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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 13 (1979), S. 13-23 
    ISSN: 1573-4889
    Keywords: thermodynamics ; stability diagrams ; Fe-Cr-Al ; corrosion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The construction of thermodynamic stability diagrams for the Fe-Cr-Al system is discussed. The constructed diagrams are used to predict materials behavior at coal gasifier oxygen and sulfur potentials. Experiments are run to compare predicted results with experimental observations. Powder mixtures of FeS, Cr2O3, and Al2O3 are used to observe the formation of the iron-chromia and iron-alumina spinels. The spinels are observed at both 871 and 982° C. The formation of an alumina spinel is observed only on the Fe-10Al alloy, whereas no iron-chromia spinel is found on the Fe-Al-Cr alloys.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 13 (1979), S. 197-202 
    ISSN: 1573-4889
    Keywords: thermodynamics ; stability diagrams ; spinels ; Fe-Cr-Ni ; corrosion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The construction of thermodynamic stability diagrams for the Fe-Cr-Ni systems is discussed. The constructed diagrams are used to predict materials behavior at coal gasifier oxygen and sulfur potentials. Some preliminary experiments are run to compare predicted results with experimental observations. Powder mixtures of FeS, NiS, and Cr 2 O 3 are used to observe the formation of the iron-chromia and nickel-chromia spinels at 871° C. Only the iron-chromia spinel was observed. No spinels were observed on 310 stainless steel samples exposed to the same environment.
    Type of Medium: Electronic Resource
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