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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 16 (1995), S. 883-900 
    ISSN: 1572-9567
    Keywords: heat capacity ; isobaric thermal expansivity ; isothermal compressibility ; m-cresol ; pressure-scanning calorimetry ; specific volume ; thermal coefficient of pressure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Measured and derived thermophysical properties ofm-cresol are reported for pressures up to 400 MPa at temperatures from 303 to 503 K. Isobaric thermal expansivities were measured by pressure-scanning calorimetry from 303 to 503 K and 0.1 to 400 MPa. The specific volume at 353 K was determined by pycnometry at atmospheric pressure and calculated from isothermal compressibilities measured as a funtion of pressure up to 400 MPa. Specific volumes at other temperatures and pressures are calculated from isothermal compressibilities measured as a function of pressure up to 400 MPa. Specific volumes, isothermal compressibilities, thermal coefficients of pressure, and isobaric and isochoric heat capacities at pressures up to 400 MPa are derived at several temperatures. The effects of pressure on the isobaric heat capacities ofm-cresol,n-hexane, and water are compared. The effects of self-association ofm-cresol are apparent in both the thermal expansivity and the heat capacity data.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 17 (1996), S. 405-422 
    ISSN: 1572-9567
    Keywords: heat capacity ; isobaric thermal expansivity ; isothermal compressibility ; pressure-scanning calorimetry ; quinoline ; specific volume ; thermal coellicient of pressure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Measured and derived thermophysical properties of quinoline are reported for pressures up to 400 MPa at temperatures from 303 to 503 K. The specific volume at 353 K was determined from the specific volume at atmospheric pressure measured b) pycnometry and from isothermal compressibilities measured as a function of pressure up to 400 M Pa. Specific volumes, isothermal compressibilities, thermal coellicients of pressure, and isobaric and isochoric heat capacities at pressures up to 4011 MPa are derived at several temperatures. The effects of pressure on the isobaric heat capacity of quinoline, a weakly self-associated liquid. are discussed and compared with the pressure effects on heat capacities ofn-hexane andm-cresol.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 15 (1994), S. 415-441 
    ISSN: 1572-9567
    Keywords: n-hexane ; isobaric thermal expansivities ; pressure-controlled scanning calorimetry ; saturated vapor pressure ; specific volume ; heat capacityisothermal compressibility ; thermal coefficient of pressure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Isobaric thermal expansivities, αp, ofn-hexane have been measured by pressure-controlled scanning calorimetry from just above the saturation vapor pressure to 40 MPa at temperatures from 303 to 453 K and to 300 MPa at 503 K. These new data are combined with literature data to obtain a correlation equation for αp valid from 240 to 503 K at pressures up to 700 MPa. Correlation equations are developed for the saturated vapor pressure, specific volume, and isobaric heat capacity of liquid n-hexane from 240 to 503 K. Calculated volumes, isobaric and isochoric specific heat capacities. isothermal compressibilities, and thermal coefficients of pressure are presented for the entire range of pressure and temperature. The pressure-temperature behavior of these quantities is discussed as a model behavior for simple liquids without strong intermolecular interactions.
    Type of Medium: Electronic Resource
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