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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 29 (1999), S. 1155-1159 
    ISSN: 1572-8838
    Keywords: bubble street ; flow instability ; gas evolving electrode ; gas fraction ; two-phase flow
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract In vertical gaps between electrode and membrane, the smooth upward flow of the gas–liquid dispersion near the electrode in the form of a bubble street may be upset under certain conditions. At a certain channel height, a downward flow develops near the membrane resulting in a more or less uniform distribution of gas bubbles over the whole cross-sectional area. The controlling conditions of the conversion of the regular bubble street flow into irregular downward flow were analysed quantitatively in a previous theoretical model, the results of which are now compared with experimental data confirming the theory. The experimental data are further used to derive a relationship for the distribution of the volume fraction of gas.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 29 (1999), S. 779-788 
    ISSN: 1572-8838
    Keywords: aluminium ; anode effect ; gas evolution ; fluid dynamics ; two-phase flow
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The cause of the incipience of the anode effect in alumina reduction cells has long been a controversial issue. The most plausible interpretations are (i) an insufficient release of the gaseous phase from underneath the anode surface together with the action of diminished wettability and (ii) the depletion of oxygen-containing ions at the anode surface to result in the limiting current condition. It is shown by means of a mathematical model that each of these effects may be active. The predominant mechanism depends on the operational conditions. Theoretical results are compared with experimental data.
    Type of Medium: Electronic Resource
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