ISSN:
1573-9171
Keywords:
dimethylzinc
;
aerosil
;
surface structures
;
thermolysis
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract It has been established by IR spectroscopy, mass spectrometry, and quantum-chemical calculations that dimethylzinc reacts with Aerosil to form complexes with strained siloxane bonds on the SiO2 surface; subsequent reactions of these complexes with free hydroxyl groups afford Si-O-Zn-Me and Si-Me surface structures. Alternative ways of formation of the above-mentioned structures are discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00707205
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