ISSN:
0044-2313
Keywords:
Na5TaO5
;
Na5NbO5
;
single crystals
;
structure
;
MAPLE
;
bond length bond strength
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
On Tantalates and Niobates ‘rich in Cations’. On Na5TaO5 and Na5NbO5Colourless, transparent single crystals of Na5TaO5 [annealed mixtures of Na2O, Li2O, and Ta2O5, Na : Li : Ta = 6.6 : 1.1 : 1, Ni-cylinder, 1000°C, 75 d] as well as Na5NbO5 [annealed mixtures of Na2O, Li2O, and Nb2O5, Na : Li : Nb = 6.6 : 1.1 : 1, Ni-cylinder, 1000°C, 75 d] have been prepared. Single crystal data show that both isotypic oxides represent a deformed variant of the NaCl-type of structure [Na5TaO5: 1154 from 1250 I0 (hkl), four-cycle diffractometer Philips PW 1100, ω2-θ scan, Ag—Kα, R = 4.88%, space group c2/c with a = 629.3(1) pm, b = 1025.4(2) pm, c = 1004.6(2) pm, b̃ 106.80(2)°, z = 4 and Na5NbO5: 998 from 1247 I0(hkl), four-cycle diffractometer Philips PW 1100, ω-2θ scan, Ag—Kα, R = 8.58% and Rw = 7.67%, space group C2/2 with a = 629.1(1) pm, b = 1024.4(2) pm, c = 1004.2(2) pm, b̃ = 106.80(2)°, Z = 4].The Madelung Part of Lattice Energy, MAPLE, and Effective Coordination Numbers, ECoN, the latter derived from Mean Effective Fictive Ionic Radii, MEFIR, as well as Charge Distribution, CHARDI, are calculated.
Notes:
Erstmals wurden farblose, transparente Einkristalle von Na5TaO5 [aus innigen Gemengen von Na2O, Li2O5 und Ta2O5, Einwaage vor dem Verreiben: Na : Li : Ta = 6,6 : 1,1 : 1, Ni-Zylinder, 1000°C, 75 d] sowie erneut solche von Na5NbO5 [aus Gemengen von Na2O, Li2O und Nb2O5, Na : Li : Nb = 6,6 : 1,1 : 1, Ni-Zylinder, 1000°C, 75 d] dargestellt. Nach Einkristalluntersuchungen liegt bei den beiden isotypen Oxiden eine Ordnungsvariante des NaCl-Typs [Na5TaO5: 1154 von 1250 I0(hkl), Vierkreisdiffraktometer Philips PW 1100, ω-2θ scan, Ag—Kα, R = 4,88%, Raumgruppe C2/c mit a = 629,3(1) pm, b = 1025,4(2) pm, c = 1004,6(2) pm, b̃ = 106,80(2)° (Guinier-Simon-Daten), Z = 4 bzw. Na5NbO5: 998 von 1247 I0(hkl), Vierkreisdiffraktometer Philips PW 1100, ω-2θ scan, Ag—Kaα, R = 8,58% und Rw = 7,67%, Raumgruppe C2/c mit a = 629,1(1) pm, b = 1024,4(2) pm, c = 1004,2(2) pm, b̃ = 106,80(2)° (Guinier-Simon-Pulverdaten), Z = 4] vor.Der Madelunganteil der Gitterenergie, MAPLE, und Effektive Koordinationszahlen, ECoN, diese über Mittlere Fiktive Ionenradien, MEFIR, sowie die Ladungsverteilung ‚CHARDI‘ wurden berechnet.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19926140809
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