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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 38 (1992), S. 2593-2602 
    ISSN: 1572-8943
    Keywords: isomorphous compounds ; solid protonic conductors ; TG ; DTA ; XRD ; IR
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Als Teil einer Studie der Eigenschaften von Feststoff-Protonenleitern wurde neben den IR- und Raman-Spektren auch das thermische Verhalten der isomorphen Verbindungen MH2(IO3)3 (M=K, Rb, NH4) untersucht. In den drei Phasen wurden mit Hilfe von TG, DTA, IR und Röntgendiffraktionsuntersuchungen detaillierte Stöchiometrien entwickelt. Es gab auch Beweise für die Bildung von polymeren [I3O8]− Phasen. Ihre Stabilität steht in Verbindung mit der unterschiedlichen Polarisationsfähigkeit der H-, K- und Rb-Kationen.
    Notes: Abstract The thermal behaviour of the MH2(IO3)3 (M=K, Rb and NH4) isomorphous compounds, as well as the IR and Raman spectra have been investigated as part of a study of the properties of solid protonic conductors. Detailed stoichiometries, sustained by TG, DTA, XRD and IR analysis, have been developed into the three phases. There were also evidences of the formation of the [I3O8]− polymeric phases. Their stabilities were associated to the different polarizing power of the H, K and Rb cations.
    Type of Medium: Electronic Resource
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