western Arabian Sea were investigated through a new set of high-precision U-series and radiocarbon (14C) dates. The data reveal an extreme case of very high and also climate dependent DCF values. For M1-5 an average DCF of 56.2 ± 3.4 % is observed between 27 and 18 kyr BP. Such high DCF values indicate a high influence of aged soil organic matter (SOM) and nearly completely closed system carbonate dissolution conditions. Towards the end of the last glacial period decreasing Mg/Ca ratios suggest an increase in precipitation which caused a marked change in the soil carbon cycling as indicated by sharply decreasing DCF. This is in contrast to the relation of soil infiltration and reservoir age observed in stalagmites from temperate zones. For Socotra Island, which is influenced by the East African-Indian monsoon, we propose that more humid conditions and enhanced net-infiltration after the LGM led to denser vegetation and thus lowered the DCF by increased 14CO2 input into the soil zone. The onset of the Younger Dryas (YD) is represented in the record by the end of DCF decrease with a sudden change to much higher and extremely variable reservoir ages. Our study highlights the dramatic variability of soil carbon cycling processes and vegetation feedback on Socotra Island manifested in stalagmite reservoir ages on both long-term trends and sub-centennial timescales, thus providing evidence for climate influence on stalagmite radiocarbon. This is of particular importance for studies focussing on 14C calibration and atmospheric reconstruction through stalagmites which relies on largely climate independent soil carbon cycling above the cave.
    Keywords: Dead Carbon Fraction; radiocarbon; Socotra; speleothem; U-series
    Type: Dataset
    Format: application/zip, 2 datasets
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  • 7
    Publication Date: 2024-03-25
    Description: In this study, the dead carbon fraction (DCF) variations in stalagmite M1-5 from Socotra Island in the western Arabian Sea were investigated through a new set of high-precision U-series and radiocarbon (14C) dates. The data reveal an extreme case of very high and also climate dependent DCF values. For M1-5 an average DCF of 56.2 ± 3.4 % is observed between 27 and 18 kyr BP. Such high DCF values indicate a high influence of aged soil organic matter (SOM) and nearly completely closed system carbonate dissolution conditions. Towards the end of the last glacial period decreasing Mg/Ca ratios suggest an increase in precipitation which caused a marked change in the soil carbon cycling as indicated by sharply decreasing DCF. This is in contrast to the relation of soil infiltration and reservoir age observed in stalagmites from temperate zones. For Socotra Island, which is influenced by the East African-Indian monsoon, we propose that more humid conditions and enhanced net-infiltration after the LGM led to denser vegetation and thus lowered the DCF by increased 14CO2 input into the soil zone. The onset of the Younger Dryas (YD) is represented in the record by the end of DCF decrease with a sudden change to much higher and extremely variable reservoir ages. Our study highlights the dramatic variability of soil carbon cycling processes and vegetation feedback on Socotra Island manifested in stalagmite reservoir ages on both long-term trends and sub-centennial timescales, thus providing evidence for climate influence on stalagmite radiocarbon. This is of particular importance for studies focussing on 14C calibration and atmospheric reconstruction through stalagmites which relies on largely climate independent soil carbon cycling above the cave.
    Keywords: Accelerator mass spectrometry (AMS); AGE; Age, AMS 14C conventional; Age, dated; Age, standard deviation; Age, Uranium-Thorium; Carbon-14, modern; Carbon-14, modern, atmosphere; Carbon-14, modern, atmosphere, standard deviation; Carbon-14, modern, error; Carbon-14, modern, initial; Carbon-14, modern, initial, standard deviation; Carbon-14, modern, standard deviation; Dead carbon fraction; Dead Carbon Fraction; Dead carbon fraction, standard deviation; DISTANCE; Moomi_Cave_2002; Moomi_Cave_M1-5; radiocarbon; Sample code/label; Socotra; Socotra Island, Arabian Sea; speleothem; Speleothem sample; SPS; U-series
    Type: Dataset
    Format: text/tab-separated-values, 1014 data points
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  • 8
    Publication Date: 2024-03-25
    Description: In this study, the dead carbon fraction (DCF) variations in stalagmite M1-5 from Socotra Island in the western Arabian Sea were investigated through a new set of high-precision U-series and radiocarbon (14C) dates. The data reveal an extreme case of very high and also climate dependent DCF values. For M1-5 an average DCF of 56.2 ± 3.4 % is observed between 27 and 18 kyr BP. Such high DCF values indicate a high influence of aged soil organic matter (SOM) and nearly completely closed system carbonate dissolution conditions. Towards the end of the last glacial period decreasing Mg/Ca ratios suggest an increase in precipitation which caused a marked change in the soil carbon cycling as indicated by sharply decreasing DCF. This is in contrast to the relation of soil infiltration and reservoir age observed in stalagmites from temperate zones. For Socotra Island, which is influenced by the East African-Indian monsoon, we propose that more humid conditions and enhanced net-infiltration after the LGM led to denser vegetation and thus lowered the DCF by increased 14CO2 input into the soil zone. The onset of the Younger Dryas (YD) is represented in the record by the end of DCF decrease with a sudden change to much higher and extremely variable reservoir ages. Our study highlights the dramatic variability of soil carbon cycling processes and vegetation feedback on Socotra Island manifested in stalagmite reservoir ages on both long-term trends and sub-centennial timescales, thus providing evidence for climate influence on stalagmite radiocarbon. This is of particular importance for studies focussing on 14C calibration and atmospheric reconstruction through stalagmites which relies on largely climate independent soil carbon cycling above the cave.
    Keywords: AGE; Age, standard deviation; Dead Carbon Fraction; DISTANCE; Laboratory code/label; Moomi_Cave_2002; Moomi_Cave_M1-5; radiocarbon; Socotra; Socotra Island, Arabian Sea; speleothem; Speleothem sample; SPS; Thorium-230/Thorium-232 activity ratio; Thorium-230/Thorium-232 activity ratio, standard deviation; Thorium-232; Thorium-232, standard deviation; Uranium-238; Uranium-238, standard deviation; U-series; δ234 Uranium; δ234 Uranium, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 740 data points
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