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  • Artikel  (5)
  • Organic Chemistry  (3)
  • Engineering General  (2)
  • PLASMA PHYSICS
  • 1
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 30 (1965), S. 1-5 
    ISSN: 0021-8383
    Schlagwort(e): Chemistry ; Organic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The reaction between citrate and aqueous iodine is accelerated by the presence of tripositive managanese. The reaction is first order with respect to iodine and increase in concentration of Citrate suppresses the rate of reaction. Increase in the concentration of Mn(III) enhances the reaction rate. pH has a marked influence on the rate of reaction, the reaction being fastest at pH 4.25. The temperature coefficient is of the order of 3. The manganous ions lower the rate of reaction at pH higher than 3.30 while no such effect is noted below this pH. A suitable mechanism has been suggested.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 28 (1965), S. 108-112 
    ISSN: 0021-8383
    Schlagwort(e): Chemistry ; Organic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The kinetics of the reduction of trivalent manganese by tartrate in aqueous solution has been studied. The reaction is catalysed by H+-ions and retarted by the presence of Mn2+. Increase in the concentration of tartrate lowers the rate of reduction of manganese (III). The temperature coefficient of the reaction which is first order, is 3.97 between 30° and 40°.
    Zusätzliches Material: 5 Tab.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 30 (1965), S. 6-9 
    ISSN: 0021-8383
    Schlagwort(e): Chemistry ; Organic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The kinetics of reduction of trivalent manganese by citrate in aqueous solution has been studied. The reaction is optimum at pH 3.30 of the citrate solution and is retarded by the presence of Mn2+ for the citrate solution of pH 3.30 or higher. Increase in the concentration of citrate lowers the rate of reduction of Mn(III). The temperature coefficient of the reaction is 1.83 between 20°C and 30°C.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 39 (1996), S. 2363-2398 
    ISSN: 0029-5981
    Schlagwort(e): Voronoi cell finite element model ; porous and composite materials ; elastoplasticity ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: The Voronoi Cell Finite Element Model (VCFEM) has been successfully developed for materials with arbitrary microstructural distribution. In this method, the finite element mesh evolves naturally by Dirichlet Tessellation of the microstructure. Composite VCFEM for small deformation plasticity has been developed by expressing the element stresses in terms of polynomial expansions of location co-ordinates. Though this works well for discrete composites with inclusions, its effectiveness diminishes sharply for porous materials with voids. The effect worsens sharply with voids of arbitrary shapes. To overcome this limitation, a new way of defining stress functions is introduced in this paper. Based on a transformation method similar to the Schwarz-Christoffel conformal mapping, it introduces reciprocal stress functions that are derived to incorporate shape effects. Several numerical experiments are conducted to establish the strength of this formulation. The effect of various microstructural morphologies on the overall response and local variables are studied.
    Zusätzliches Material: 25 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 39 (1996), S. 3247-3272 
    ISSN: 0029-5981
    Schlagwort(e): arbitrary Lagrangian-EulerianFEM ; r-adaptation ; s-adaptation ; metal forming ; Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: In this paper, an adaptive Arbitrary Lagrangian-Eulerian (ALE) finite element method is developed for solving large deformation problems with applications in metal-forming simulation. The ALE mesh movement is coupled with r-adaptation of automatic node relocation, to minimize element distortion during the process of deformation. Strain localization is considered in this study through the constitutive relations for ductile porous materials. Prediction of localized deformation is achieved through a multilevel mesh superimposition method, termed as s-adaptation. The model is validated by comparison with established results and codes, and a few metal-forming problems are simulated to test its effectiveness.
    Zusätzliches Material: 20 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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