Publication Date:
2016-12-03
Description:
The polybromide salts [BrC(NMe 2 ) 2 ] 2 [Br 8 ] and [BrC(NMe 2 ) 2 ][Br 3 ] were synthesized in the ionic liquid [BMP][OTf] (1-butyl-1-methyl-pyrrolidinium triflate). The compounds were characterized by Raman, NMR, and X-ray single crystal structure determination as well as quantum-chemical calculations. The polybromide dianion [Br 8 ] 2– structure shows similarities to the very recently reported structure of the first octachloride [Cl 8 ] 2– .
Print ISSN:
0044-2313
Electronic ISSN:
1521-3749
Topics:
Chemistry and Pharmacology
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