ALBERT

Description: Leg 49 of the International Phase of Ocean Drilling (IPOD) was designed with a wide spectrum of problems in mind. Topics investigated were (1) variation with time of mantle sources of spreading-center magmas, (2) aging of the volcanic layer, (3) degree of hydrothermal alteration and metamorphism of the volcanic layer, (4) lateral and vertical variation of the petrochemistry, magnetic properties, and structure of the volcanic layer, (5) north-south variability of spreading-center magmas through the North Atlantic, (6) initiation of glaciation during the late Pliocene, and (7) the influence of bottom currents originating at the Iceland-Faeroes Ridge on sediments of the ridge flank province of the western North Atlantic.

Description: Unlike many cruises of the Deep Sea Drilling Project, Leg 48 was scientifically planned to drill a number of sites to systematically address the problems of passive margin evolution. Site 400 was drilled at the foot of the Meriadzek Escarpment of North Biscay in 4399 meters depth. The site was located in a half-graben forming part of a succession of tilted and rotated fault blocks near the continent/ocean boundary. Site 401 was situated on the planated edge of a tilted fault-block underlying the southern edge of the Meriadzek Terrace on the north Biscay margin. Site 402 was located on the upper slope of the northern continental margin of the Bay of Biscay. The main objectives were to establish the presence or absence of shallow water Upper Cretaceous beds, and to penetrate pre-Aptian synrift sediments and the upslope equivalent of the deep water Albian-Aptian carbonaceous mudstones penetrated at Hole 400A.

Description: In Costa Rica the manganese deposits are an integral part of the Nicoya ophiolite complex. They contain both primary mineralization and, due to weathering, small residual concentrations. The most common manganese minerals in surface outcrops are psilomelane and pyrolusite. Most of them exist in jasper bodies often in a form of breccia in contact with underlaying basalt. In some instances stratiform manganese-oxide crusts and nodule deposits cap jasper bodies and stratabound deposits being overlain by radiolarites.

Description: Manganiferous soil concretions have been located in pineapple and sugar cane plantations of the Schofield Plateau, Oahu, and black manganiferous coatings on the surface of soils have been observed on the crests of embankments next to pineapple plantations on Oahu, Molokai, and Lanai. The concretions and coatings are found inoxisols derived from volcanic parent material. The moisture regime of the soils is characterized by alternate wet and dry periods. This alternation facilitates remobilization and reprecipitation of manganese and to a much lesser extent iron and associated trace metals in the soils. Optimum conditions for manganiferous soil concretion development are encountered on the Schofield Plateau, where mean annual rainfall exceeds 1000 mm/year but where there is a net evaporation loss from the soils during the dry period (May through October). Remobilization of manganese is less pronounced in the oxisols of Molokai and Lanai, where mean annual rainfall is lower. Thin manganiferous coatings rather than concretions therefore form in these islands. The contents of Mn, Fe, Cu, and Ni of the soils on which Hawaiian concretions form are higher than those of New Zealand soils in which manganese soil concretions are found. This is reflected by the much redder color of the Hawaiian concretion-bearing soils compared with their New Zealand counterparts. Rare earths show an enrichment sequence: parent rock ---+ soil ---+ soil concretion. A small positive Ce anomaly is noted in the soil and is more marked in the concretions. This may be due to the increasing oxidation of Ce in the concretions relative to the soil, although contamination of the soil by concretionary material may also playa role. The parent rock shows no Ce anomaly. Barium and Pb are enriched in concretions relative to the surrounding soil, whereas D, Th, Hf, Nb, Zr, and As are present in similar or higher concentrations in the soil relative to the concretions. Arsenic may follow Fe in the soils. Todorokite is the predominant manganese mineral in the Hawaiian soil concretions, not pyrolusite as previously reported. Scanning electron microscope studies show the crystalline nature of the manganese oxide minerals in the concretions.

Description: Phosphate deposits which apparently formed during the Miocene climatic optimum are widespread on the Chatham Rise and Camp bell Plateau, and on seamounts in the north Tasman Sea. They formed under oxidising conditions by the phosphatisation of older or contemporaneous foraminiferal oozes (Campbell Plateau and Chatham Rise) and coral limestones (Tasman Sea). The phosphorites of the rise and plateau were formed where current activity was sufficiently strong to prevent normal sedimentation, and now form lag deposits. After the Miocene, phosphorite formation ceased and was followed by manganese oxide deposition where conditions were highly oxidising on the eastern Campbell Plateau and north Tasman seamounts, and by glauconite formation in the much less oxidising environments of the western Campbell Plateau and the Chat ham Rise. The manganese deposits are not volcanogenic, as was formerly thought, but formed by slow precipitation from well oxygenated sea water.

Description: The rate of accumulation of a ferromanganese coating on a fragment of pillow basalt was estimated using a variety of techniques. Unsupported 230 Th activity decrease in the oxide layer, K/A dating of the basalt, fission tracks dating of the glassy layer around the basalt, thickness of the palagonitization rind, and integrated 230 Th activity give ages from approximately 3 x 10-6 years to 5 x 10-3 years. Data suggest that the ferromanganese material formed rapidly (33 mm/10-6 years) and by hydrothermal or volcanic processes.